Persistent organic pollutants in breast milk of mothers residing around an open dumping site in Kolkata,India: Specific dioxin-like PCB levels and fish as a potential source

Concentrations of persistent organic pollutants (POPs) such as polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), polychlorinated biphenyls (PCBs) and organochlorine pesticides were measured in human breast milk collected from mothers residing near an open dumping site and a reference site in Kolkata, India during 2004–2005. POPs were detected in all the human milk samples analyzed, suggesting that residents of Kolkata are widely exposed to these contaminants. Concentrations of dioxin-like PCBs in the samples from the dumping site were significantly higher than in the reference site samples, whereas no such difference was found for PCDDs and PCDFs. In addition, significantly higher concentrations of total PCBs were also observed in the samples from the dumping site than the reference site. Interestingly, concentrations of total and dioxin-like PCBs in the breast milk of mothers from the dumping site significantly increased with the number of years of residence near the dumping site. These results indicate that significant pollution sources of PCBs are present in the dumping site of Kolkata and the residents living around are exposed to relatively higher levels of PCBs. When the residue levels of dioxins and related compounds in fish collected from ponds near the Kolkata dumping site and the reference site were measured, it was found that dioxin-like PCB and TEQ levels in fish from the dumping site were notably higher than those from the reference site. This result indicates that fish is a potential source of PCBs for residents living near the Kolkata dumping site.     

Morphological changes at Vellar estuary, India--impact of the December 2004 tsunami

Coastal subsystems formed by interaction of various processes, impacted by natural hazards like tsunami and storms, pose irreversible morphological changes. Vellar estuary, located on the southeast coast of India, with huge sand dunes (of 3-6m height and spread to 560ha) and barrier islands, has undergone extensive morphological changes due to the giant Indian Ocean tsunami that occurred on 26th December 2004. The damage caused by the tsunami has been quantified using extensive field data collected during pre- and post-tsunami periods through Real Time Kinematic GPS (for mapping coastal features and beach profiles) and Geographic Information System (GIS) couple. The tsunami with a wave height as high as 4m not only inundated the entire coastal land up to a maximum of 2km but also eroded the sand dunes and deposited the eroded material at the inlet, which ultimately formed as a vast tidal flat spread over 31ha. The estuary has suffered immensely due to the tsunami especially in terms of (i) loss of natural protection barriers (sand dunes), which made this coastal area more vulnerable to storm attack, and (ii) shallowness of inlet creating hindrance to navigation of fishing vessels. Based on the observations made at Vellar coast and past recovery experiences of tsunami/hurricanes elsewhere in the world, we contend that the morphological loss might take at least two annual cycles to regain its original form and the rebuilding of sand dunes may even take a decade.     

Organohalogen compounds in human breast milk from mothers living in Payatas and Malate, the Philippines: Levels, accumulation kinetics and infant health risk

Human breast milk samples (n = 33) from primipara and multipara mothers from Payatas a waste dump site, and Malate a reference site in the Phillipines were collected in 2004 and analyzed for eight organohalogen compounds, viz., PCBs, DDTs, CHLs, HCHs, HCB, TCPMe, PBDEs and HBCDs. DDTs and PCBs were predominant in all the samples. Overall mean concentrations of PBDEs found in our study were higher (7.5 ng/g lipid wt.) than those reported for Japan and many other Asian countries. Primipara mothers had significantly higher levels of DDTs, CHLs and HCHs than multipara mothers, but not PBDEs and HBCDs. A few individuals accumulated CHLs close to or even higher than the tolerable daily intake guidelines proposed by Health Canada.     

Mineralization of phenol by Ce(IV)-mediated electrochemical oxidation in methanesulphonic acid medium: a preliminary study

The mediated electrochemical oxidation (MEO) process using cerium(IV) in methanesulphonic acid (MSA) as the oxidizing medium was employed for the mineralization of phenol in batch and continuous feeding modes. Although nitric acid was an extensively studied electrolyte for organic mineralization reactions in MEO processes it does possess the problem of NO(x) gas production during the reduction of nitric acid in the cathode compartment of the electrochemical cell. This problem could be circumvented by proper choice of the electrolyte medium such as MSA. The mediator cerium in MSA solution was first oxidized to higher oxidation state using an electrochemical cell. The produced Ce(IV) oxidant was then used for the destruction of phenol. It was found that phenol could be mineralized to CO2 by Ce(IV) in MSA. The evolved CO2 was continuously measured and used for the calculation of destruction efficiency. The destruction efficiency was observed to be 85% based on CO2 evolution for 1000 ppm phenol solution at 80 degrees C in continuous feed mode.     

Non-metallic organic dyes as photosensitizers for dye-sensitized solar cells: a review

Environmental Science and Pollution Research - The advent of novel technologies has led to the need for environmental and economic integration. Energy consumption plays a vital role in human...     

Soil contamination by brominated flame retardants in open waste dumping sites in Asian developing countries

In Asian developing countries, large amounts of municipal wastes are dumped into open dumping sites each day without adequate management. This practice may cause several adverse environmental consequences and increase health risks to local communities. These dumping sites are contaminated with many chemicals including brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs) and hexabromocyclododecanes (HBCDs).BFRs may be released into the environment through production processes and through the disposal of plastics and electronic wastes that contain them.The purpose of this study was to elucidate the status of BFR pollution in municipal waste dumping sites in Asian developing countries. Soil samples were collected from six open waste dumping sites and five reference sites in Cambodia, India, Indonesia, Malaysia, and Vietnam from 1999 to 2007. The results suggest that PBDEs are the dominant contaminants in the dumping sites in Asian developing countries, whereas HBCD contamination remains low. Concentrations of PBDEs and HBCDs ranged from ND to 180 μg/kg dry wt and ND to 1.4 μg/kg dry wt, respectively, in the reference sites and from 0.20 to 430 μg/kg dry wt and ND to 2.5 μg/kg dry wt, respectively, in the dumping sites. Contamination levels of PBDEs in Asian municipal dumping sites were comparable with those reported from electronic waste dismantling areas in Pearl River delta, China.     

Monitoring of pesticide residues in South Indian tea

Tea is the most commonly consumed beverage in the world. Tea infusion is prepared by pouring boiling hot water over cured leaves of the Camellia sinensis plant. Such a beverage should be free from toxic chemicals. Studies on the monitoring of pesticide residues in tea of South India had been carried. Tea samples collected from different districts of South India were analysed for the residues of certain pesticide such as dicofol, ethion, quinalphos, hexaconazole, fenpropathrin, fenvalerate and propargite. These pesticides are commonly used for the control of pests and diseases in tea. The results of study indicated that among 468 samples examined, only one sample contained hexaconazole residue that exceeded the maximum residue limit (MRL). Though the residues of ethion, quinalphos, hexaconazole, dicofol, propargite and fenpropathrin were most commonly found, only one sample exceeded the MRL.     

Preliminary investigation on the impact of engineered PVP-capped and uncapped silver nanoparticles on Eudrilus eugeniae,a terrestrial ecosystem model

Environmental Science and Pollution Research - Recently, the production of silver nanoparticles and their commercial products has generated increased concern and caused a hazardous impact on the...     

Recent trends in microbial nanoparticle synthesis and potential application in environmental technology: a comprehensive review

Environmental Science and Pollution Research - Microbial technology comprising environment in various aspects of pollution monitoring, treatment of pollutants, and energy generation has been put...     

Seasonal variation of persistent organochlorine insecticide residues in Vellar River waters in Tamil Nadu, South India

Water samples collected from Vellar river and Pichavaran mangroves at Porto Novo (11 degrees 29' N, 79 degrees 46' E), Tamil Nadu State, South India, from December 1987 to January 1989 were analyzed to determine the seasonal variation of the levels of organochlorine insecticides such as HCH (BHC) and DDT. Both these insecticides showed higher levels from October to February, although this trend was more pronounced in HCH than DDT, reflecting the application of technical HCH largely and probably small quantities of DDT during the flowering season of rice. The alpha-HCH was detected as a dominant isomer for all seasons monitored followed by beta-HCH. Among DDT compounds, p,p'-DDT was the highest in river water except in the dry season when p,p'-DDD showed a higher percentage. On the other hand, in mangroves p,p'-DDE was highest during the wet season and p,p'-DDD during the dry season. Air-water partitioning data of HCH isomers and DDT compounds in Vellar river revealed that these chemicals tend to be in the water phase. These observations may aid in understanding the role of a tropical paddy area on the behavior and fate of man-made chemicals in view of worldwide contamination.