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361.
Electrothermal atomic absorption spectrometry methods with Zeeman effect background correction (Z-GFAAS) for determination
of As, Sb, Se, Ag, Cd, Pb, Cu, Fe, Zn, Cr, and Ni in water and sludge samples were developed. The measurements using Z-GFAAS
and variable magnetic field at the three-field dynamic mode permit the sensitivity adaptation for higher analytical concentrations.
Calibration ranges were expanded over two orders of magnitude within one measurement run by the applying three-field dynamic
mode of this correction system. There are presented calibration data, furnace programs, modifiers, and microwave digestion
programs of the obviously monitored elements in the environmental samples. Very low detection limits (3σ criterion) were obtained.
Quality assurance was checked by the suitable CRM. The study brings simultaneous determination of the samples with different
element concentration range and different sample matrixes, as an important application information for an analyst working
in the area of the eco-analytical research. 相似文献
362.
Fiscal spending and the environment: Theory and empirics 总被引:1,自引:0,他引:1
Ramón López Gregmar I. Galinato Asif Islam 《Journal of Environmental Economics and Management》2011,62(2):180-198
During economic crises, governments often increase fiscal spending to stimulate the economy. While the fiscal spending surge may be temporary, spending composition is often altered in favor of expenditures on social programs and other public goods which may persist over time. We model and measure the impact of fiscal spending patterns on the environment. The model predicts that a reallocation of government spending composition towards social and public goods reduces pollution. However, increasing total government spending without altering its composition does not reduce pollution. We empirically test these predictions for air and water pollutants showing that they are fully supported. 相似文献
363.
John M. Logan Enrique Rodríguez-Marín Nicolas Goñi Santiago Barreiro Haritz Arrizabalaga Walter Golet Molly Lutcavage 《Marine Biology》2011,158(1):73-85
Atlantic bluefin tuna (Thunnus thynnus) are highly migratory predators whose abundance, distribution, and somatic condition have changed over the past decades.
Prey community composition and abundance have also varied in several foraging grounds. To better understand underlying food
webs and regional energy sources, we performed stomach content and stable isotope analyses on mainly juvenile (60–150 cm curved
fork length) bluefin tuna captured in foraging grounds in the western (Mid-Atlantic Bight) and eastern (Bay of Biscay) Atlantic
Ocean. In the Mid-Atlantic Bight, bluefin tuna diet was mainly sand lance (Ammodytes spp., 29% prey weight), consistent with historic findings. In the Bay of Biscay, krill (Meganyctiphanes norvegica) and anchovy (Engraulis encrasicolus) made up 39% prey weight, with relative consumption of each reflecting annual changes in prey abundance. Consumption of anchovies
apparently declined after the local collapse of this prey resource. In both regions, stable isotope analysis results showed
that juvenile bluefin tuna fed at a lower trophic position than indicated by stomach content analysis. In the Mid-Atlantic
Bight, stable isotope analyses suggested that >30% of the diet was prey from lower trophic levels that composed <10% of the
prey weights based upon traditional stomach content analyses. Trophic position was similar to juvenile fish sampled in the
NW Atlantic but lower than juveniles sampled in the Mediterranean Sea in previous studies. Our findings indicate that juvenile
bluefin tuna targeted a relatively small range of prey species and regional foraging patterns remained consistent over time
in the Mid-Atlantic Bight but changed in relation to local prey availability in the Bay of Biscay. 相似文献
364.
Eva Friis Møller Christian Marc Andersen Borg Sigrún H. Jónasdóttir Suree Satapoomin Cornelia Jaspers Torkel Gissel Nielsen 《Marine Biology》2011,158(3):677-688
The vertical distribution of copepods, fecal pellets and the fecal pellet production of copepods were measured at seven stations
across the Southern Indian Ocean from productive areas off South Africa to oligotrophic waters off Northern Australia during
October/November 2006. We quantified export of copepod fecal pellet from surface waters and how much was retained. Furthermore,
the potential impact of Oncaea spp. and harpacticoid copepods on fecal pellets degradation was evaluated and found to be regional substantial. The highest
copepod abundance and fecal pellet production was found in the western nutrient-rich stations close to South Africa and the
lowest at the central oligotrophic stations. The in situ copepod fecal pellet production varied between 1 and 1,000 μg C m−3 day−1. At all stations, the retention of fecal pellets in the upper 400 m of the water column was more than 99% and the vertical
export of fecal pellets was low (<0.02 mg m−2 day−1). 相似文献
365.
The present study provides the longest and most intensive plankton and larval fish seasonal variability analysis in the Canary
Islands and forms a basis for understanding life cycle scheduling and interactions among species, as well as the potential
variability in transport processes of early life stages. Larval fish assemblages were studied weekly at Gran Canaria Island,
Canary Islands, from January 2005 to June 2007, which represented two contrasting hydrological and biological periods. The
former year was characterized by lower temperature and salinity that increased through 2006 and 2007. In contrast, chlorophyll
concentration and mesozooplankton biomass decreased through the same period, especially when only the late winter bloom period
was evaluated. However, ichthyoplankton abundance did not exhibit any clear pattern, as larger values were observed during
2006. The larval fish community of this oceanic island, located near the NW African upwelling, was composed of both neritic
and oceanic taxa. Two families accounted for almost half of the collected larvae: Clupeidae (21.9%) and Myctophidae (20.5%).
Although total larval concentration did not exhibit any seasonal peak linked to changes in zooplankton, the ichthyoplankton
composition gradually changed during the year due to the high diversity and extended spawning periods of the fish species
represented in samples. “Winter” and “summer” larval assemblages were identified, corresponding to the mixing and stratification
periods of the water column, respectively. These assemblages were characterized by changes in the contribution of the most
abundant annual taxa (Sardinella aurita,
Cyclothone braueri, Ceratoscopelus spp. and Gobids) and by the presence of larvae of winter (Pagellus bogaraveo, Pomacentridae sp1) or summer spawners (Pomacentridae sp2, Trachinus draco, Arnoglossus thori, Tetraodontidae sp1). Upwelling filaments shed from the NW African coast reached the sampling area three times during this
study, but changes in the local larval community were only detected in August 2005. 相似文献
366.
Gustavo Ratto Fabián Videla J. Reyna Almandos Ricardo Maronna Daniel Schinca 《Environmental monitoring and assessment》2006,121(1-3):325-340
This article presents and discusses SO2 (ppbv) concentration measurements combined with meteorological data (mainly wind speed and direction) for a five-year campaign (1996 to 2000), in a site near an oil refinery plant close to the city of La Plata and surroundings (aprox. 740.000 inh.), considered one of the six most affected cities by air pollution in the country. Since there is no monitoring network in the area, the obtained results should be considered as medium term accumulated data that enables to determine trends by analyzing together gas concentrations and meteorological parameters. Preliminary characterization of the behaviour of the predominant winds of the region in relation with potential atmospheric gas pollutants from seasonal wind roses is possible to carry out from the data. These results are complemented with monthly averaged SO2 measurements. In particular, for year 2000, pollutant roses were determined which enable predictions about contamination emission sources. As a general result we can state that there is a clear increase in annual SO2 concentration and that the selected site should be considered as a key site for future survey monitoring network deployment. Annual SO2 average concentration and prevailing seasonal winds determined in this work, together with the potential health impact of SO2 reveals the need for a comprehensive and systematic study involving particulate matter an other basic pollutant gases. 相似文献
367.
San Vicente Bay is a coastal shallow embayment in Central Chile with multiple uses, one of which is receiving wastewater from
industrial fisheries, steel mill effluents, and domestic sewage. A simulation model was developed and applied to dissolved
oxygen consumption by organic residues released into this embayment. Three compartments were established as function of: depth,
circulation and outfall location. The model compartments had different volumes, and their oxygen saturation value was used
as baseline. The parameters: (a) BOD5 of the industrial and urban effluents, (b) oxygen demand by organic sediments, (c) respiration, (d) photosynthesis and (e)
re-aeration were included in the model. Iteration results of the model showed severe alterations in Compartment 1, with a
decrease of 65% in the oxygen below saturation. Compartment 2 showed a small decline (10%) and compartment 3 did not show
apparent changes in oxygen values. Measures recommended for remediation were to decrease the BOD5 loading by 30% in the affected sector. Iteration of the model for 200 h following recommendations derived from the preceding
results produced an increase in saturation of 60% (5 ml O2 L−1), which suggested an improvement of the environmental conditions. 相似文献
368.
Şebnem Elçi Ramazan Aydın Paul A. Work 《Environmental monitoring and assessment》2009,159(1-4):255-265
Acoustic Doppler current meters (ADV, ADCP, and ADP) are widely used in water systems to measure flow velocities and velocity profiles. Although these meters are designed for flow velocity measurements, they can also provide information defining the quantity of particulate matter in the water, after appropriate calibration. When an acoustic instrument is calibrated for a water system, no additional sensor is needed to measure suspended sediment concentration (SSC). This provides the simultaneous measurements of velocity and concentration required for most sediment transport studies. The performance of acoustic Doppler current meters for measuring SSC was investigated in different studies where signal-to-noise ratio (SNR) and suspended sediment concentration were related using different formulations. However, these studies were each limited to a single study site where neither the effect of particle size nor the effect of temperature was investigated. In this study, different parameters that affect the performance of an ADV for the prediction of SSC are investigated. In order to investigate the reliability of an ADV for SSC measurements in different environments, flow and SSC measurements were made in different streams located in the Aegean region of Turkey having different soil types. Soil samples were collected from all measuring stations and particle size analysis was conducted by mechanical means. Multivariate analysis was utilized to investigate the effect of soil type and water temperature on the measurements. Statistical analysis indicates that SNR readings ob tained from the ADV are affected by water temperature and particle size distribution of the soil, as expected, and a prediction model is presented relating SNR readings to SSC mea surements where both water temperature and sediment characteristics type are incorporated into the model. The coefficients of the suggested model were obtained using the multivariate anal ysis. Effect of high turbidity conditions on ADV performance was also investigated during and after rain events. 相似文献
369.
The addition of lipid wastes to the digestion of swine manure was studied as a means of increasing biogas production. Lipid waste was obtained from a biodiesel plant where used cooking oil is the feedstock. Digestion of this co-substrate was proposed as a way of valorising residual streams from the process of biodiesel production and to integrate the digestion process into the biorefinery concept.Batch digestion tests were performed at different co-digesting proportions obtaining as a result an increase in biogas production with the increase in the amount of co-substrate added to the mixture. Semi-continuous digestion was studied at a 7% (w/w) mass fraction of total solids. Co-digestion was successful at a hydraulic retention time (HRT) of 50 d but a decrease to 30 d resulted in a decrease in specific gas production and accumulation of volatile and long chain fatty acids. The CH4 yield obtained was 326 ± 46 l/kg VSfeed at an HRT of 50 d, while this value was reduced to 274 ± 43 l/kg VSfeed when evaluated at an HRT of 30 d. However these values were higher than the one obtained under batch conditions (266 ± 40 l/kg VSfeed), thus indicating the need of acclimation to the co-substrate. Despite of operating at low organic loading rate (OLR), measurements from respirometry assays of digestate samples (at an HRT of 50 d) suggested that the effluent could not be directly applied to the soil as fertiliser and might have a negative effect over soil or crops. 相似文献
370.
Assessment of patch quality by ladybirds: relative response to conspecific and heterospecific larval tracks a consequence of habitat similarity? 总被引:2,自引:0,他引:2
Alexandra Magro Joseph N. Téné Nicolas Bastin Anthony F. G. Dixon Jean-Louis Hemptinne 《Chemoecology》2007,17(1):37-45
Summary. Aphid colonies can reach high levels of abundance but last for short periods of time. The larvae of aphidophagous ladybirds
(Coleoptera: Coccinellidae) that feed on these colonies might therefore suffer from starvation, which favours the occurrence
of cannibalism and intraguild predation. Thus, the assessment of patch quality becomes crucial and it has been shown that
female ladybirds refrain from laying eggs in the presence of an oviposition deterring semiochemical deposited by their larvae.
Adalia bipunctata (L.), Adalia decempunctata (L.) and Coccinella septempunctata L. are 3 sympatric species of ladybirds, which can co-occur in aphid colonies. As a consequence, their eggs and larvae are
under threat, not only from cannibalism but also intraguild predation. Females should, therefore, also use the tracks deposited
by heterospecific larvae to assess the quality of aphid colonies as oviposition sites. The expectation is that: 1- the strength
of the reaction to each other’s larval tracks should be correlated with percentage habitat overlap and that 2- the reaction
to conspecific larval tracks should be stronger than to heterospecific tracks. In order to test these hypotheses, females’
oviposition behaviour was analysed and a chemical analysis of the tracks of their larvae undertaken.
The results show that oviposition behaviour is not related to habitat overlap. Both species of Adalia react to tracks of their own larvae and those of C. septempunctata, but A. decempunctata reacted more strongly than A. bipunctata. C. septempunctata reacted very slightly to its own tracks but not to those of either species of Adalia.
The larval tracks are mainly composed of alkanes. Those of the two species of Adalia are qualitatively 100% similar and 60% so when the quantitative results are compared. They are, however, only 24–29% similar
to those of Coccinella septempunctata. 相似文献