全文获取类型
收费全文 | 162篇 |
免费 | 0篇 |
国内免费 | 1篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 9篇 |
环保管理 | 9篇 |
综合类 | 33篇 |
基础理论 | 25篇 |
污染及防治 | 67篇 |
评价与监测 | 12篇 |
社会与环境 | 7篇 |
出版年
2024年 | 1篇 |
2022年 | 5篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 8篇 |
2017年 | 8篇 |
2016年 | 4篇 |
2015年 | 2篇 |
2014年 | 10篇 |
2013年 | 10篇 |
2012年 | 14篇 |
2011年 | 8篇 |
2010年 | 10篇 |
2009年 | 8篇 |
2008年 | 17篇 |
2007年 | 9篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 6篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有163条查询结果,搜索用时 9 毫秒
61.
Fattorini D Notti A Di Mento R Cicero AM Gabellini M Russo A Regoli F 《Chemosphere》2008,72(10):1524-1533
Mussels are widely used as bioindicator organisms for monitoring chemical pollutants including trace metals. These elements are natural constituents in the marine environment and their basal concentrations in the organisms can be influenced by several environmental and biological factors. The aim of this work was to extend our knowledge on the natural variability of trace metals in mussels tissues, focusing on seasonal and inter-annual fluctuations in a coastal reference site of the Adriatic coast (Portonovo); a total of 39 samplings were performed during 5 years, providing an extended data-set for tissue levels of As, Ba, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, V and Zn. Concentrations of trace metals in mussels tissues revealed marked seasonal fluctuations with significant differences between various sampling years. Such fluctuations appeared mostly related to phytoplanctonic blooms and especially to reproductive cycle which exhibited a certain inter-annual shift of the gametogenesis period. Lower concentrations were measured in summer months for the majority of elements while a different seasonal cycle was observed for arsenic, not correlated with gonadic development, neither with other elements. Chemical speciation of arsenic was characterized to distinguish compounds of natural origin from those potentially reflecting an anthropogenic impact. Arsenobetaine and arsenocholine were always the predominant forms (up to 85% of total arsenic), while a significant increase of dimethylarsine and trimethylarsine oxide in spring (24% of total arsenic) might reflect the effect of phytoplanctonic bloom on both geochemistry and trophic transfer of this element. A significant inter-annual variability was observed for both the seasonal cycle and the range of values measured for all the elements, with particularly marked differences for arsenic, ranging from less than 10 to more than 40 microg/g in summer periods of different years. Data obtained on reference mussels were used to assess the impact of 41 off-shore platforms distributed along 5 nautical districts in the Northern and Central Adriatic Sea. Organisms sampled on these structures from 2001 to 2005 exhibited a certain enrichment of cadmium and zinc, probably associated to the use of anodic electrodes. Marked annual and geographical variations were measured for concentrations of arsenic in mussels of different platforms. However, the comparison with results of Portonovo, allowed to exclude the anthropogenic impact of exploitation activities and revealed a natural regional gradient of arsenic levels in mussels tissues associated to the changing influence of the Po river runoff on seawater salinity. In particular the higher concentrations measured in organisms sampled from platforms in the Central compared to Northern Adriatic confirmed a significant relationship between salinity and arsenic bioaccumulation, consistent with a role of arsenobetaine as an acquired osmolyte for mussels. The overall results confirmed the importance of natural variability when assessing the potential impact of anthropogenic activities. 相似文献
62.
Hydrolytic degradation of azimsulfuron, a sulfonylurea herbicide 总被引:1,自引:0,他引:1
The chemical degradation of the herbicide azimsulfuron was investigated in aqueous solutions at different pH values. The hydrolysis rate, determined by HPLC analyses, was pH dependent and was much faster in acidic than in neutral or weakly basic conditions. The metabolites formed at different pH values were compared with standards when possible or isolated and identified using ESI-LC-MS/MS, (1)H NMR and (13)C NMR. The two main products of hydrolysis in mild acidic solution were identified as 2-amino-4,6-dimethoxy-pyrimidine and 2-methyl-4-(2-methyl-2H-tetrazol-5-yl)-2H-pyrazole-3-sulfonamide, both produced as a result of the sulfonylurea bridge cleavage. Under basic conditions, a new product, a substituted 2-pyrimidinamine, deriving from the contraction of the sulfonylurea bridge, was isolated and completely characterized for the first time. 相似文献
63.
Alessandra Cincinelli Tania Martellini Luciano Lepri Nicoletta Borghesi Rebecca M. Dickhut 《Environmental pollution (Barking, Essex : 1987)》2009,157(7):2153-2158
Mean hexachlorobenzene (HCB) and hexachlorocyclohexane (HCH) concentrations, measured in seawater and air samples, confirmed the decline in levels of these compounds in Antarctic air and water. However, low α/γ-HCH ratios in air at the beginning of the sampling period suggest a predominance of fresh lindane entering the Antarctic atmosphere during the Austral spring probably due to current use in the Southern Hemisphere. Water-air fugacity ratios demonstrate the potential for HCH gas deposition to coastal Antarctic seas, while the water-air fugacity ratios for HCB imply that volatilization does not account for the observed decrease of HCB in surface seawater. HCH concentrations found in krill samples were correlated with seawater concentrations indicative of bioconcentration of HCHs from seawater. 相似文献
64.
Faria Clara V. Moreira Gabriel C. Araújo Alessandra P. B. Marques Laura E. Oliveira Lara P. Ricci Bárbara C. Amaral Miriam C. S. Fonseca Fabiana V. 《Environmental science and pollution research international》2021,28(19):23778-23790
Environmental Science and Pollution Research - Conventional sewage treatment systems are generally not designed to remove micropollutants, requiring the development of new technologies, such as the... 相似文献
65.
Faria Maria Graciela Iecher Avelino Katielle Vieira Philadelpho Biane Oliveira dos Santos Bomfim Rafaela do Valle Juliana Silveira Júnior Affonso Celso Gonçalves Dragunski Douglas Cardoso de Souza Ferreira Ederlan de Souza Carolina Oliveira Ribeiro Camila Duarte Ferreira Colauto Nelson Barros Linde Giani Andrea 《Environmental science and pollution research international》2022,29(58):87519-87526
Environmental Science and Pollution Research - Lentinus crinitus bioaccumulates lithium in mycelia, but bioaccumulation may be affected by pH of the culture medium. Lithium is used in clinical... 相似文献
66.
67.
Beatrice Oneda Rosa Baldinger Regina Reissmann Irina Reshetnikova Pavel Krejci Rahim Masood Nicole Ochsenbein-Kölble Deborah Bartholdi Katharina Steindl Denise Morotti Marzia Faranda Alessandra Baumer Reza Asadollahi Pascal Joset Dunja Niedrist Christian Breymann Gundula Hebisch Margaret Hüsler René Mueller Elke Prentl Josef Wisser Roland Zimmermann Anita Rauch 《黑龙江环境通报》2014,34(6):525-533
68.
69.
70.