Unexpected difference in phenol sorption on PTMA- and BTMA-bentonite

The comparison of phenol sorption on phenyltrimethylammonium (PTMA)- and benzyltrimethylammonium (BTMA)-bentonite shows a clear difference as far as phenol sorption isotherms are concerned. For PTMA-bentonite the sorption isotherm is of a straight-line character which results from simple partitioning of phenol between the aqueous and organic phases sorbed on the bentonite surface. For BTMA-bentonite the isotherm has a convex shape, characteristic of physicochemical sorption.For the first time a three-parametric model, including the dissociation constant of phenol pK_a, distribution constant of phenol Kd_phen and phenolate anion Kd_phen⁻ between the aqueous phase and the bentonite phases is used for the evaluation of phenol sorption on organoclays with pH change. The model shows that the values of Kd_phen are higher than those of Kd_phen⁻ for all investigated initial phenol concentrations.The inspection of the FTIR spectrum of BTMA-bentonite loaded with phenol in the regions 1300–1600 and 1620–1680 cm⁻¹ shows the features of π–π electron interaction between the benzene rings of phenol and the BTMA cation together with the phenol–water hydrogen bond strengthened by this interaction.     

Studies on reactions of ozone with alkenes

In the last years, a continuous increase of the O3 concentration has been recorded in the lower atmospheric layers. Photochemical reactions with NO(x), CO and organic compounds are the main sources of O3 in the troposphere. In this work, an attempt was made to determine the impact of alkenes on the O3 concentration in the troposphere. A study on the gas-phase reactions of 03 with 1-hexene, 1-heptene and 1-nonene was made. The reactions were carried out at room temperature under atmospheric pressure. Ozone was formed by the ultraviolet radiation emitted by a mercury lamp, in order to simulate the atmospheric conditions. The changes with time in the concentration of O3, 1-alkenes and formed aldehydes were investigated. Qualitative and quantitative analyses were done by means of the gas chromatography and colorimetry. The following products were identified: pentanal from 1-hexene; hexanal from 1-heptene; oktanal from 1-nonene. For each of the reactions, HCHO was also determined as a product. The reaction rate constants were calculated and obtained in units of 10(-17) cm(-3) molecule(-1) s(-1): 1.94-0.99 for 1-hexene, 5.54-4.51 for 1-heptene and 1.54-0.76 for 1-nonene. Based on the results obtained, an explanation of O3 concentration variations in the planetary boundary layer can be given. Last year a considerable increase of O3 concentration on the roads of Western Europe was recorded. This increase could have resulted from the decrease of alkene concentration in the air due to common use of the catalytic converters in cars. The unsaturated hydrocarbons rapidly oxidize on the catalyst. In Eastern Europe, where the amount of cars equipped with catalytic converters is smaller than in Western Europe, the alkene content in the exhaust fumes results in a decrease of the O3 concentration in the troposphere.     

Spent sulfuric acid plant catalyst: valuable resource of vanadium or risky residue? Process comparison for environmental implications

Environmental Science and Pollution Research - The enormous amount of spent catalysts generated worldwide may pose a risk to the environment because of their high load of metals, including...     

Legacies,socio-economic and biophysical processes and drivers: the case of future forest cover expansion in the Polish Carpathians and Swiss Alps

Mountain forest areas are key for providing a wide range of ecosystem services and are hot spots for land use change processes, in particular, increase in forest cover at the expense of mountain pastures and meadows. Mountain forest systems in eastern and western Europe have likely similar future socio-economic situations but significantly different socio-economic history. Using a scenario-based land use modelling approach (Dyna-CLUE framework) we model three scenarios (trend, liberalisation and self-sufficiency) of future land use in the Polish Carpathians and the Swiss Alps, focussing on forest cover change. We find that forest cover increase can be expected to continue in European mountainous regions under all likely scenarios, limited only by relatively strict policy interventions. Biophysical factors, rather than socio-economic ones, are key for defining the suitability for, and therefore likely locations of future forest cover, but land use legacy plays a very important role in the spatial patterns of future forest cover, particularly in eastern Europe.

     

Discrete and time-integrated sampling for chromium load calculations in a watershed with an impoundment reservoir at an exceptionally low water level

Instantaneous (discrete) and time-integrated (composed) samples were collected during a 19-week period in a watershed impacted by discontinuous discharges from local tanneries (Carpathians Mountains, Poland). Existence of the impoundment reservoir in this watershed allowed investigation of its role in chromium transport. In collected samples, dissolved and particulate chromium concentrations were measured to apportion both loads. This study has demonstrated that the impoundment reservoir retains not only particulate but also a dissolved form of chromium and its efficiency reaches 74–94 %. Sampling results proved that chromium contamination in the investigated river is variable and discontinuous. Discrete sampling can lead to an underestimation of chromium contamination level (up to 78 %), especially when illegal/unexpected discharges occur in the watershed. A discrete sampling regime also produces less reliable data for contaminant budget calculations, especially in sites where strong variability of contamination is anticipated, while at the output from reservoirs, the load can be reasonably estimated using this mode of sampling.     

White rot fungi can be a promising tool for removal of bisphenol A,bisphenol S,and nonylphenol from wastewater

Environmental Science and Pollution Research - Endocrine-disrupting chemicals (EDC) are a wide group of chemicals that interfere with the endocrine system. Their similarity to natural steroid...     

Decreasing the hazardous effect of waste quartz powder and the toxicity of epoxy resin by its synergistic application in industrial coatings

Environmental Science and Pollution Research - Quartz powder sourced from industrial wastes is very hazardous. It is because it contains large amounts of fine particles. Thus, it has the potential...     

Regional challenges in tourist wetland systems: an integrated approach to the Ria Formosa in the Algarve, Portugal

Coastal change and coastal erosion have been a long-existing source of environmental changes. Traditionally, regional changes in wetland systems and their relations to agriculture, industry and urbanization are a major cause for concern. Nowadays, coastal distress has reached even global proportions: the problems of coastal change are strongly linked to the loss of fragile ecosystems, eutrophication and loss of biodiversity. Given that over 70 % of all human activity is in coastal areas, it is clear that many environmental and socio-economic changes occur at a local level and manifest themselves in a spatial context. The physical effect on the geographic morphology is evident in the related consequences for land use. A deep understanding of the changes in land use, and simultaneously in coastal erosion, calls for the integrated monitoring of the most relevant effects in fragile regions. The Ria Formosa wetland system is a unique and very special wetland system in the Algarve (Portugal) and has been integrated in the NATURA 2000 network. The strong symbiosis between nature, agriculture and fisheries, as well as tourism, in the Algarve has led to spatial-ecological synergy. By using coastal recession analysis techniques by means of remote-sensed imagery from 1987, 1989, 2000 and 2007 and by combining this information with available data sets on surface erodibility, a cost surface on multitemporal transitions of land-use classes from the CORINE Land Cover data allows us to assess and integrate a decision-making framework by means of GIS. The novelty of this combined approach to land-use management is the blend of spatial analysis and remote-sensing techniques that share important information on ecosystems at risk. Our findings suggest a growing concern to the area brought by anthropogenic activity. This is studied to a spatial accounting of the distribution of land changes and transitions, where (1) a significant loss of coastal area is witnessed along the Ria Formosa, leading in particular to loss of agricultural land. (2) This loss is underpinned by an increase in leisure facilities to respond to the tourism demand of the region of the Algarve, while landscape metrics suggest that these areas are more volatile for coastal erosion. (3) Simulation through Markov chains on the land use and effects of urban, agricultural, forest and wetland dynamics suggests that by 2026, it is expected to continue to have an increase in urban land, leading to an augmented vulnerability of coastal erosion processes brought by the loss of forest areas which protect from erosion given the root system that directly protects from the existing wave energy and helps sedimentation processes. The above methodology and the availability of data that are freely available render such a combined approach interesting for many other regions of the world, where tourism, coastal change and regional balance are of the utmost importance for sustainable development. The advanced research tools presented here are of critical importance for coastal zone degradation management.