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41.
Joris Mergaert Caroline Anderson Ann Wouters Jean Swings 《Journal of Polymers and the Environment》1994,2(3):177-183
The microbial degradation of tensile test pieces made of poly(3-hydroxybutyrate) [P(3HB)] or copolymers with 10% [P(3HB-co-10%3HV)] and 20% [P(3HB-co-20%3HV)] 3-hydroxyvaleric acid was studied in small household compost heaps. Degradation was measured through loss of weight (surface erosion) and changes in molecular weight and mechanical strength. It was concluded, on the basis of weight loss and loss of mechanical properties, that P(3HB) and P(3HB-co-3HV) plastics were degraded in compost by the action of microorganisms. No decrease inM
w could be detected during the degradation process. The P(3HB-co-20%3HV) copolymer was degraded much faster than the homopolymer and P(3HB-co-10%3HV). One hundred nine microbial strains capable of degrading the polymersin vitro were isolated from the samples used in the biodegradation studies, as well as from two other composts, and identified. They consisted of 61 Gram-negative bacteria (e.g.,Acidovorax facilis), 10 Gram-positive bacteria (mainlyBacillus megaterium), 35Streptomyces strains, and 3 molds. 相似文献
42.
This study concerns design features of urban parking lots which can increase the perception of such areas as both safe and attractive. College students evaluated the attractiveness and perceived security associated with 180 scenes of parking lots adjacent to commercial and multi-family residential structures in Atlanta and Athens, Georgia, U.S.A. High intergroup correlations (r > 0·90) indicated the reliability of evaluations of both perceived features. Regressions of physical features on perceived security ratings and attractiveness ratings yielded highly predictive models (R2 = 0·76 and 0·80, respectively). For both sets of ratings a Maintenance and Design factor accounted for the most variance. Although attractiveness ratings were higher as the total amount of vegetation increased in a scene, security was in general rated higher only when vegetation was well maintained and appeared to be installed as part of a landscape design. Attractiveness was generally higher for multi-family residential scenes than for commercial scenes. Perceived security was higher for frontal views of structures, especially when entrances were proximate to the viewer. Research implications are discussed in terms of the impact of natural features in urban areas for increasing attractiveness and reducing fear of crime. 相似文献
43.
Donald M. Anderson Mark W. Rodney 《Journal of the American Water Resources Association》2006,42(5):1391-1403
ABSTRACT: Efforts are under way to recover habitat for several threatened and endangered species in and along the Platte River in central Nebraska. A proposed recovery program for these species requires a means of characterizing “wet” versus “normal” versus “dry” hydrologic conditions in order to set corresponding Platte River instream flow targets. Methods of characterizing hydrologic conditions in real time were investigated for this purpose. Initially, 10 watershed variables were identified as potentially valuable indicators of hydrologic conditions. Ultimately, six multiple linear regression equations were developed for six periods of the year using a subset of these variables expressed as frequencies of nonexceedence. The adequacy of these equations for characterizing conditions was assessed by evaluating their historic correlation to subsequent flow in the central Platte River (1947–1994). These equations explained 54 to 82 percent of variability in the observed flow exceedences in the validation datasets, depending upon the period of year evaluated. These equations will provide initial criteria for setting applicable flow targets to determine, in real time, whether water regulation projects associated with the species recovery effort can divert or store flows without conflicting with recovery objectives. 相似文献
44.
Mark Dougherty Randel L. Dymond Thomas J. Grizzard Adil N. Godrej Carl E. Zipper John Randolph Christine M. Anderson‐Cook 《Journal of the American Water Resources Association》2006,42(5):1405-1419
ABSTRACT: Long term effects of precipitation and land use/land cover on basin outflow and nonpoint source (NFS) pollutant flux are presented for up to 24 years for a rapidly developing headwater basin and three adjacent headwater basins on the urban fringe of Washington, D.C. Regression models are developed to describe the annual and seasonal responses of basin outflow and IMPS pollutant flux to precipitation, mean impervious surface (IS), and land use. To quantify annual change in mean IS, a variable called delta IS is created as a temporal indicator of urban soil disturbance. Hydrologic models indicate that total annual surface outflow is significantly associated with precipitation and mean IS (r2= 0.65). Seasonal hydrologic models reveal that basin outflow is positively associated with IS during the summer and fall growing season (June to November). NPS pollutant flux models indicate that total and storm total suspended solids (TSS) flux are significantly associated with precipitation and urban soil disturbance in all seasons. Annual NPS total nitrogen flux is significantly associated with both urban and agricultural soil disturbance (r2= 0.51). Seasonal models of phosphorus flux indicate a significant association of total phosphorus flux with urban soil disturbance during the growing season. Total soluble phosphorus (TSP) flux is significantly associated with IS (r2= 0.34) and urban and agricultural soil disturbance (r2= 0.58). In urbanizing Cub Run basin, annual TSP concentrations are significantly associated with IS and cultivated agriculture (r2= 0.51). 相似文献
45.
Moths learn to associate a flower odor with a food reward after a few learning trials. Can a hungry, male moth learn to associate a sex attractant with food instead of with sex? We provided a hungry male with odors of single female sex pheromone components, of the full sex pheromone blend or of a flower odor component as cues in an appetitive learning assay. The male learned the single pheromone components just as well as the flower odor. Learning was, however, severely impaired when the full sex pheromone blend was used as conditioning stimulus. The "hard-wiring" between pheromone odor and sex thus seems to be restricted to those circumstances when the male moth experiences the full blend. 相似文献
46.
Li L Cunningham CJ Pas V Philp JC Barry DA Anderson P 《Waste management (New York, N.Y.)》2004,24(2):127-137
The influence of a new aeration system on the biopile performance was investigated. The purpose was to increase biodegradation efficiency by optimising airflow through the pile. During a 1-month field trial, the performance of a new system using two perforated vertical pipes with wind-driven turbines was compared with that of a standard pile configuration with two horizontal perforated pipes. Both piles were composed of a similar mix of diesel-contaminated soils, woodchips, compost and NPK fertiliser. Hydrocarbons were recovered using solvent extraction, and determined both gravimetrically and by gas chromatography. Total heterotrophs, pH and moisture content were also assessed. Air pressure measurements were made to compare the efficiency of suction in the pipes. Results at the end of the experiment showed that there was no significant difference between the two piles in the total amount of hydrocarbon biodegradation. The normalised degradation rate was, however, considerably higher in the new system than in the standard one, suggesting that the vertical venting method may have improved the efficiency of the biological reactions in the pile. The pressure measurements showed a significant improvement in the suction produced by the new aeration system. However, many factors other than the airflow (oxygen supply) may influence and limit the biodegradation rates, including moisture content, age of contaminants and the climatic conditions. Additional experiments and modelling need to be carried out to explore further the new aeration method and to develop criteria and guidelines for engineering design of optimal aeration schemes in order to achieve maximum biodegradation in biopiles. 相似文献
47.
Development and validation of a method for analysis of "dioxin-like" PCBs in environmental samples from the steel industry 总被引:1,自引:0,他引:1
A method, previously used for determination of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), has been modified for quantitative analysis of "dioxin-like" polychlorobiphenyls (PCBs) in environmental samples from the steel industry. The existing sample clean-up procedure, involving liquid chromatography on multi-layered silica and Florisil columns, has been extended to include a third chromatography stage on a basic alumina stationary phase. The additional clean-up stage is required for PCB analysis in order to eliminate interferences from relatively large concentrations of saturated cyclic and aliphatic hydrocarbons. Samples were analysed for WHO-12 congeners using high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) and standard solutions of the method US EPA 1668A. Replicate analysis of method blanks revealed background contamination for PCBs 118, 105 and 77, which are generally abundant in ambient air. These contaminants were taken into account using a subtraction method. The entire procedure was validated by replicate analysis (N = 3) of a certified reference sediment. The RSD for each WHO-12 congener was below 15%, 13C12-labelled PCB internal standard recoveries were in the range 70-95%. A waste dust sample collected in the electrostatic precipitator of a UK sinter plant was analysed for determination of PCDD/Fs and WHO-12 PCBs and exhibited a PCDD/F I-TEQ of 148.5 +/- 21.2 ngkg(-1) and a WHO-TEQ of 7.2 +/- 1.5 ngkg(-1). WHO-12 congeners contributed only 4.6% to the overall TEQ and PCB 126 was the major congener contributing to the WHO-TEQ (96%). The contribution to the overall TEQ of the waste dust sample was mainly attributed to PCDF followed by PCDD, which accounted for 86.6% and 8.7% to the overall TEQ, respectively. 相似文献
48.
Veinott G Sylvester P Hamoutene D Anderson MR Meade J Payne J 《Journal of environmental monitoring : JEM》2003,5(4):626-634
In 1989, the tailings pond dam at the site of a former copper mine near Little Bay, Newfoundland and Labrador, Canada, ruptured and tailings spilled into Little Bay Arm. At the time, no action was taken to arrest the flow of tailings or to mitigate the effects of the spill. To date, no action has been taken to repair the dam and tailings continue to flow into Little Bay Arm. As a result, the marine environment around Little Bay Arm has become contaminated with heavy metals from the tailings. However, the tailings are not the only source of heavy metals to the ecosystem. An old slag heap and what is presumably concentrated copper ore spilled during the loading of ore freighters, are also contributing to the ecosystem's metal load. Marine sediment throughout the Arm contained elevated concentrations of Cu, Ni, Zn, As, V, Co, and Mn. Beach material also contained elevated concentrations of metals with material near the slag heap being the most contaminated. At this site, Cu concentrations were in excess of 5000 mg kg(-1) dry weight, Zn greater than 3000 mg kg(-1) and Co concentrations exceeded 700 mg kg(-1). The highest concentrations of metals in biota were found near the slag heap, near the tailings dam breach, and at the site of the former concentrate loading dock. Despite elevated metal concentrations, the tailings and nearby sediment were not devoid of life. Bivalves and seaweed were abundant in the area and there were no obvious signs of tissue damage or disease in soft shell clams (Mya arenaria) living in the tailings. These clams may be suffering from chronic exposure to the tailings, however, evidence of lipid peroxidation in the clams was inconclusive. 相似文献
49.
Ammonia is a basic gas and one of the most abundant nitrogen-containing compounds in the atmosphere. When emitted, ammonia reacts with oxides of nitrogen and sulfur to form particles, typically in the fine particle size range. Roughly half of the PM(2.5) mass in eastern United States is ammonium sulfate, according to the US EPA. Results from recent studies of PM(2.5) show that these fine particles are typically deposited deep in the lungs and may lead to increased morbidity and/or mortality. Also, these particles are in the size range that will degrade visibility. Ammonia emission inventories are usually constructed by multiplying an activity level by an experimentally determined emission factor for each source category. Typical sources of ammonia include livestock, fertilizer, soils, forest fires and slash burning, industry, vehicles, the oceans, humans, pets, wild animals, and waste disposal and recycling activities. Livestock is the largest source category in the United States, with waste from livestock responsible for about 3x10(9) kg of ammonia in 1995. Volatilization of ammonia from livestock waste is dependent on many parameters, and thus emission factors are difficult to predict. Despite a seasonal variation in these values, the emission factors for general livestock categories are usually annually averaged in current inventories. Activity levels for livestock are from the USDA Census of Agriculture, which does not give information about animal raising practices such as housing types and grazing times, waste handling systems, and approximate animal slurry spreading times or methods. Ammonia emissions in the United States in 1995 from sources other than livestock are much lower; for example, annual emissions are roughly 8x10(8) kg from fertilizer, 7x10(7) kg from industry, 5x10(7) kg from vehicles and 1x10(8) kg from humans. There is considerable uncertainty in the emissions from soil and vegetation, although this category may also be significant. Recommendations for future directions in ammonia research include designing experiments to improve emission factors and their resolution in all significant source categories, developing mass balance models, and refining of the livestock activity level data by eliciting judgment from experts in this field. 相似文献
50.
Integrity of chloroplast membranes is essential to photosynthesis. Loss of thylakoid membrane integrity has been proposed as a consequence of ozone (O(3)) exposure and therefore may be a mechanistic basis for decreased photosynthetic rates commonly associated with ozone exposure. To investigate this hypothesis, Pinus ponderosa seedlings were exposed to ambient air or ozone concentrations maintained at 0.15 or 0.30 microliter l(-1) for 10 h day(-1) for 51 days during their second growing season. Over the course of the study, foliage samples were periodically collected for thylakoid membrane, chlorophyll and protein analyses. Additionally, gas-exchange measurements were made in conjunction with foliage sampling to verify that observed chloroplastic responses were associated with ozone-induced changes in photosynthesis.Needles exposed to elevated ozone exhibited decreases in chlorophyll a and b content. The decreases were dependent on the duration and intensity of ozone exposure. When based on equal amounts of chlorophyll, ozone-exposed sample tissue exhibited an increase in total protein. When based on equal amounts of protein, ozone-exposed samples exhibited an increase in 37 kDa proteins, possibly consisting of breakdown products, and a possible decrease in 68 kDa proteins, Rubisco small subunit. There was also a change in the ratio of Photosystem I protein complexes CPI and CPII that may have contributed to decreased photosynthesis. Net photosynthetic rates were decreased in the high ozone treatment suggesting that observed structural and biochemical changes in the chloroplast were associated with alterations of the photosynthetic process. 相似文献