Investigating the potential of functionalized MCM-41 on adsorption of Remazol Red dye

The modification of MCM-41 was performed with 3-aminopropropyltrimethoxysilane. The structural order and textural properties of the synthesized materials were studied by X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetry/differential thermogravimetry, nitrogen adsorption, and desorption analysis. The adsorption capacity of NH₂-MCM-41 was studied with Remazol Red dye. The following parameters were studied in the adsorption process: pH, temperature, adsorbent dosage, and initial concentration. The desorption process was studied in different concentrations of NaOH solutions. The Freundlich isotherm model was found to be fit with the equilibrium isotherm data. Kinetics of adsorption follows the modified Avrami rate equation. The maximum adsorption capacity was estimated to be 45.9 mg?g^?1, with removal of the dye of 99.1 %. The NH₂-MCM-41 material exhibited high desorption capacity with 98.1 %.     

The impact of anger on creative process engagement: The role of social contexts

Drawing on the cognitive persistence perspective of creativity and conservation of resources theory, we investigated how 2 social contexts (perceived relationship conflict and coworker support for creativity) influence the relationship between anger and creative process engagement (CPE) in organizations. We tested our hypotheses using 422 daily surveys from 98 participants, collected over 5 consecutive workdays. The results show that anger perceived relationship conflict and coworker support for creativity interact to influence CPE. Specifically, when relationship conflict is high, the anger–CPE relationship is positive for employees who receive high coworker support for creativity, but negative for those who receive low coworker support for creativity. In contrast, when relationship conflict is low, the anger–CPE relationship is positive but does not differ at high versus low coworker support for creativity.     

Occurrence of mycotoxins in wheat grains exposed to fungicides on fusarium head blight control in southern Brazil

Mycotoxins occurrence in wheat grains impose risks to human and animal health. The southern Brazil has favorable weather conditions for Fusarium graminearum infections and consequently for mycotoxins accumulation on grains. The goal of this study was to evaluate the behavior of new wheat commercial genotypes to Fusarium Head Blight (FHB), to control performance of new fungicide formulations and their relationship with mycotoxins concentration in grains. The manly mycotoxin occurrence on wheat grains in southern Brazil was deoxynivalenol (DON). Two cultivars showed high DON concentration above the tolerance limits (>3000 μg kg^?1). Many other mycotoxins monitored presented concentrations below method detection limit. Satisfactory levels of fungicide effectiveness were achieved against F. graminearum. Some fungicides promoted a satisfactory decrease on DON accumulation in grains. The best results were obtained when prothioconazole was present. SDHI (Succinate dehydrogenase inhibitors) + QoI (Quinone outside inhibitors) fungicides showed benefic effects at FHB control at field, but it did not promote satisfactory reduction on DON contamination. Fungicides can be used satisfactory for FHB control and reduce DON contamination in grains in southern Brazil. The presence of prothioconazole should be recommended. Some genotypes showed high DON concentration and it was not directly related with FHB severity at field.     

Cultivation of freshwater microalgae in biodiesel wash water

Biodiesel wash water is a contaminating industrial effluent that must be treated prior to disposal. The use of this effluent as a low-cost alternative cultivation medium for microalgae could represent a viable supplementary treatment. We cultivated 11 microalgae species with potential use for biodiesel production to assess their growth capacities in biodiesel industrial washing waters. Only Monoraphidium contortum, Ankistrodesmus sp., Chlorococcum sp., and one unidentified Chlorophyceae species grew effectively in that effluent. M. contortum showed the highest growth capacity and had the second highest fatty acid content (267.9 mg g⁻¹ of DW), predominantly producing palmitic (20.9%), 7,10,13-hexadecatrienoic (14%), oleic (16.2%), linoleic (10.5%), and linolenic acids (23.2%). In the second phase of the experiment, the microalgae were cultivated in biodiesel wash water at 75% of its initial concentration as well as in WC (control) medium. After 21 days of cultivation, 25.8 and 7.2% of the effluent nitrate and phosphate were removed, respectively, and the chemical oxygen demand was diminished by 31.2%. These results suggest the possibility of cultivating biodiesel producing microalgae in industrial wash water effluents.

     

Parental diets determine the embryonic fatty acid profile of the tropical nudibranch Aeolidiella stephanieae: the effect of eating bleached anemones

Aeolidiella stephanieae is a stenophagous tropical nudibranch that feeds exclusively on glass anemones of the genus Aiptasia. These sea anemones usually harbour endosymbiotic photosynthetic dinoflagellates that contribute to the nutrition of their host by providing photosynthetates, such as fatty acids (FA). The present work determined the effect of parental diets on the FA profile of A. stephanieae embryos by feeding breeding pairs of this nudibranch with either symbiotic or aposymbiotic A. pallida. Contrasting FA profiles, namely in the levels of palmitic acid (16:0) and docosahexaenoic acid (DHA, 22:6n-3), were recorded for both parental diets and egg masses produced by nudibranchs eating either symbiotic or aposymbiotic A. pallida. Noteworthy effects of parental dietary FAs on egg masses were also observed, particularly for DHA, which is mainly synthetized by the endosymbionts of A. pallida. Additionally, the present study also highlights how bleaching events may promote cascading effects on the nutrition of marine species with a stenophagous diet, such as A. stephanieae.     

Influence of non-erodible particles with multimodal size distribution on aeolian erosion of storage piles of granular materials

Environmental Fluid Mechanics - Aeolian erosion of granular materials is investigated by means of a mathematical emission model and experimental wind tunnel measurements. Main model input data are:...     

Unexpected toxicity decrease during photoelectrochemical degradation of atrazine with NaCl

This report shows an unexpected toxicity decrease during atrazine photoelectrodegradation in the presence of NaCl. Atrazine is a pesticide classified as endocrine disruptor occurring in industrial effluents and agricultural wastewaters. We therefore studied the effects of the degradation method, electrochemical and electrochemical photo-assisted, and of the supporting electrolyte, NaCl and Na₂SO₄, on the residual toxicity of treated atrazine solutions. We also studied the toxicity of treated atrazine solutions using Artemia nauplii. Results show that at initial concentration of 20 mg L⁻¹, atrazine was completely removed in up to 30 min using 10 mA cm⁻² electrolysis in NaCl medium, regardless of the electrochemical method used. The total organic carbon removal by the photo-assisted method was 82% with NaCl and 95% with Na₂SO₄. The solution toxicity increased during sole electrochemical treatment in NaCl, as expected. However, the toxicity unexpectedly decreased using the photo-assisted method. This finding is a major discovery because electrochemical treatment with NaCl usually leads to the formation of toxic chlorine-containing organic degradation by-products.     

Experimental surface flow visualization and numerical investigation of flow structure around an oblong stockpile

Emission factors are largely used to quantify particle emissions from industrial open storage piles. These factors are based on the knowledge of velocity distribution and flow patterns over the stockpile surface which still requires further research. The aim of the present work is to investigate the airflow characteristics over a single typical oblong pile and in its near-ground surroundings for various wind flow directions. Wind tunnel experiments using an oil-film surface coating technique were carried out for near-wall flow visualization. Numerical simulation results, favorably compared to PIV measurements, were used to allow comparison analysis of flow features. For the stockpile oriented 90° to the wind main direction, typical topology of flow around wall-mounted obstacles were observed, notably a wake zone downstream the pile including two main counter-rotating vortices. Further analysis of numerical wall shear stress distribution and streamlines indicates that two complex three-dimensional vortical flow structures develop downstream the pile. For other incoming wind flow directions (30 and 60°), the flow characteristics over the storage pile greatly differ as a single helical main vortex develops from the pile’s crest. Corresponding high values of wall shear stress are noticed downstream the storage pile. For each configuration studied, downwash and upwash zones are induced by the vortical structures developed. This near-wall flow topology combined with areas of high friction levels may be linked to potential dust emission from the ground surface surrounding industrial stockpiles.