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861.
Five aromatic hydrocarbons (benzene, toluene, and three isomeric xylenes) were monitored in indoor and outdoor air of 7 public buildings and 54 private homes, located in Barcelona City metropolitan area and in several rural areas of Catalonia. The sampling was carried out over four periods: spring-summer and winter of 2000, and summer and winter of 2001. Passive ORSA 5 Dra¨ger samplers were used for benzene, toluene, and xylenes (BTX) adsorption. BTX were extracted with carbon disulphide and analysed using ... 相似文献
862.
A bacterium classified as Achromobacter xylosoxidans strain IR08 by phenotypic typing coupled with 16S rRNA gene analysis was isolated from a soil contaminated with electrical transformer ?uid for over sixty years using Aroclor 1221 as an enrichment substrate. The substrate utilization profiles revealed that IR08 could grow on all three monochlorobiphenyls (CBs), 2,4'- and 4,4'-dichlorobiphenyl as well as 2-chlorobenzoate (2-CBA), 3-CBA, 4-CBA, and 2,3-dichlorobenzoate. Unusually, growth was poorly sustaine... 相似文献
863.
Ryan L. Fimmen Tamara D. Trouts Daniel D. Richter Jr. Dharni Vasudevan 《环境科学学报(英文版)》2008,20(10):1273-1280
The objective of this study was to improve primary-amine nitrogen (1°-N) quantification in dissolved organic matter (DOM) originating from natural waters where inorganic forms of N, which may cause analytical interference, are commonly encountered. Efforts were targeted at elucidating organic-N structural criteria influencing the response of organic amines to known colorimetric and fluorescent reagents and exploring the use of divalent metal-assisted amide hydrolysis in combination with fluorescence analyse... 相似文献
864.
Numerical study on the ozone formation inside street canyons using a
chemistry box model 总被引:1,自引:1,他引:0
Tropospheric ozone is a secondary air pollutant produced in the presence of nitrogen oxides (NO_x),volatile organic compounds (VOCs),and solar radiation.In an urban environment,ground-level vehicular exhaust is the major anthropogenic source of ozone precursors.In the cases of street canyons,pollutant dilution is weakened by the surrounding buildings that creates localized high concentration of NO_x and VOCs,and thus leads to high potential of ozone formation.By considering the major physical and chemica... 相似文献
865.
概述 人们应该如何评估国家和个人的福利,即"幸福水平"呢?关于这个问题的答案对于国家甚至国际发展政策的制定至关重要,因为这些政策都清楚地将"变得更好"作为目标.勿庸置疑,如何衡量"更好"就成为了一个关键问题. 相似文献
866.
为了解可吸入颗粒物污染水平与气象因素之间的关系,从2008年9月—2010年2月采集乌鲁木齐市可吸入颗粒物样品,并对其随时间的变化特征及其与气象因素之间的相关性进行了统计分析。结果表明,采样时间内可吸入颗粒物中PM2.5和PM2.5-10的质量浓度的范围分别为38.2~468.7μg/m3和20.8~243.1μg/m3,平均浓度分别为134.2μg/m3和69.2μg/m3。可吸入颗粒物同时受几种气象因素的影响,其浓度与温度、能见度、风速呈负相关,与湿度呈正相关。 相似文献
867.
基于GIS的上海浦东暴雨内涝灾害脆弱性研究 总被引:4,自引:0,他引:4
随着全球气候变化和城市化进程的加速发展,城市暴雨洪涝灾害的频度和强度不断加强。灾害脆弱性研究是当前灾害研究的热点,基于灾损率的脆弱性分析方法是当前灾害脆弱性研究的重要课题点与前沿。采用G IS和遥感技术,依据20年、50年、100年、200年、500年、1000年一遇的6个重现期情景,对上海浦东新区开展了基于灾损曲线的脆弱性研究。研究中修正了上海地区的径流模型,基于G IS栅格编制了不同重现期的淹没深度图,实地调查了研究区暴雨内涝灾害的灾损率数据,确定了研究区的脆弱性等级划分,并利用G IS编制了基于不同重现期情景的上海浦东脆弱性图。研究中提出的方法对于沿海城市开展暴雨内涝等自然灾害脆弱性研究具有借鉴意义,研究结果可供区域灾害风险评估和防灾减灾规划参考。 相似文献
868.
Bryan Butter Paola Santander Guadalupe del C. Pizarro Diego P. Oyarzún Federico Tasc Julio Sánchez 《环境科学学报(英文版)》2021,33(3):304-312
Chromium (Cr) is used in many manufacturing processes, and its release into natural waters is a major environmental problem today. Low concentrations of Cr(VI) are toxic to human health and living organisms due to the carcinogenic and mutagenic nature of this mineral. This work examined the conversion of Cr(VI) to Cr(III) via electrochemical reduction using gold electrode in an acidic sodium alginate (SA) solution and subsequent removal of the produced Cr(III)-SA by the polymer-enhanced ultrafiltration (PEUF) technique. A solution of SA in nitric acid was used both as an electrolytic medium during the voltammetric measurements and bulk electrolysis and as an extracting agent during the PEUF technique. The electroanalysis of Cr(VI) was performed by linear sweep voltammetry in the presence of acidic SA solution to study its voltammetric behavior as a function of the Cr(VI) concentration, pH, presence of Cr(III), SA concentration and scan rate. In addition, the quantitative reduction of Cr(VI) to Cr(III) was studied through the bulk electrolysis technique.The results showed efficient reduction with well-defined peaks at approximately 0.3 V vs. Ag/AgCl, using a gold working electrode. As the pH increased, the reduction signal strongly decreased until its disappearance. The optimum SA concentration was 10 mmol/L, and it was observed that the presence of Cr(III) did not interfere in the Cr(VI) electroanalysis. Through the quantitative reduction by bulk electrolysis in the presence of acidic SA solution, it was possible to reduce all Cr(VI) to Cr(III) followed by its removal via PEUF. 相似文献
869.
Olga S. Arvaniti Marilena E. Dasenaki Alexandros G. Asimakopoulos Niki C. Maragou Vasilios G. Samaras Korina Antoniou Georgia Gatidou Daniel Mamais Constantinos Noutsopoulos Zacharias Frontistis Nikolaos S. Thomaidis Athanasios S. Stasinakis 《Frontiers of Environmental Science & Engineering》2022,16(11):148
870.
Chen Xing Daihui Yang Yan Zhang Tian Sun Junfei Duan Hussein A.Younus Shiguo Zhang 《绿色能源与环境(英文)》2022,7(1):43-52
Heteroatom-doped meso/micro-porous carbon materials are conventionally produced by harsh carbonization under an inert atmosphere involving specific precursors, hard/soft templates, and heteroatom-containing agents. Herein, we report a facile synthesis of N and O co-doped meso/micro-porous carbon (NOMC) by template-free carbonization of a small-molecule precursor in a semi-closed system. The semi-closed carbonizaiton process yields hydrophilic NOMCs with large surface area in a high yield. The porous structure as well as the elemental composition of NOMCs can be modulated by changing the holding time at a particular temperature. NOMCs as metal-free heterogeneous catalysts can selectively oxidize benzyl alcohol and its derivatives into aldehydes/ketones with>85%conversion in aqueous solution, which is much higher than that of the control sample obtained in tube furnace (21%conversion), mainly due to their high N content, high percentage of pyridinic N, and large surface area. The presence of O-containing moieties also helps to improve the hydrophilicity and dispersion ability of catalysts and thus facilitates the mass transfer process during aqueous oxidation. The NOMC catalysts also dispayed excellent activity for a wide range of substrates with a selectivity of>99%. 相似文献