A passive sampling device for determining formaldehyde in indoor air

A passive sampling device based on the principle of diffusion has been developed for the determination of formaldehyde in ambient air. The sampler consists of a capped glass tube (with approximate dimensions of 2.4 × 9 cm) containing a glass-fiber filter treated with NaHSO₃. In the field, the device collects a sample by being uncapped for a specified sampling time. After being recapped and returned to the laboratory, the filter is analyzed by the chromotropic acid (CTA) method. Laboratory validation studies were conducted by exposing the sampling devices for 1 week to dry formaldehyde gas generated by passing trioxane vapor over an acid catalyst bed. In these tests, formaldehyde concentrations ranged from 0.05 to 0.80 mL/m³. Reproducibility was excellent, with relative standard deviations averaging 5.4% for five constant concentrations. The lower detection limit was determined to be 3.6 mL/m³ h. In an occupational environment an 8-h sample would be sufficient to detect compliance with the OSHA permissible exposure limit of 3 mL/m³; in a residential environment a 1-week sample would allow detection of 0.025 mL/m³ for indoor air quality audits.     

Effects of head restraint and seat redesign on neck injury risk in rear-end crashes

Automobile insurance claims were examined to determine the rates of neck injuries in rear-end crashes for vehicles with and without redesigned head restraints, redesigned seats, or both. Results indicate that the improved geometric fit of head restraints observed in many newer vehicle models are reducing the risk of whiplash injury substantially among female drivers (about 37% in the Ford Taurus and Mercury Sable), but have very little effect among male drivers. New seat designs, such as active head restraints that move upward and closer to drivers' heads during a rear impact, give added benefit, producing about a 43% reduction in whiplash injury claims (55% reduction among female drivers). Estimated effects of Volvo's Whiplash Injury Prevention System and Toyota's Whiplash Injury Lessening design were based on smaller samples and were not statistically significant.     

Prediction of cervical spine injury risk for the 6-year-old child in frontal crashes

This article presents a series of 49 km/h sled tests using the Hybrid III 6-year-old dummy in a high-back booster, a low-back booster, and a three-point belt. Although a 10-year review at a level I trauma center showed that noncontact cervical spine injuries are rare in correctly restrained booster-age children, dummy neck loads exceeded published injury thresholds in all tests. The dummy underwent extreme neck flexion during the test, causing full-face contact with the dummy's chest. These dummy kinematics were compared to the kinematics of a 12-year-old cadaver tested in a similar impact environment. The cadaver test showed neck flexion, but also significant thoracic spinal flexion which was nonexistent in the dummy. This comparison was expanded using MADYMO simulations in which the thoracic spinal stiffness of the dummy model was decreased to give a more biofidelic kinematic response. We conclude that the stiff thoracic spine of the dummy results in high neck forces and moments that are not representative of the true injury potential.     

Chemical extraction methods to assess bioavailable arsenic in soil and solid media

Soil ingestion by children is an important pathway in assessing public health risks associated with exposure to arsenic-contaminated soils. Soil chemical methods are available to extract various pools of soil arsenic, but their ability to measure bioavailable arsenic from soil ingestion is unknown. Arsenic extracted by five commonly used soil extractants was compared with bioavailable arsenic measured in vivo by immature swine (Sus scrofa) dosing trials. Fifteen contaminated soils that contained 233 to 17 500 mg kg(-1) arsenic were studied. Soil extractants were selected to dissolve surficially adsorbed and/or readily soluble arsenic (water, 1 M sodium acetate, 0.1 M Na2HPO4/0.1 M NaH2PO4) and arsenic in Fe and Mn oxide minerals (hydroxylamine hydrochloride, ammonium oxalate). The mean percent of total arsenic extracted was: ammonium oxalate (53.6%) > or = hydroxylamine hydrochloride (51.7%) > phosphate (10.5%), acetate (7.16%) > water (0.15%). The strongest relationship between arsenic determined by soil chemical extraction and in vivo bioavailable arsenic was found for hydroxylamine hydrochloride extractant (r = 0.88, significant at the 0.01 probability level). Comparison of the amount of arsenic extracted by soil methods with bioavailable arsenic showed the following trend: ammonium oxalate, hydroxylamine hydrochloride > in vivo > phosphate, acetate > water. The amount of arsenic dissolved in the stomach (potentially bioavailable) is between surficially adsorbed (extracted by phosphate or acetate) and surficially adsorbed + nonsurficial forms in Fe and Mn oxides (extracted by hydroxylamine hydrochloride or ammonium oxalate). Soil extraction methods that dissolve some of the amorphous Fe, such as hydroxylamine hydrochloride, can be designed to provide closer estimates of bioavailable arsenic.     

Evaluation of leachate composition by multivariate data analysis (MVDA)

Landfills generate emissions in the form of gas and leachate. The emissions are often measured within monitoring programmes. It is likely that the requirements of such monitoring programmes can be extended in the future, particularly in light of the increased interest in specific organic substances. Multivariate data analyses (MVDA) have been used to evaluate the possibility of predicting the content of specific organic substances from more common analyses. The results indicate that this is possible for a specific leachate. MVDA can also be used to reduce the number of analyses performed within existing monitoring programmes while retaining information about all the variables formerly included in the programmes.     

Agricultural Land Use Effects on Sediment Loading and Fish Assemblages in Two Minnesota (USA) Watersheds

We examined the relationship between water quality and fish communities within two agricultural areas using a computer simulation model. Our analyses focused on a coolwater stream, Wells Creek in southeastern Minnesota, and a warmwater stream, the Chippewa River in western Minnesota. We used the Agricultural Drainage and Pesticide Transport (ADAPT) model in relation to land use to calculate instream suspended sediment concentrations using estimates of sediment delivery, runoff, baseflow and streambank erosion, and quantified the effects of suspended sediment exposure on fish communities. We predicted the effects of agricultural practices on stream fish communities under several possible land use scenarios, with reference to current conditions. Land use changes led to reductions in sediment loading of up to 84% in Wells Creek and 49% in the Chippewa River. The reduction in sediment loading across scenarios may be directly related to a reduction in runoff by about 35% in both study areas. We found a 98% decrease in lethal concentrations of suspended sediment on fish in Wells Creek with an increase in conservation tillage, riparian buffers, and permanent vegetative cover. However, the effects of suspended sediment did not significantly decrease in the Chippewa River. This difference between study areas was likely due to differences in tolerance to suspended sediment between coolwater and warmwater fish communities and differences in topography, runoff and bank erosion between the two streams. The Minnesota Cooperative Fish and Wildlife Research Unit is jointly sponsored by the US Geological Survey, the University of Minnesota, the Minnesota Department of Natural Resources, and the Wildlife Management Institute.     

An Evaluation of Vernal Pool Creation Projects in New England: Project Documentation from 1991–2000

Vernal pools are vulnerable to loss through development and agricultural and forestry practices owing to their isolation from open water bodies and their small size. Some vernal pool-dependent species are already listed in New England as Endangered, Threatened, or Species of Special Concern. Vernal pool creation is becoming more common in compensatory mitigation as open water ponds, in general, may be easier to create than wooded wetlands. However, research on vernal pool creation is limited. A recent National Research Council study (2001) cites vernal pools as challenging to recreate. We reviewed documentation on 15 vernal pool creation projects in New England that were required by federal regulatory action. Our purpose was to determine whether vernal pool creation for compensatory mitigation in New England replaced key vernal pool functions by assessing project goals and documentation (including mitigation plans, pool design criteria, monitoring protocols, and performance standards). Our results indicate that creation attempts often fail to replicate lost pool functions. Pool design specifications are often based on conjecture rather than on reference wetlands or created pools that function successfully. Project monitoring lacks consistency and reliability, and record keeping by regulatory agencies is inadequate. Strengthening of protection of isolated wetlands in general, and standardization across all aspects of vernal pool creation, is needed to ensure success and to promote conservation of the long-term landscape functions of vernal pools.     

Implications of fluoride--an endless uncertainty

Fluorosis has become pandemic and it has assumed global status in the public health point of view. The paper deals with the health issues pertaining to fluorosis with special emphasis in the Indian context. It explains the equivocal evidences of fluoride-related problems and discusses the control measures of fluorosis. In general, it reveals how fluoride is useful at very low concentrations and at the same time brings forth manifestation of clinical abnormalities at higher concentrations that are the basis of the principles of toxicology.     

Feed utilisation and growth in juveniles of Labeo rohita under the stress of endosulfan

The objective of the present study is to evaluate the nutrition and growth of Labeo rohita under the sublethal stress of endosulfan. It has been observed that the feed utilisation and growth were inferior in the fish under the stress of the toxicant. It was more so in the test fish under the influence of higher sublethal concentration. The food conversion ratio was higher suggesting that the nutrients are wasted.