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911.
912.
913.
M. Asim M. Jawaid K. Abdan M. R. Ishak 《Journal of Polymers and the Environment》2018,26(4):1520-1527
The aim of the present study is to investigate mechanical and morphological properties of pineapple leaf fibres (PALF) reinforced phenolic composites and its comparison with kenaf fibre (KF)/phenolic composites. Mechanical properties (tensile, flexural and impact) of untreated and treated PALF phenolic composites at different fibre loading were investigated. Tensile, flexural and impact properties of PALF and kenaf/phenolic composites were analyzed as per ASTM standard. Morphological analysis of tensile fracture samples of composites was carried out by scanning electron microscopy. Obtained results indicated that treated PALF/phenolic composites at 50% PALF loading exhibited better tensile, flexural and impact properties as compared to other untreated PALF/phenolic composites. Treated kenaf/phenolic composites at 50% fibre loading showed better tensile, flexural and impact properties than untreated kenaf/phenolic composite. It is concluded that treated 50% fibre loading kenaf and PALF/phenolic composites showed better mechanical properties than untreated kenaf and PALF/phenolic composites due to good fibre/matrix interfacial bonding. Results obtained in this study will be used for the further study on hybridization of PALF and KF based phenolic composites. 相似文献
914.
Rushdya R. A. Hassan Maisa M. A. Mansour 《Journal of Polymers and the Environment》2018,26(7):2698-2707
The current study is interested in evaluating the decay of cotton, Whatman and chemical pulp caused by Trichoderma harzianum and Paecilomyces variotii. The structural changes of the paper were evaluated by Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM). The SEM results show differences in hyphae colonization and paper decay patterns between studied species under the current study; P. variotii caused an eroded structure in the cotton (cavity forming), whereas the initial T. harzianum colonization produced rupture and erosion (soft-rot decay type II) for the three types of paper ,the gaps were elongated with sharp pointed ends, which consisted either of individual cavities or in chains. Moreover, FTIR results confirmed that there a relationship could be observed between fungal decay and crystalline cellulose content because the intensity of peaks at 1335 and 1111 cm?1 significantly decreased due to the fungal decay. Furthermore, the intensity of O–H stretching absorption slightly decreased, and this may be attributed to hydrolysis of cellulose molecules. 相似文献
915.
Marijana Ponjavic Marija S. Nikolic Sanja Jeremic Lidija Djokic Jasmina Nikodinovic-Runic Vladan R. Cosovic Jasna Djonlagic 《Journal of Polymers and the Environment》2018,26(6):2346-2359
Hydrolytic, enzymatic degradation and composting under controlled conditions of series of triblock PCL/PEO copolymers, PCEC, with central short PEO block (M n 400 g/mol) are presented and compared with homopolymer (PCL). The PCEC copolymers, synthesized via ring-opening polymerization of ε-caprolactone, were characterized by 1H NMR, quantitative 13C NMR, GPC, DSC and WAXS. The introduction of the PEO central segment (<?2 wt%) in PCL chains significantly affected thermal degradation and crystallization behavior, while the hydrophobicity was slightly reduced as confirmed by water absorption and moisture uptake experiments. Hydrolytic degradation studies in phosphate buffer after 8 weeks indicated a small weight loss, while FTIR analysis detected changes in crystallinity indexes and GPC measurements revealed bulk degradation. Enzymatic degradation tested by cell-free extracts containing Pseudomonas aeruginosa PAO1 confirmed high enzyme activity throughout the surface causing morphological changes detected by optical microscopy and AFM analysis. The changes in roughness of polymer films revealed surface erosion mechanism of enzymatic degradation. Copolymer with the highest content of PEO segment and the lowest molecular weight showed better degradation ability compared to PCL and other copolymers. Furthermore, composting of polymer films in a model compost system at 37 °C resulted in significant degradation of the all synthesized block copolymers. 相似文献
916.
Modolo R. C. E. Senff L. Ferreira V. M. Tarelho L. A. C. Moraes C. A. M. 《Journal of Material Cycles and Waste Management》2018,20(2):1006-1015
Journal of Material Cycles and Waste Management - Several types of industrial solid waste have been used as byproducts in the construction and materials industries. Some of the applications seem to... 相似文献
917.
Safar Korai M. Bux Mahar R. Aslam Uqaili M. 《Journal of Material Cycles and Waste Management》2018,20(2):1239-1247
Journal of Material Cycles and Waste Management - Power generation from municipal solid waste plays significant role to mitigate the environmental pollution. The power generation potential of... 相似文献
918.
Luiz F. Maldonado Pablo A. R. Muñoz Guilhermino J. M. Fechine 《Journal of Polymers and the Environment》2018,26(8):3187-3196
Here, the influence of graphene as a coating on the biodegradation process for two different polymers is investigated, poly(butylene adipate-co-terephthalate) (PBAT) (biodegradable) and low-density polyethylene (LDPE) (non-biodegradable). Chemical vapor deposition graphene was transferred to the surface of two types of polymers using the Direct Dry Transfer technique. Polymer films, coated and uncoated with graphene, were buried in a maturated soil for up to 180 days. The films were analyzed before and after exposure to microorganisms in order to obtain information about the integrity of the graphene (Raman Spectroscopy), the biodegradation mechanism of the polymer (molecular weight and loss of weight), and surface changes of the films (atomic force microscopy and contact angle). The results prove that the graphene coating acted as a material to control the biodegradation process the PBAT underwent, while the LDPE covered by graphene only had changes in the surface properties of the film due to the accumulation of solid particles. Polymer films coated with graphene may allow the production of a material that can control the microbiological degradation, opening new possibilities in biodegradable polymer packaging. Regarding the possibility of graphene functionalization, the coating can also be selective for specific microorganisms attached to the surface. 相似文献
919.
Applying Statistical Causal Analyses to Agricultural Conservation: A Case Study Examining P Loss Impacts
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Song S. Qian R. Daren Harmel 《Journal of the American Water Resources Association》2016,52(1):198-208
Estimating the effect of agricultural conservation practices on reducing nutrient loss using observational data can be confounded by factors such as differing crop types and management practices. As we may not have the full knowledge of these confounding factors, conventional statistical meta‐analysis methods can be misleading. We discuss the use of two statistical causal analysis methods for quantifying the effects of water and soil conservation practices in reducing P loss from agricultural fields. With the propensity score method, a subset of data was used to form a treatment group and a control group with similar distributions of confounding factors. With the multilevel modeling method, data were stratified based on important confounding factors, and the conservation practice effect was evaluated for each stratum. Both methods resulted in similar estimates of the conservation practice effect (total P load reduction avg. ~70%). In addition, both methods show evidence of conservation practices reducing the incremental increase in total P export per unit increase in fertilizer application. These results are presented as examples of the types of outcomes provided by statistical causal analyses, not to provide definitive estimates of P loss reduction. The enhanced meta‐analysis methods presented within are applicable for improved assessment of agricultural practices and their effects and can be used for providing realistic parameter values for watershed‐scale modeling. 相似文献
920.
Augmenting Watershed Model Calibration with Incorporation of Ancillary Data Sources and Qualitative Soft Data Sources
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Haw Yen Michael J. White James C. Ascough II Douglas R. Smith Jeffrey G. Arnold 《Journal of the American Water Resources Association》2016,52(3):788-798
Watershed simulation models such as the Soil & Water Assessment Tool (SWAT) can be calibrated using “hard data” such as temporal streamflow observations; however, users may find upon examination of model outputs, that the calibrated models may not reflect actual watershed behavior. Thus, it is often advantageous to use “soft data” (i.e., qualitative knowledge such as expected denitrification rates that observed time series do not typically exist) to ensure that the calibrated model is representative of the real world. The primary objective of this study is to evaluate the efficacy of coupling SWAT‐Check (a post‐evaluation framework for SWAT outputs) and IPEAT‐SD (Integrated Parameter Estimation and Uncertainty Analysis Tool‐Soft & hard Data evaluation) to constrain the bounds of soft data during SWAT auto‐calibration. IPEAT‐SD integrates 59 soft data variables to ensure SWAT does not violate physical processes known to occur in watersheds. IPEAT‐SD was evaluated for two case studies where soft data such as denitrification rate, nitrate attributed from subsurface flow to total discharge ratio, and total sediment loading were used to conduct model calibration. Results indicated that SWAT model outputs may not satisfy reasonable soft data responses without providing pre‐defined bounds. IPEAT‐SD provides an efficient and rigorous framework for users to conduct future studies while considering both soft data and traditional hard information measures in watershed modeling. 相似文献