Benzene degradation in waste gas by photolysis and photolysis-ozonation: experiments and modeling

A photochemical model of benzene degradation compares well with experimental data obtained in the Lab. 62 reactions were needed to fully describe benzene degradation. A feasibility study shows that the photolysis of benzene is a cost-effective process. Experimental data and modeling results show that the degradation efficiency will increase when the combination of UV light and ozone is used. The degradation of benzene, a carcinogenic air pollutant, was studied in a gas-phase photochemical reactor with an amalgam lamp emitting ultraviolet light at 185 and 254 nm. Efficient benzene degradation (>70%) was possible for benzene mass flow rates of up to 1.5 mg·min⁻¹. Adding ozone allowed benzene mass flow rates of up to 5 mg·min⁻¹ to be treated with the same efficiency. In terms of energy consumption, ozone doubles the efficiency of the process. A comprehensive mechanistic simulation model was developed incorporating a chemical kinetics model (62 reactions involving 47 chemical species), a material balance model incorporating diffusion and flow, a flow velocity model, and a light field model. The model successfully predicted the efficiency of the reactor, generally within 20%, which indicates that the model is sound, and can be used for feasibility studies. The prediction of the reactor efficiency in the presence of ozone was less successful, with systematically overestimated efficiency. Condensation of reaction products in the reactor is thought to be the main cause of model inaccuracy. Both experimental data and model predictions show that there is a synergistic effect between ozonation and ultraviolet degradation.     

Probing emissions of military cargo aircraft: description of a joint field measurement Strategic Environmental Research and Development Program

To develop effective air quality control strategies for military air bases, there is a need to accurately quantify these emissions. In support of the Strategic Environmental Research and Development Program project, the particulate matter (PM) and gaseous emissions from two T56 engines on a parked C-130 aircraft were characterized at the Kentucky Air National Guard base in Louisville, KY. Conventional and research-grade instrumentation and methodology were used in the field campaign during the first week of October 2005. Particulate emissions were sampled at the engine exit plane and at 15 m downstream. In addition, remote sensing of the gaseous species was performed via spectroscopic techniques at 5 and 15 m downstream of the engine exit. It was found that PM mass and number concentrations measured at 15-m downstream locations, after dilution-correction generally agreed well with those measured at the engine exhaust plane; however, higher variations were observed in the far-field after natural dilution of the downstream measurements was accounted for. Using carbon dioxide-normalized data we demonstrated that gas species measurements by extractive and remote sensing techniques agreed reasonably well.     

A habitat‐based approach to predict impacts of marine protected areas on fishers

Although marine protected areas can simultaneously contribute to biodiversity conservation and fisheries management, the global network is biased toward particular ecosystem types because they have been established primarily in an ad hoc fashion. The optimization of trade‐offs between biodiversity benefits and socioeconomic values increases success of protected areas and minimizes enforcement costs in the long run, but it is often neglected in marine spatial planning (MSP). Although the acquisition of spatially explicit socioeconomic data is perceived as a costly or secondary step in MSP, it is critical to account for lost opportunities by people whose activities will be restricted, especially fishers. We developed an easily reproduced habitat‐based approach to estimate the spatial distribution of opportunity cost to fishers in data‐poor regions. We assumed the most accessible areas have higher economic and conservation values than less accessible areas and their designation as no‐take zones represents a loss of fishing opportunities. We estimated potential distribution of fishing resources from bathymetric ranges and benthic habitat distribution and the relative importance of the different resources for each port of total catches, revenues, and stakeholder perception. In our model, we combined different cost layers to produce a comprehensive cost layer so that we could evaluate of trade‐offs. Our approach directly supports conservation planning, can be applied generally, and is expected to facilitate stakeholder input and community acceptance of conservation.     

Spatial Analysis of Soil Salinity and Soil Structural Stability in a Semiarid Region of New South Wales,Australia

Salt-affected soils are a major threat to agriculture especially in the semiarid regions of the world. The effective management of these soils requires adequate understanding of not only how water and, hence, solutes are transported within the soil, but also how soil salinity and sodicity spatially interact to determine soil structural breakdown. For sustainable agricultural production, information on quantitative soil quality, such as salinity, is required for effective land management and environmental planning. In this study, quantitative methods for mapping indicators of soil structural stability, namely salinity and sodicity, were developed to assess the effect of these primary indicators on soil structural breakdown. The current levels of soil salinity, as measured by electrical conductivity (EC) of the soil/water suspension, soil sodicity, represented by exchangeable sodium percentage (ESP), and aggregate stability, were assessed. Remote sensing, geographical information system (GIS), and geostatistical techniques-primarily regression-kriging and indicator-kriging-were used to spatially predict the soil sodicity and salinity. The patterns of salinity (EC) and sodicity (ESP > 5%) were identified. The effect of land use on these soil quality indicators was found to be minimal. Co-spatial patterns were elucidated between sodic soils (defined by ESP > 5%) and highly probable mechanically dispersive soils predicted from indicator-kriging of ASWAT scores. It was established that the incorporation of EC with ESP into an objective index, called electrolyte stability index (ESI = ESP/EC), gave a good indication of soil dispersion, although the threshold ESI value below which effective structural breakdown might occur is 0.025, which is twice as small as the expected 0.05. The discrepancies between ESI and ASWAT scores suggest that other soil factors than salinity and sodicity are affecting soil structural breakdown. This calls for further investigation. The study provides valuable information in the form of risk zones of soil structural breakdown for land management. These zones, with a probability of mechanical soil dispersion of >0.70, require immediate management attention with greater monitoring and amelioration techniques, particularly gypsum or lime application and/or altered cultivation techniques.     

从法律视角分析三峡库区水环境的保护

随着三峡库区的形成,三峡库区水环境的质量也引起了公众的注意.三峡库区现行的水环境保护法律存在缺陷,即缺乏一部统领性的法律,缺少专门的流域管理机构及协调机制,公众环保意识淡薄,水资源使用制度存在缺陷和污染治理缺乏市场机制.因此,建议采取如下措施:制定三峡库区水污染防治条例,建立库区水环境管理委员会,鼓励公众参与,完善水资源有偿使用制度和排污收费制度.     

CAERvest® – a novel endothermic hypothermic device for core temperature cooling: safety and efficacy testing

Introduction. Cooling of the body is used to treat hyperthermic individuals with heatstroke or to depress core temperature below normal for neuroprotection. A novel, chemically activated, unpowered cooling device, CAERvest®, was investigated for safety and efficacy. Methods. Eight healthy male participants (body mass 79.9?±?1.9?kg and body fat percentage 16.1?±?3.8%) visited the laboratory (20 °C, 40% relative humidity) on four occasions. Following 30-min rest, physiological and perceptual measures were recorded. Participants were then fitted with the CAERvest® proof of concept (PoC) or prototype 1 (P1), 2 (P2) or 3 (P3) for 60 min. Temperature, cardiovascular and perceptual measures were recorded every 5 min. After cooling, the CAERvest® was removed and the torso checked for cold-related injuries. Results. Temperature measures significantly (p?Conclusion. This study demonstrates that the CAERvest® is an effective device for reducing body temperature in healthy normothermic individuals without presence of cold injury. Further research in healthy and clinical populations is warranted.     

Fume Control in Rubber Processing By Direct-Flame Incineration

The application of direct-flame incineration to successfully eliminate a smoke-oil-mist and odor problem in the manufacture of rubber-base rug underlay, is presented. The investigation of various air pollution control processes leading to the development and adoption of the direct-flame incineration system, is covered. The rug-underlay curing process incorporating the direct-flame incineration system with primary heat recovery is described. Results and discussion of a source test to determine the effectiveness of direct-flame incineration in this application are included.     

ASsessment Of Alcohol Ethoxylate Surfactants And Fatty Alcohols Mixtures In River Sediments And Prospective Risk Assessment

A feasible and relatively readily available analytical method was adapted for the assessment of alcohol ethoxylates (AE) and fatty alcohols (FA) in sediments. This study illustrates the simultaneous measurement of 38 of 114 possible alcohol ethoxylate ethoxymers (AE) and fatty alcohols (FA) found in commercially important AE products. We predicted toxicity for all identified fractions, as well as the total mixture toxicity, relative to three exposure scenarios via sewage treatment plants (STP) for these widely used chemicals in consumer products and hence generate a preliminary environmental risk screening for AE and FA in sediments. The method is based on derivatization of solvent or solid-phase extracts with 2-fluoro-N-methylpyridinium p-toluenesulfonate (Pyr+). The derivatized extracts were analyzed with liquid chromatography/mass spectrometry (LC/MS) operating in the positive ion electrospray mode. The extraction efficiency of AE and FA in three different sediments of varying composition was evaluated with spike-recovery studies, ranging from 64% to 80%. The detection limits for individual ethoxymers typically ranged from 1 to 5ngg⁻¹on a dry weight basis. The mean limit of detection (LOD) was 6ngg⁻¹and the median LOD was 3ngg⁻¹. AE and FA in sediments were found to be stable for two weeks if preserved with 3% (v/v) formalin and stored at 4–6^∘C. Based on equilibrium partitioning, background concentrations of AE and FA were predicted to be below concentrations known to elicit chronically toxic effects. Total worst case mixture toxicities for all AE ethoxymers combined with FA were predicted to result in a risk quotient less than 0.6. Activated sludge treatment (STP) significantly reduced the release of total AE and FA by four-fold, suggesting that the total mixture risk quotient would be < 0.15 for sediment dependent organisms.     

Graphs of grief and other green feelings: the uses of affect in the study of environmental communication

ABSTRACT

How can theories of affect and felt emotions be useful in studying the communication of environmental crises? Beginning from tears spilt over a graph of transgressed planetary boundaries published in an academic paper, this article explores the presentation in graphic visual forms of affective imagery and a growing sophistication amongst scientists, policymakers and activist communicators in the visualization of information, data and stories employed to carry the often difficult and complex messages of current earth systems crises. Critically, this article attends to the “emotion work” of such images. Taking a lead from cultural sociology and attempting to elucidate the relationship between societies under pressure and its choice of texts, this article considers the environmental documentary Cowspiracy [Anderson, K., & Kuhn, K. (2014). Cowspiracy. San Francisco, CA: AUM Films & First Spark Media.] to ask questions of affect’s relation to expressions of the earth systems crisis, which is also a crisis of culture.