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551.
Helen K. French Sjoerd E.A.T.M. van der Zee 《Environmental science and pollution research international》2014,21(15):8897-8913
This paper gives an overview of management considerations required for better control of deicing chemicals in the unsaturated zone at sites with winter maintenance operations in cold regions. Degradable organic deicing chemicals are the main focus. The importance of the heterogeneity of both the infiltration process, due to frozen ground and snow melt including the contact between the melting snow cover and the soil, and unsaturated flow is emphasised. In this paper, the applicability of geophysical methods for characterising soil heterogeneity is considered, aimed at modelling and monitoring changes in contamination. To deal with heterogeneity, a stochastic modelling framework may be appropriate, emphasizing the more robust spatial and temporal moments. Examples of a combination of different field techniques for measuring subsoil properties and monitoring contaminants and integration through transport modelling are provided by the SoilCAM project and previous work. Commonly, the results of flow and contaminant fate modelling are quite detailed and complex and require post-processing before communication and advising stakeholders. The managers’ perspectives with respect to monitoring strategies and challenges still unresolved have been analysed with basis in experience with research collaboration with one of the case study sites, Oslo airport, Gardermoen, Norway. Both scientific challenges of monitoring subsoil contaminants in cold regions and the effective interaction between investigators and management are illustrated. 相似文献
552.
553.
Occurrence of glucocorticogenic activity in various surface waters in The Netherlands 总被引:1,自引:0,他引:1
Merijn Schriks Sander C. van der Linden Peter G.M. Stoks Bart van der Burg Leo Puijker Pim de Voogt Minne B. Heringa 《Chemosphere》2013
Considering the important role that surface waters serve for drinking water production, it is important to know if these resources are under the impact of contaminants. Apart from environmental pollutants such as pesticides, compounds such as (xeno)estrogens have received al lot of research attention and several large monitoring campaigns have been carried out to assess estrogenic contamination in the aquatic environment. The introduction of novel in vitro bioassays enables researchers to study if – and to what extent – water bodies are under the impact of less-studied (synthetic) hormone active compounds. The aim of the present study was to carry out an assessment on the presence and extent of glucocorticogenic activity in Dutch surface waters that serve as sources for drinking water production. The results show glucocorticogenic activity in the range of <LOD – 2.4 ng dexamethasone equivalents L−1 (dex EQs) in four out of eight surface waters. An exploratory time-series study to obtain a more complete picture of the yearly average of fluctuating glucocorticogenic activities at two sample locations demonstrated glucocorticogenic activities ranging between <LOD – 2.7 ng dex EQs L−1. Although immediate human health effects are unlikely, the environmental presence of glucocorticogenic compounds in the ng L−1 range compels further environmental research and assessment. 相似文献
554.
555.
Gustavsson L Hollert H Jonsson S van Bavel B Engwall M 《Environmental science and pollution research international》2007,14(3):202-211
Goal, Scope and Background Sweden has prohibited the deposition of organic waste since January, 2005. Since 1 million tons of sludge is produced every
year in Sweden and the capacity for incineration does not fill the demands, other methods of sludge management have to be
introduced to a larger degree. One common method in the USA and parts of Europe is the use of wetlands to treat wastewater
and sewage sludge. The capacity of reed beds to affect the toxicity of a complex mixture of nitroaromatics in sludge, however,
is not fully elucidated. In this study, an industrial sludge containing explosives and pharmaceutical residues was therefore
treated in artificial reed beds and the change in toxicity was studied. Nitroaromatic compounds, which are the main ingredients
of many pharmaceuticals and explosives, are well known to cause cytotoxicity and genotoxicity. Recently performed studies
have also showed that embryos of zebrafish (Danio rerio) are sensitive to nitroaromatic compounds. Therefore, we tested the sludge passing through constructed wetlands in order
to detect any changes in levels of embryotoxicity, genotoxicity and dioxin-like activity (AhR-agonists). We also compared
unplanted and planted systems in order to examine the impact of the root system on the fate of the toxicants.
Methods An industrial sludge containing a complex mixture of nitroaromatics was added daily to small-scale constructed wetlands (vertical
flow), both unplanted and planted with Phragmites australis. Sludge with an average dry weight of 1.25%, was added with an average hydraulic loading rate of 1.2 L/day. Outgoing water
was collected daily and stored at −20°C. The artificial wetland sediment was Soxhlet extracted, followed by clean-up with
multi-layer silica, or extracted by ultrasonic treatment, yielding one organic extract and one water extract of the same sample.
Genotoxicity of the extracts was measured according to the ISO protocol for the umu-C genotoxicity assay (ISO/TC 147/SC 5/WG9
N8), using Salmonella typhimurium TA1535/pSK1002 as test organism. Embryotoxicity and teratogenicity were studied using the fish egg assay with zebrafish (Danio rerio) and the dioxin-like activity was measured using the DR-CALUX assay. Chemical analyses of nitroaromatic compounds were performed
using Solid Phase Micro Extraction (SPME) and GC-MS.
Results Organic extracts of the bed material showed toxic potential in all three toxicity tests after two years of sludge loading.
There was a difference between the planted and the unplanted beds, where the toxicity of organic extracts overall was higher
in the bed material from the planted beds. The higher toxicity of the planted beds could have been caused by the higher levels
of total carbon in the planted beds, which binds organic toxicants, and by enrichment caused by lower volumes of outgoing
water from the planted beds.
Discussion Developmental disorders were observed in zebrafish exposed directly in contact to bed material from unplanted beds, but not
in fish exposed to bed material from planted beds. Hatching rates were slightly lower in zebrafish exposed to outgoing water
from unplanted beds than in embryos exposed to outgoing water from planted beds. Genotoxicity in the outgoing water was below
detection limit for both planted and unplanted beds. Most of the added toxicants via the sludge were unaccounted for in the
outgoing water, suggesting that the beds had toxicant removal potential, although the mechanisms behind this remain unknown.
Conclusions During the experimental period, the beds received a sludge volume (dry weight) of around three times their own volume. In
spite of this, the toxicity in the bed material was lower than in the sludge. Thus, the beds were probably able to actually
decrease the toxicity of the added, sludge-associated toxicants. When testing the acetone extracts of the bed material, the
planted bed showed a higher toxicity than the unplanted beds in all three toxicity tests. The toxicity of water extracts from
the unplanted beds, detected by the fish egg assay, were higher than the water extracts from the planted beds. No genotoxicity
was detected in outgoing water from either planted or unplanted beds. All this together indicates that the planted reed beds
retained semi-lipophilic acetone-soluble toxic compounds from the sludge better than the unplanted beds, which tended to leak
out more of the water soluble toxic compounds in the outgoing water. The compounds identified by SPME/GC in the outgoing water
were not in sufficient concentrations to have caused induction in the genotoxicity test.
Recommendations and Perspectives This study has pointed out the benefits of using constructed wetlands receiving an industrial sludge containing a complex
mixture of nitroaromatics to reduce toxicity in the outgoing water. The water from planted, constructed wetlands could therefore
be directed to a recipient without further cleaning. The bed material should be investigated over a longer period of time
in order to evaluate potential accumulation and leakage prior to proper usage or storage. The plants should be investigated
in order to examine uptake and possible release when the plant biomass is degraded.
This article has been developed on the basis of a presentation given at the Annual meeting of SETAC Europe German Language
Branch 2004 in Aachen.
ESS-Submission Editor: Dr. Ludek Blaha (blaha@recetox.muni.cz) 相似文献
556.
Vijver MG Vink JP Miermans CJ van Gestel CA 《Environmental pollution (Barking, Essex : 1987)》2007,148(1):132-140
The main factors contributing to variation in metal concentrations in earthworms inhabiting floodplain soils were investigated in three floodplains differing in inundation frequency and vegetation type. Metal concentrations in epigeic earthworms showed larger seasonal variations than endogeic earthworms. Variation in internal levels between sampling intervals were largest in earthworms from floodplain sites frequently inundated. High and low frequency flooding did not result in consistent changes in internal metal concentrations. Vegetation types of the floodplains did not affect metal levels in Lumbricus rubellus, except for internal Cd levels, which were positively related to the presence of organic litter. Internal levels of most essential metals were higher in spring. In general, no clear patterns in metal uptake were found and repetition of the sampling campaign will probably yield different results. 相似文献
557.
Anas Fauzi Andrew K. Skidmore Ignas M. A. Heitkönig Hein van Gils Martin Schlerf 《Environmental monitoring and assessment》2014,186(12):8487-8498
There is growing concern that increasing eutrophication causes degradation of coastal ecosystems. Studies in terrestrial ecosystems have shown that increasing the concentration of nitrogen in soils contributes to the acidification process, which leads to leaching of base cations. To test the effects of eutrophication on the availability of base cations in mangroves, we compared paired leaf and soil nutrient levels sampled in Nypa fruticans and Rhizophora spp. on a severely disturbed, i.e. nutrient loaded, site (Mahakam delta) with samples from an undisturbed, near-pristine site (Berau delta) in East Kalimantan, Indonesia. The findings indicate that under pristine conditions, the availability of base cations in mangrove soils is determined largely by salinity. Anthropogenic disturbances on the Mahakam site have resulted in eutrophication, which is related to lower levels of foliar and soil base cations. Path analysis suggests that increasing soil nitrogen reduces soil pH, which in turn reduces the levels of foliar and soil base cations in mangroves. 相似文献
558.
Geological CO2 capture and storage (CCS) is among the main near-term contenders for addressing the problem of global climate change. Even
in a baseline scenario, with no comprehensive international climate policy, a moderate level of CCS technology is expected
to be deployed, given the economic benefits associated with enhanced oil and gas recovery. With stringent climate change control,
CCS technologies will probably be installed on an industrial scale. Geologically stored CO2, however, may leak back to the atmosphere, which could render CCS ineffective as climate change reduction option. This article
presents a long-term energy scenario study for Europe, in which we assess the significance for climate policy making of leakage
of CO2 artificially stored in underground geological formations. A detailed sensitivity analysis is performed for the CO2 leakage rate with the bottom-up energy systems model MARKAL, enriched for this purpose with a large set of CO2 capture technologies (in the power sector, industry, and for the production of hydrogen) and storage options (among which
enhanced oil and gas recovery, enhanced coal bed methane recovery, depleted fossil fuel fields, and aquifers). Through a series
of model runs, we confirm that a leakage rate of 0.1%/year seems acceptable for CCS to constitute a meaningful climate change
mitigation option, whereas one of 1%/year is not. CCS is essentially no option to achieve CO2 emission reductions when the leakage rate is as high as 1%/year, so more reductions need to be achieved through the use of
renewables or nuclear power, or in sectors like industry and transport. We calculate that under strict climate control policy,
the cumulative captured and geologically stored CO2 by 2100 in the electricity sector, when the leakage rate is 0.1%/year, amounts to about 45,000 MtCO2. Only a little over 10,000 MtCO2 cumulative power-generation-related emissions are captured and stored underground by the end of the century when the leakage
rate is 1%/year. Overall marginal CO2 abatement costs increase from a few €/tCO2 today to well over 150 €/tCO2 in 2100, under an atmospheric CO2 concentration constraint of 550 ppmv. Carbon costs in 2100 turn out to be about 40 €/tCO2 higher when the annual leakage rate is 1%/year in comparison to when there is no CO2 leakage. Irrespective of whether CCS deployment is affected by gradual CO2 seepage, the annual welfare loss in Europe induced by the implementation of policies preventing “dangerous anthropogenic
interference with the climate system” (under our assumption, implying a climate stabilisation target of 550 ppmv CO2 concentration) remains below 0.5% of GDP during the entire century.
相似文献
Koen SmekensEmail: |
559.
A. Hollander M. Hauck I. T. Cousins M. A. J. Huijbregts A. Pistocchi A. M. J. Ragas D. van de Meent 《Environmental Modeling and Assessment》2012,17(6):577-587
Multimedia mass balance models differ in their treatment of spatial resolution from single boxes representing an entire region to multiple interconnected boxes with varying landscape properties and emission intensities. Here, model experiments were conducted to determine the relative importance of these two main factors that cause spatial variation in environmental chemical concentrations: spatial patterns in emission intensities and spatial differences in environmental conditions. In the model, experiments emissions were always to the air compartment. It was concluded that variation in emissions is in most cases the dominant source of variation in environmental concentrations. It was found, however, that variability in environmental conditions can strongly influence predicted concentrations in some cases, if the receptor compartments of interest are soil or water—for water concentrations particularly if a chemical has a high octanol–air partition coefficient (K oa). This information will help to determine the required level of spatial detail that suffices for a specific regulatory purpose. 相似文献
560.
de Leeuw Frank A. A. M. van Pul W. Addo J. van den Berg Frederik Gilbert Andrew J. 《Environmental monitoring and assessment》2000,62(2):133-145
In the evaluation of potentially adverse effects oforganic chemicals such as pesticides on theenvironment the atmosphere may play an important role.After its release to the atmosphere the chemical willbe transported/dispersed in the atmosphere and finallyit will be removed either by atmospheric-chemicaldestruction or by deposition to the underlying soil orsurface water. In a risk assessment decision supportsystem both ambient concentrations and depositionfluxes must be known to evaluate the risk of directexposure (inhalation) or the risk of soil and watercontamination caused by deposition. This paperdiscusses the use of atmospheric dispersion models insuch risk assessment decision support systems. 相似文献