DISTRIBUTION AND GRAIN-SIZE PARTITIONING OF METALS IN BOVFOM SEDIMENTS OF AN EXPERIMENTALLY ACIDIFIED WISCONSIN LAKE1

ABSTRACT: A study of concentrations and distribution of major and trace elements in surficial bottom sediments of Little Rock Lake in northern Wisconsin included examination of spatial variation and grain-size effects. No significant differences with respect to metal distribution in sediments were observed between the two basins of the lake, despite the experimental acidification of one of the basins from pH 6.1 to 4.6. The concentrations of most elements in the lake sediments were generally similar to soil concentrations in the area and were well below sediment quality criteria. Two exceptions were lead and zinc, whose concentrations in July 1990 exceeded the criteria of 50 μg/g and 100 μg/g, respectively, in both littoral and pelagic sediments. Concentrations of some elements, particularly Cu, Pb, and Zn, increased along transects from nearshore to midlake, following a similar gradient of sedimentary organic carbon. In contrast, Mn, Fe, and alkali/alkaline-earth elements were at maximum concentrations in nearshore sediments. These elements are less likely to partition to organic particles, and their distribution is more dependent on mineralogical composition, grain size, and other factors. Element concentrations varied among different sediment grain-size fractions, although a simple inverse relation to grain size was not observed. Fe, Mn, Pb, and Zn were more concentrated in a grain-size range 20–60 tm than in either the very fine or the coarse fractions, possibly because of the aggregation of smaller particles cemented together by organic and Fe/Mn hydrous-oxide coatings.     

THE SENSITWITY OF NORTHERN SIERRA NEVADA STREAMFLOW TO CLIMATE CHANGE1

ABSTRACT: The sensitivity of streamflow to climate change was investigated in the American, Carson, and Truckee River Basins, California and Nevada. Nine gaging stations were used to represent streamflow in the basins. Annual models were developed by regressing 1961–1991 streamflow data on temperature and precipitation. Climate-change scenarios were used as inputs to the models to determine streamflow sensitivities. Climate-change scenarios were generated from historical time series by modifying mean temperatures by a range of +4°C to—4°C and total precipitation by a range of +25 percent to -25 percent. Results show that streamflow on the warmer, lower west side of the Sierra Nevada generally is more sensitive to temperature and precipitation changes than is streamflow on the colder, higher east side. A 2°C rise in temperature and a 25-percent decrease in precipitation results in stream-flow decreases of 56 percent on the American River and 25 percent on the Carson River. A 2°C decline in temperature and a 25-percent increase in precipitation results in streamflow increases of 102 percent on the American River and 22 percent on the Carson River.     

Screening method for locating groundwater monitoring wells

The traditional approach to characterizing the extent of groundwater contamination is often phased over a period of several years. A screening method has been developed that allows the investigation process to be reduced to a single phase. Existing data are used to develop a preliminary estimate of the extent of contamination, which is refined by the screening method using groundwater data collected and analyzed in the field. The screening method is applicable at sites with volatile organic compound contamination. Groundwater samples are collected using direct push or drill rig assisted methods, and the groundwater headspace gas is analyzed for the contaminant of interest. The refined estimate is used to locate all of the groundwater monitoring wells necessary to finalize the estimate of the extent of contamination. Therefore, only one investigation phase is required, and time and cost savings are realized with respect to the traditional multiphase approach. The screening method was successfully applied at a CERCLA site in Nebraska with two distinct plumes of TCE-contaminated groundwater. The Nebraska remedial investigation was completed approximately 18 months earlier than the estimated completion of a comparable phased investigation, with a corresponding cost reduction estimated at approximately 10 percent. If data from the screening method were used instead of data from monitoring wells, the estimated cost savings would be over 50 percent. Additional applications and evaluations may lead to industry and regulatory acceptance of the method as a primary characterization tool.     

Development of a Computer Workstation for Famine Early Warning and Food Security

Beginning in 1990, the University of Arizona, Arizona Remote Sensing Center (ARSC) has been involved in a collaborative effort with the Global Information and Early Warning System (GIEWS) and the Remote Sensing Center of the Food and Agriculture Organization (FAO) of the United Nations in designing and developing an integrated computer workstation for famine early warning. The goal of the project is to provide food security analysts with a set of computer tools to manage a very large and diverse set of data for predicting the onset of food security emergencies for every country on Earth. The initial stage of the project involved the conceptual definition of system elements and the development of overall system architecture. We are now developing an open, flexible, and portable system designed to significantly assist the work of the analysts. System architecture provides a task-specific and user-friendly graphic user interface (GUI) within a Windows environment that will link image processing, geographic information system (GIS), spreadsheet, text, and graphics software packages into a single operational environment. A relational database management system (RDBMS) is serving as the back-end of the workstation to facilitate data storage and retrieval and as a means to preserve analysis methodologies.     

Ecologically derived guidelines for managing two New Zealand lakes

Lakes Manapouri and Te Anau, in Fiordland National Park, became the center of a major controversy after the New Zealand government offered their water resource to an overseas aluminum smelting consortium for electricity generation. Although the scheme proceeded, the lake levels were not raised as originally proposed. Rather, government sought guidelines to optimize hydroelectric potential while maintaining ecological stability of the vulnerable, largely forested, glaciated lakeshores. Guidelines were derived by relating the vegetation zonation to the natural lake-level fluctuations recorded daily for 37 years. Ahigh operating range in the upper third of the lakes' natural ranges, based on flood tolerances of the woody shoreline species, restricts both duration and frequency. Alow operating range (ca. lower third) safeguards stability of shoreline sediments by limiting drawn-down rates, duration, and frequency. Themain operating range (ca. middle third) has few limitations. These guidelines, which allow utilization of ca. 93% of the water resource, have now been verified by instances of flooding and draw-down rates that exceeded the natural rates recorded earlier. The guidelines were officially accepted by the government in 1977 as a basis for managing the valuable multiple resources of these two lakes and their environs, and they were formalized in legislation in 1981. The details and merits of the guideline approach are discussed.     

Impact of right-of-way construction on vegetation in the Red Lake Peatland,northern Minnesota

During the winters of 1978–79 and 1979–80, a 500-kV electrical transmission right-of-way (r-o-w) was constructed across the Red Lake Peatland in northwestern Minnesota, the largest contiguous peatland in the lower 48 states of the USA. Immediately before, and for two years following construction, vascular vegetation was monitored within the r-o-w and in undisturbed control areas. Monitoring was carried out in five vegetation types: a thicket swamp, a low shrub bog, a graminoid fen, a treed bog, and a treed fen. Evaluation of construction impacts was based on vegetation structure, irrespective of species composition, and on community composition (species data for low shrubs and herbs). Construction eliminated trees from the r-o-w. Vegetation structure, excluding trees, was markedly altered in the two bog types and the treed fen type in the first postconstruction growing season. By the second season, measurable recovery to control levels had begun. The sample plots were placed into a previously developed vegetation classification system for the Red Lake Peatland, on the basis of herbs and low shrubs. There was a shift in composition in the low shrub bog and in the treed vegetation types following construction. Results of both methods of data analysis were consistent. Major vegetation changes following construction occurred in the low shrub bog and treed types. The open, low-stature fen types showed almost no changes related to construction. Even in the affected types, all vegetation strata except trees were returning to their preconstruction status by the second growing season following construction.     

The Worldwide Availability of Phosphate Rock

The US Bureau of Mines has investigated the resource potential of 201 phosphate mines and depositee in 28 market economy countries and 17 mines and deposits in the USSR and China. The 201 mines and deposits contain an estimated 34.2 billiong tonnes (t) of recoverable phosphate rock (at the demonstrated resource level), with Morocco and Western Sahara accounting for 61% (21 billion t) and with the USA accounting for 19% (6.4 billion t). The 17 mines and deposits evaluated in the USSR and China contain approximately 1.5 billion t of potentially recoverable phosphate rock. Potential annual capacity from low-cost, high-grade producing mines in the USA is estimated to decline significantly during the latter half of the next decade, and the US phosphate fertilizer industry will have to obtain phosphate rock by developing new, higher-cost, lower-grade mines or import phosphate rock to satisfy anticipated demand in the next century. Of the world's new production capacity that are likely to be developed over the next decade, slightly over one-third could be produced at an estimated 1981 cost of $40/t or less, and about two-thirds would cost in the $40 to $50 per tonne range (including a 15% rate of return). In comparison, most of the competing phosphate rock from producing mines in Morocco could be produced for less than $40/t.     

ON THE USE OF SEEPAGE METERS TO ESTIMATE GROUNDWATER NUTRIENT LOADING TO LAKES1

Data from a study on East Lake Tohopekaliga, Florida, indicate that the seepage meter measurement method may often overestimate nutrient contributions to lakes. Nutrient loading data from this method and a method employing lakeside piezometer nutrient data and seepage meter flows were not comparable. Seepage nutrient loading from the meter and piezometer methods comprised 39 and 18 percent of the nitrogen budget and 38 and 9 percent of the phosphorus budget, respectively, for East Lake Tohopekaliga. In terms of water, groundwater seepage accounted for only 14 percent of the total input to the lake. It is felt that some of the past studies using the seepage meter method to estimate nutrient loading may be in error due to reasons related to the enclosure of lake sediments by the meter and the accompanying anaerobic conditions which quickly result.