The contamination and distribution of organochlorinated compounds were considered in three crustacean species (edible crab, Cancer pagurus; spider crab, Maja brachydactyla; velvet swimming crab, Necora puber) from five sites along the coasts of Brittany and Normandy (Western and North-Western France). PCBs (16 single congeners), pp'-DDE and HCB were measured in hepatopancreas, gonads and muscle: in all, 175 samples were analysed. The spider crab was the only species found in the five sampling sites, thus enabling comparison between areas. Specimens from Antifer were much more contaminated (summation operator 16 PCBs in hepatopancreas=2000-4000 ng g(-1) dry weight) than those from other sites (50-1000 ng g(-1) d.w.). Among all the three species, the spider crab appeared more contaminated by PCBs than the edible crab, by a factor 2-3, probably in relation with specific differences in their life cycle. There was no difference due to the gender of the species. Within the different analysed tissues, contamination levels increased from muscle to gonads and hepatopancreas in relation with the fat content. A very similar PCB composition was observed in all samples, PCB fingerprints being characterised by the relative importance of the more persistent PCB congeners: CB153, 138, 180, 187, and 118. Finally, these results were compared to recent food regulations first of maximum marker PCB intake and secondly of maximum dioxin-like PCB intake. By considering the muscle, all samples were far below the regulatory limits; for hepatopancreas and gonads, however, some samples were unfit for human consumption. 相似文献
Surface sediments from estuarine and coast of CanGio wetland (CGW) of Hochiminh City, Vietnam, were investigated to identify the spatial and temporal variations of polycyclic aromatic hydrocarbons (PAHs). The total PAHs showed wide variation but similar to patterns observed (F?=?0.901, p?=?0.46) in LongTau (31?±?77 ng/g dry weight, n?=?13), SoaiRap (53?±?81, n?=?4), ThiVai (60?±?62, n?=?10) estuaries, and coastal areas (112?±?211, n?=?9). A decreasing trend in the wet season (F?=?8.8, p?=?0.01) reflected that inland sources such as wastewater discharged and atmospherically transported contaminants contributed to PAHs in sediments. The risk posed by the PAHs in the coastal and estuarine areas of CGW is still negligible. The present study provides baseline data, which can be used for regular monitoring and future strategy of environmental protection for the study area.