Tax policy and secondary material use

Legislative interest in policies to stimulate resource recovery has pointed out the need for an analysis of the determinants of materials flows. This paper characterizes the flows of virgin and secondary materials and explores in detail points where the two materials become substitute commodities. Econometric models specified at these points of substitution in the wastepaper and scrap steel industries are used to analyze various policy options being considered by Congress.     

Soils Characteristics of The Bassendean and Spearwood Sands of the Gnangara Mound (Western Australia) and their Controls On Recharge, Water Level Patterns and Solutes of The Superficial Aquifer

The flow pathways of water in the soils of the Gnangara Mound are highly irregular and depend upon the moisture content, the repellency and preferential wettability potential of the soils. The occurrence of preferential flow is more evident in dry soils. As the soil wets during the rainy season, the water repellence and differential wettability decreases, the fingering and the preferential flow paths disappear. Most of the agricultural sites in the Spearwood Sands which showed more irregular flow than the Bassendean Sands are under continuous irrigation during cultivation season. As the repellency problems are chemically treated, it is therefore expected that the flow will be more uniform all the year round. Landuse is mainly responsible for variation in recharge rates; however, the hydraulic properties control aquifer response and water level pattern to a greater degree. Water levels in the mid 1970s were in a semi steady state. Since that time, a combination of increasing water use by pine plantations, heavy pumping from private boreholes in market gardens and private homes and intensive pumping from the Gnangara Mound for the metropolitan water supply have caused water levels to continually decline in the Superficial aquifer. Nitrate and phosphate concentrations in the regional Superficial aquifer are generally very low. None of the tested pesticides (atrazine, diazinon, dimethoate, endosulfan, fenamiphos, iprodione, malathion and chlorpyrifos) were detected in the groundwater samples collected from the monitoring bores.     

Trihalomethane formation potential of filter isolates of electrolyte-extractable soil organic carbon

Certain organic C moieties of soil origin in drinking source waters of Sacramento-San Joaquin Delta (Delta) can react with chlorine to form trihalomethanes (THMs) during the disinfection process. Isolation and characterization of them and quantitation of their THM formation potential (THMFP) is necessary for developing effective strategies to reduce their influxes in Delta waters and for removing them during drinking water treatment. In this study, organic C from two Delta soils was extracted using deionized H(2)O and four Na- or Ca-based electrolytes of varying electrical conductivity values. Extracts were filtered into particulate, colloidal, fine colloidal, and soluble organic C for quantitation and THMFP determination. Results suggested that <1.5% of soil organic C was electrolyte-extractable. The soluble organic C fraction from both soils dominated in quantity and THMFP. Electrolyte effects were cation dependent. Sodium-based electrolytes at either conductivity level did not significantly decrease extractable organic C (EOC) or THMFP compared with deionized H(2)O. In contrast, Ca-based electrolytes reduced EOC and THMFP by >50% even at 1 dS m(-1). Further increase in Ca concentration did not significantly decrease EOC or THMFP. Most reduction in EOC and THMFP by Ca-based electrolytes occurred with the fractions other than the soluble organic C. Results suggested that under natural soil leaching and runoff conditions, the majority of THMFP is associated with organic C of <0.025 mum in diameter. Further molecular characterization of the fractions with high THMFP may help understand the nature of chlorine-reactive organic C from Delta soils.     

Microbial response to heavy metal-polluted soils: community analysis from phospholipid-linked fatty acids and ester-linked fatty acids extracts

Heavy metal pollution of soil is of concern for human health and ecosystem function. The soil microbial community should be a sensitive indicator of metal contamination effects on bioavailability and biogeochemical processes. Simple methods are needed to determine the degree of in situ pollution and effectiveness of remediating metal-contaminated soils. Currently, phospholipid-linked fatty acids (PLFAs) are preferred for microbial profiling but this method is time consuming, whereas direct soil extraction and transesterification of total ester-linked fatty acids (ELFAs) is attractive because of its simplicity. The 1998 mining acid-metal spill of >4000 ha in the Guadiamar watershed (southwestern Spain) provided a unique opportunity to study these two microbial lipid profiling methods. Replicated treatments were set up as nonpolluted, heavy metal polluted and reclaimed, and polluted soils. Inferences from whole community-diversity analysis and correlations of individual fatty acids with metals suggested Cu, Cd, and Zn were the most important in affecting microbial community structure, along with pH. The microbial stress marker, monounsaturated fatty acids, was significantly lower for reclaimed and polluted soil over nonpolluted soils for both PLFA and ELFA extraction. Another stress marker, the monounsaturated to saturated fatty acids ratio, only showed this for the PLFA. The general fungal marker (18:2omega6c), the arbuscule mycorrhizae marker (16:1omega5c), and iso- and anteiso-branched PLFAs (gram positive bacteria) were suppressed with increasing pollution whereas 17:0cy (gram negative bacteria) increased with metal pollution. For both extraction methods, richness and diversity were greater in nonpolluted soils and lowest in polluted soils. The ELFA method was sensitive for reflecting metal pollution on microbial communities and could be suitable for routine use in ecological monitoring and risk assessment programs because of its simplicity and reproducibility.     

Modified Fenton's processes for effective in‐situ chemical oxidation—Laboratory and field evaluation

Fenton's reagent in its conventional form, although effective for contaminant treatment, is impractical from an in‐situ field application perspective due to low pH requirements (i.e., pH 3‐4), and limited reagent mobility when introduced into the subsurface. Modified Fenton's processes that use chelated‐iron catalysts and stabilized hydrogen peroxide have been developed with the goal of promoting effective in‐situ field application under native pH conditions (i.e., pH 5‐7), while extending the longevity of hydrogen peroxide. Laboratory experiments conducted in soil columns packed with organic soil to compare modified Fenton's catalysts with conventional catalysts (acidified iron [II]) indicated superior mobility and sorption characteristics for modified Fenton's catalysts. Furthermore, the acidic pH of a conventional catalyst was buffered to the native soil range, leading to increased iron precipitation/adsorption following permeation through the soil column. The chelates present within the modified Fenton's catalyst showed greater affinity toward iron compared with the native soil and, hence, minimized iron loss through adsorption during the permeation process even at pH 5‐7. Field effectiveness of the modified Fenton's process was demonstrated at a former dry‐cleaning facility located in northeast Florida. Preliminary laboratory‐scale experiments were conducted on soil‐slurry and groundwater samples to test the process efficacy for remediation of chlorinated solvents. Based on successful experimental results that indicated a 94 percent (soil slurry) to 99 percent (groundwater) reduction of cis‐1,2‐DCE, PCE, and TCE, a field‐scale treatment program was initiated utilizing a plurality of dual‐zone direct push injection points installed in a grid fashion throughout the site. Results of treatment indicated a 72 percent reduction in total chlorinated contamination detected in the site groundwater following the first injection event; the reduction increased to 90 percent following the second injection event. © 2002 Wiley Periodicals Inc.     

THE LODGING VELOCITY FOR EMERGENT AQUATIC PLANTS IN OPEN CHANNELS1

ABSTRACT: The growth of aquatic plants in open‐channels has many adverse environmental effects including, but not limited to, impeding the transport of water, hindering navigation, increasing flood elevations, increasing sediment deposition, and degrading water quality. Existing control strategies include physical removal and chemical treatment. Physical removal is only a temporary solution and chemical treatment is unacceptable if the water will be consumed by humans. The hydrodynamic method can wash out the encroached aquatic plants by keeping flow velocity higher than the critical velocity required to bend and rupture (lodge) their stems. This approach is a promising, physically‐based, efficient, economic, and permanent solution for this problem. However, the success of this approach requires the accurate prediction of the critical lodging velocity. This paper presents an analytic study of the lodging velocity for the submerged portion of aquatic plants of narrow leaved emergent stems that are wider at bottom than the top. Based on the principles of engineering materials and the theory of turbulent flow, a semi‐empirical formula is derived for the prediction of the critical lodging velocity. It indicates that the lodging of aquatic plants is controlled not only by flow conditions but also the geometric and mechanical characteristics of the plants. These analytic results provide a satisfactory explanation of the lodging phenomena observed in the field and are verified by the available experimental data.     

AN EVALUATION OF PHYSICAL STREAM HABITAT ATTRIBUTES USED TO MONITOR STREAMS1

ABSTRACT: The last few decades have seen an increased reliance on the use of stream attributes to monitor stream conditions. The use of stream attributes has been criticized because of variation in how observers evaluate them, inconsistent protocol application, lack of consistent training, and the difficulty in using them to detect change caused by management activity. In this paper, we evaluate the effect of environmental heterogeneity and observer variation on the use of physical stream attributes as monitoring tools. For most stream habitat attributes evaluated, difference among streams accounted for greater than 80 percent of the total survey variation. To minimize the effect that variation among streams has on evaluating stream conditions, it may be necessary to design survey protocols and analysis that include stratification, permanent sites, and/or analysis of covariance. Although total variation was primarily due to differences among streams, observers also differed in their evaluation of stream attributes. This study suggests that if trained observers conducting a study that is designed to account for environmental heterogeneity can objectively evaluate defined stream attributes, results should prove valuable in monitoring differences in reach scale stream conditions. The failure to address any of these factors will likely lead to the failure of stream attributes as effective monitoring tools.     

THE STRUCTURE AND PRACTICE OF WATER QUALITY TRADING MARKETS1

ABSTRACT: The use of transferable discharge permits in water pollution, what we will call water quality trading (WQT), is rapidly growing in the U.S. This paper reviews the current status of WQT nationally and discusses the structures of the markets that have been formed. Four main structures are observed in such markets: exchanges, bilateral negotiations, clearinghouses, and sole source offsets. The goals of a WQT program are environmental quality and cost effectiveness. In designing a WQT market, policy makers are constrained by legal restrictions and the physical characteristics of the pollution problem. The choices that must be made include how trading will be authorized, monitored and enforced. How these questions are answered will help determine both the extent to which these goals are achieved, and the market structures that can arise. After discussing the characteristics of different market structures, we evaluate how this framework applies in the case of California's Grassland Drainage Area Tradable Loads Program.     

Promoting internalized motivation for environmentally responsible behavior: A prospective study of environmental goals

We used a prospective design and structural equation modeling procedures to examine the processes by which people internalize the doing of new environmental behaviors. As predicted by self-determination theory (Deci & Ryan, 1985: Intrinsic Motivation and Self-determination in Human Behaviour, Plenum, New York; Deci & Ryan, 2000: Psychol. Inquiry 11, 227), participants who perceived the experimenter as autonomy-supportive evidenced greater internalized motivation regarding a set of self-selected environmental goals. Internalized motivation in turn predicted goal performance during the following week, which in turn predicted intentions to keep on striving after the study was over. Implications for the question of how to motivate people to engage in more environmentally responsible behavior are discussed.