Methylcyclopentadienyl Manganese Tricarbonyl as an Antiknock: Composition and Fate of Manganese Exhaust Products

Methylcyclopentadienyl manganese tricarbonyl (MMT) has been marketed as a combustion improver for fuel oil and turbine fuel. Use concentrations for this purpose are about 0.025 g manganese/gal in fuel oil and 0.08 to 0.5 g/gal in turbine fuels. In addition, it has been used to a small extent in gasoline.     

Emission Control in Coking Operations By Use of Stage Charging

At the Clairton Coke Works of the United States Steel Corporation (the world’s largest coke plant), with coal charges of about 30,000 net tons per day, a system designated as “stage charging” has been developed for charging coal into the coke oven chamber without emissions to the atmosphere. The principles of the system are based on controlled sequential flow of the coal from the charging hoppers, during which the oven chamber is maintained under a very slight negative pressure condition by use of steam aspiration in the offtakes for on-the-main charging. The techniques are basic but require knowledge of the coal characteristics, adequate and properly maintained aspirating systems, including clean offtake piping, control of coal volume in the individual hoppers, and last, and probably most important, adherence by the operating crew to specific charging and leveling practices.     

Cooling Towers and the Environment

Measurements of natural draft cooling tower plume behavior, as well as meteorological variables, were obtained from aircraft flights near major power plants of the American Electric Power System. Persistence of the visible plume to great distances depends essentially on ambient humidity. Atmospheric stability at plume elevation was also important. Cooling tower-induced fog at ground-level was never observed in any of the tests, and aerodynamic downwash of the visible plume was absent also. The cooling towers did cause modification of natural clouds and they occasionally shadowed some local areas from the sun. Merging of the stack and cooling tower plumes was a common occurrence.     

Infrared Photography as an Air Pollution Surveillance Instrument

Remote sensing is an extremely new science which developed from World War II technology. At that time, infrared sensitive film (false color) was used to detect such things as troop movements and camouflaged war materials. In essence, the film displayed a color contrast between the artificial and organic vegetation.     

A Wind Tunnel Study of Gaseous Pollutants in City Street Canyons

Steady state mean concentrations of tracer gas were measured in a 400:1 scale model of an idealized city with variable geometry placed within a wind tunnel at various orientations to the mean flow for a free stream velocity of 6.8 ft/sec. The tracer gas was released from two parallel line sources to simulate lanes of traffic in an effort to quantify the persistence of pollution as well as the mean values realized at street levels. An aerodynamically rough turbulent boundary layer of neutral thermal stratification was employed to simulate the atmosphere. Values of concentration measured in the model city were converted to prototype concentrations in ppm and compared to National Ambient Air Quality Standards. It was shown that single isolated structures may cause favorable mixing of pollution downwind but very high concentrations exist in the immediate leeward vicinity of the building. Two favorable geometries for city blocks tested were found to reduce pedestrian exposure to pollution both near heavy traffic congestion and downwind. It was concluded that the pollutant dilution was controlled by the mean flow rather than by turbulent diffusion and that the lateral spread of the plume was slight as one proceeded downwind of the line source. The combination of favorable geometry and higher dilution velocities may bring pollution levels down to existing Air Quality Standards. The body of information presented in this paper should interest city planners and air quality monitoring personnel, as well as those researchers attempting to study and model flow in city street canyons. It provides order of magnitude estimates on pedestrian and office worker exposure to pollutants under a wide range of conditions.     

Flow Patterns Upstream of Isokinetic Dust Sampling Probes

In isokinetic sampling from a gas stream it is usually assumed that the flow pattern upstream of the sampling probe is not affected by the presence of the probe. That some probes do seriously affect the gas streamlines is shown by velocity traverses taken with a hot wire anemometer under controlled flow conditions in a wind tunnel. The degree to v/hich the streamlines are affected depends on the wall thickness and taper of the nozzle, the stem diameter, as well as on the size and proximity of sampling accessories in the vicinity of the nozzle. For a probe to cause negligible disturbance under isokinetic conditions it should have a sharp-edged nozzle with little or no outside bevel, and the stem of the probe should be at least 11 stem diameters downstream from the nozzle inlet.     

Electrostatic Precipitator Applications in the Paper Industry

A survey of paper industry applications of electrostatic precipita-tors reveals problem areas and compares operators' experience on both tile shell and heated steel jacket units. In addition, items such as dew point operation, corrosion, electrode cleaning, wire breakage, etc. are discussed.     

R&D Activities,Operating Experience Discussed at Fabric Alternatives Forum

ABSTRACT

Previously reported volatile organic compounds (VOC) radiocarbon (¹⁴C) measurements for 1992 summertime Atlanta, GA, have been compared with chromatographic data and emissions inventory predictions. The chromatographic approach that was used provided a more comprehensive VOC characterization than typically achieved, and the emissions inventory was research-grade level (date-, site-, and time-specific). The comparisons are in general agreement that biogenic emissions contribute only modestly (<10%) to the VOC content of the particular ambient samples that were collected and measured. The choices of sampling site (near city-center) and times (early morning and late evening) are major influences on the results, which consequently should not be regarded as representing the average VOC biogenic impact for the Atlanta area.