全文获取类型
收费全文 | 746篇 |
免费 | 115篇 |
国内免费 | 243篇 |
专业分类
安全科学 | 133篇 |
废物处理 | 26篇 |
环保管理 | 76篇 |
综合类 | 553篇 |
基础理论 | 126篇 |
污染及防治 | 60篇 |
评价与监测 | 64篇 |
社会与环境 | 36篇 |
灾害及防治 | 30篇 |
出版年
2024年 | 6篇 |
2023年 | 26篇 |
2022年 | 56篇 |
2021年 | 63篇 |
2020年 | 45篇 |
2019年 | 43篇 |
2018年 | 61篇 |
2017年 | 49篇 |
2016年 | 54篇 |
2015年 | 60篇 |
2014年 | 54篇 |
2013年 | 64篇 |
2012年 | 57篇 |
2011年 | 64篇 |
2010年 | 67篇 |
2009年 | 62篇 |
2008年 | 50篇 |
2007年 | 36篇 |
2006年 | 39篇 |
2005年 | 33篇 |
2004年 | 24篇 |
2003年 | 19篇 |
2002年 | 20篇 |
2001年 | 13篇 |
2000年 | 11篇 |
1999年 | 8篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1963年 | 1篇 |
排序方式: 共有1104条查询结果,搜索用时 15 毫秒
241.
242.
Md. Musfiqur Rahman Tae Woong Na A. M. Abd El-Aty Jong-Hyouk Park M. N. U. Al Mahmud Angel Yang Ki Hun Park Jae-Han Shim 《Environmental monitoring and assessment》2013,185(11):9461-9469
The pre-harvest residue limit (PHRL) of abamectin (abamectin B1a and B1b) in Perilla frutescens leaves grown under greenhouse conditions were investigated using high-performance liquid chromatography with a fluorescence detector. Samples were extracted with acetonitrile. The extract was purified through a solid phase extraction procedure. Then the purified extract was derivatized with trifluoroacetic anhydride and N-methylimidazole to form a strong stable fluorescent derivative of abamectin. Finally, derivatized abamectins were conveyed to the detector via an Atlantis C18 column, with water and methanol as a mobile phase. Calibration curves were linear over the calibration ranges with coefficients of determinants r 2?≥?0.999. The limits of detection and quantification were 0.0033 and 0.01 mg kg?1 for abamectin B1a and B1b, respectively. Recovery was assessed in a control matrix at two different fortification concentrations, with three replicates for each concentration. Good recoveries were obtained for the target analytes and ranged from 82.11 to 93.03 %, with relative standard deviations of less than 8 %. The rate of disappearance of total abamectin on perilla leaves for recommended and double the recommended doses was described as first-order kinetics with a half-life of 0.7 days. Using the PHRL curve, we could predict the residue level of total abamectin to be 0.92 mg kg?1 at 7 days before harvest or 0.26 mg kg?1 at 4 days before harvest, which would be below the provisional MRL designed by the Korea Food and Drug Administration. 相似文献
243.
为了提高选择性催化还原(SCR)在低温区(200℃)的脱硝性能,提出利用插在烟道中的沿面放电反应器生成氧活性物质,部分氧化NO以实现低温快速SCR脱硝过程.同时,研究了氧活性物质注入实现快速SCR的脱硝性能,考察了氧活性物质注入降低二氧化硫和水蒸汽对SCR反应的影响.实验结果表明:在模拟烟气温度为150℃时,采用氧活性物质注入,部分氧化烟气中的NO以实现快速SCR反应条件下(NO/NO2浓度比为1),脱硝效率为51.9%,比标准SCR提升23%;当模拟烟气中存在SO2或H2O时,氧活性物质注入可有效降低SO2、H2O对SCR脱硝效率的影响. 相似文献
244.
膜-生物反应器处理高盐废水膜面污染物特性研究 总被引:9,自引:5,他引:4
研究MBR在低有机负荷条件下处理高盐废水的膜面污染物特征.结果表明,稳定运行121 d后,MBR对有机物和NH+4-N去除率稳定,出水效果良好;污泥性质发生较大变化,挥发性固体含量(VSS)/固体含量(SS)的下降,污泥体积指数(SVI)下降,表明污泥中无机成分含量增加,絮体更为紧密,沉降性能变好;污泥溶解性微生物产物(SMP)和胞外聚合物(EPS)成分发生较大变化,蛋白质所占比例降低,腐殖酸所占比例增加;扫描电子显微镜-X射线能谱仪(SEM-EDX)结果表明膜面存在无机污染物,其主要组成元素为Na、Al、Mg、Ca、K、Fe、Ti、Cr、W、Si和Cl;凝胶过滤色谱(GFC)分析表明,SMP中的大分子有机物被膜截留并累积是形成膜污染的原因之一;傅立叶红外(FTIR)光谱和三维荧光光谱(EEM)分析表明,膜面有机污染物的主要成分为糖类、蛋白质和腐殖酸;膜污染物组分质量分析说明在处理高盐废水时无机膜污染不可忽略. 相似文献
245.
南京北郊大气VOCs变化特征及来源解析 总被引:10,自引:8,他引:2
利用2011-03-01~2012-02-29南京北郊大气VOCs观测资料,对大气VOCs浓度变化特征和特征物比值差异展开研究,并应用PCA/APCS受体模型对不同季节VOCs来源进行了解析.结果表明,南京大气总VOCs体积混合比为43.52×10-9,其中烷烃占45.1%、烯烃占25.3%、炔烃占7.3%和芳香烃占22.3%.总VOCs体积混合比呈现夏季高,冬季低的季节变化.VOCs组分中烷烃在冬季最高,烯烃夏季最高,芳香烃春季最高,炔烃冬季最高.特征物比值(VOCs/乙炔)和T/B比值反映出观测点受周边工业区影响较大.VOCs源解析表明,主要来源来自工厂生产、机动车排放、燃料燃烧、生产活动挥发、溶剂使用和自然源.虽然有季节变化,但与工业生产活动相关的来源占大气VOCs 45%~63%,其次为机动车来源占34%~50%. 相似文献
246.
Al TA Banks V Loomer D Parker BL Ulrich Mayer K 《Journal of contaminant hydrology》2006,88(1-2):137-152
The potential for trace-metal contamination of aquifers as a side effect of In Situ Chemical Oxidation (ISCO) of chlorinated solvent contamination by KMnO(4) is investigated with column experiments. The experiments investigate metal mobility during in situ chemical oxidation of TCE by KMnO(4) under conditions where pH, flow rate, KMnO(4), TCE, and trace-metal concentrations were controlled. During ISCO, the injection of MnO(4) creates oxidizing conditions, and acidity released by the reactions causes a tendency toward low pH in aquifers. In order to evaluate the role of pH buffering on metal mobility, duplicate columns were constructed, one packed with pure silica sand, and one with a mixture of silica sand and calcite. Aqueous solutions of TCE and KMnO(4) (with 1 mg/L Cu, Pb, Zn, Mo, Ni, and Cr(VI)) were allowed to mix at the inlet to the columns. After the completion of the experiments, samples of Mn oxide were removed from the columns and analyzed by analytical scanning and transmission electron microscopy. In order to relate the results of the laboratory experiments to field settings, the analyses of Mn-oxide samples from the lab experiments were compared to samples of Mn oxide collected from a field-scale chemical-oxidation experiment that were also analyzed by analytical electron microscopy as well as time-of-flight secondary-ion mass spectroscopy. The pH ranged from 2.40 in the silica sand column to 6.25 in the calcite-containing column. The data indicate that aqueous Mo, Pb, Cu and Ni concentrations are attenuated almost completely within the columns. In contrast, Zn concentrations are not significantly attenuated and Cr(VI) is transported conservatively. The results indicate that within the range 2.40 to 6.25, metal mobility is not affected by pH. Comparison of analyses of Mn-oxide from the lab and field demonstrate that a variety of metals are sequestered from solution by Mn oxide. 相似文献
247.
T. Al Austin W. F. Riddle R. Q. Landers 《Journal of the American Water Resources Association》1979,15(5):1265-1280
ABSTRACT: A flood control reservoir protects valuable developments on the downstream flood plain by storing flood waters and releasing them at a rate that will reduce the downstream damage. The water surface level of the flood pool behind the dam can fluctuate considerably during the occurrence of a large magnitude flood causing severe impacts on shoreline vegetation and water based recreation facilities located in the flood pool. A mathematical simulation model describing shoreline vegetative succession in response to flooding is presented. Plant species are grouped into ecologically similar compartments. Differential equations describing compartment intrinsic growth, intraspecies competition, interspecies competition, and other growth limiting factors are solved numerically. The model is used to evaluate the impacts of various operating policies on plant succession for a new reservoir in Central Iowa. 相似文献
248.
249.
250.
京津冀区域沙尘暴和群发性强沙尘暴特征分析 总被引:2,自引:4,他引:2
利用京津冀区域内102个气象站1954~2002年观测资料,分析了此区域沙尘暴和群发性强沙尘暴的变化特征.结果表明:京津冀区域绝大部分地区是沙尘暴主要影响区,冀北高原是此区域的易发区和多发区.沙尘暴发生时间具有明显的日变化特征和季节差异,沙尘暴呈现整体减少趋势,各分区变化趋势具有相似性,只是在减少幅度上略有不同.近50年此区域共出现了39例群发性强沙尘暴,冀北高原和定州、饶阳一带是此区域群发性强沙尘暴天气的多发区.多发季节为春季(3~5月),占全年总数的76.9%,尤以4月份最多,占全年总数的51.3%.群发性强沙尘暴年代际变化呈现总体减少趋势,其发生次数、覆盖面积均以90年代为最低值. 相似文献