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51.
An improved dynamic coupled column liquid chromatographic (DCCLC) technique for determining water solubility data of hydrophobic compounds is presented. The technique is based on pumping water through a thermostated generator column in order to generate emulsion-free, saturated aqueous solutions of the compound under study. Through a switching valve system the solute in the aqueous solution is extracted and concentrated by an on-line solid-phase extraction process and subsequently eluted and analyzed by high performance liquid chromatography (fluorescence detection coupled to photodiode array detection). The improvements carried out to the original DCCLC technique have given rise to savings in time for the experimental work and increased sensitivity during the detection and quantification stage. Applicability of the method for studying highly hydrophobic substances is demonstrated by determining water solubility of anthracene and pyrene in the temperature range of 8.9-49.9 and 8.5-32.2 degrees C, respectively. The measured water solubilities are in good agreement with the best available literature data. The method has also been applied to the determination of water solubility of m-terphenyl, 9, 10-dihydrophenanthrene and guaiazulene, in the temperature range of 4.8-49.9, 4.8-25.0, and 4.5-29.9 degrees C, respectively. The uncertainty in the Sw values determined in this work ranged from 0.7% to 4.6%. The experimental water solubility data, as a function of temperature, are fitted to the equation In Sw = A + B/T; where Sw and T are given in mole fraction and Kelvin, respectively. 相似文献
52.
Nora Escribano Arturo H. Ariño Andrea Pino-del-Carpio David Galicia Rafael Miranda 《Conservation biology》2021,35(6):1894-1902
Zoos and aquaria, often regarded as preservation-cum-entertainment enterprises, are also actors in the effort to curb the biodiversity crisis: raising awareness, supporting conservation, and conducting research. We assessed trends in zoo and aquaria research topics and study organisms over time worldwide. For the zoos and aquaria registered in the Species360's Zoological Information Management System and the World Association of Zoos and Aquariums, we compiled metadata on their research published in the peer-reviewed literature indexed in Scopus and carried out a keyword frequency analysis. The production of scientific papers by zoos increased at a much faster rate than the average accrual of scientific papers in the literature. Evolution of research themes ran parallel to that of biological sciences (e.g., development of molecular genetics or increased awareness about conservation). The focus of 48.5% of zoo-led research was on vertebrates, of which mammal research was 33.7%. Whether zoos are effectively contributing to conservation may still be debatable, but our results highlight their institutional efforts to increase knowledge about the species in their care. 相似文献
53.
Collaborative problem solving has increasingly become important in the face of the complexities in the management of resources, including protected areas. The strategy undertaken by Girringun Aboriginal Corporation in north tropical Queensland, Australia, for developing co-management demonstrates the potential for a problem solving approach involving sequential initiatives, as an alternative to the more familiar negotiated agreements for co-management. Our longitudinal case study focuses on the development of indigenous ranger units as a strategic mechanism for the involvement of traditional owners in managing their country in collaboration with government and other interested parties. This was followed by Australia's first traditional use of marine resources agreement, and development of a multi-jurisdictional, land to sea, indigenous protected area. In using a relationship building approach to develop regional scale co-management, Girringun has been strengthening its capabilities as collaborator and regional service provider, thus, bringing customary decision-making structures into play to 'care for country'. From this evolving process we have identified the key components of a relationship building strategy, 'the pillars of co-management'. This approach includes learning-by-doing, the building of respect and rapport, sorting out responsibilities, practical engagement, and capacity-building. 相似文献
54.
Assessment of Water Supply as an Ecosystem Service in a Rural-Urban Watershed in Southwestern Mexico City 总被引:1,自引:0,他引:1
Jujnovsky J González-Martínez TM Cantoral-Uriza EA Almeida-Leñero L 《Environmental management》2012,49(3):690-702
Studies from the ecosystem services perspective can provide a useful framework because they allow us to fully examine the
benefits that humans obtain from socio-ecological systems. Mexico City, the second largest city in the world, has faced severe
problems related to water shortages, which have worsened due to increasing population. Demand for space has forced changes
in land cover, including covering areas that are essential for groundwater recharge. The city has 880 km2 of forest areas that are crucial for the water supply. The Magdalena River Watershed was chosen as a model because it is
a well-preserved zone within Mexico City and it provides water for the population. The general aim of this study was to assess
the ecosystem service of the water supply in the Magdalena River Watershed by determining its water balance (SWAT model) and
the number of beneficiaries of the ecosystem services. The results showed that the watershed provides 18.4 hm3 of water per year. Baseflow was dominant, with a contribution of 85%, while surface runoff only accounted for 15%. The zone
provides drinking water to 78,476 inhabitants and could supply 153,203 potential beneficiaries. This work provides an example
for understanding how ecosystem processes determine the provision of ecosystem services and benefits to the population in
a rural–urban watershed in Mexico City. 相似文献
55.
Arturo U. Rodriguez Subrata B. Ghosh Robert Jeng Mohini M. Sain 《Journal of Polymers and the Environment》2010,18(3):430-436
Starches modified by Ophiostoma spp. have been investigated to develop bio-materials with enhanced mechanical and physical properties for thermoplastic applications.
In this study, glass transition temperature (Tg) of modified starches was investigated in both dynamic mechanical analyzer (DMA) and differential scanning calorimeter (DSC)
to detect molecular changes in the starch’s structure. Overall, two thermal transitions were observed in modified starches,
as opposed to one in their native counterparts. Scanning electron microscopy of granular modified starch indicated visible
damages and internal structural perturbations in addition to occlusion of granular pores by extraneous materials owing to
possible enzymatic degradation and production of secondary metabolites. Modified starches registered two-fold improvement
in storage modulus as compared to that of native starches. From the study of second derivative of the mass loss against temperature,
two thermal transitions were also identified in modified starches. X-ray diffraction analyses showed that crystalline regions
of the starch granules remained intact after the modification. It is proposed that the second phase transition potentially
corresponds to modified amylose fractions and/or exopolysaccharides produced by the fungi. 相似文献
56.
We estimate the Marginal Cost of Public Funds (MCPF) for Peru using a detailed computable general equilibrium (CGE) model. Revenues from all major sources (including taxes on factors of production, natural resources such as energy and minerals, consumption, and imports) are examined. Our focus is on the efficiency implications of mineral and energy taxes, given their importance to Peruvian public finance. The primary data are from the Global Trade Analysis Project (GTAP) as modified to include detailed tax information from the Peruvian Ministry of Economy and Finance and the Peruvian Internal Revenue Service. Consistent with the theories of public finance, we find that the MCPF is greater for activities that face high or widely varying tax rates. The taxes on energy and mineral activities represent a clear illustration of this relationship. The results presented in this paper indicate opportunities to improved efficiency in the current tax mix, and also indicate the financing costs of proposed expenditures that would be funded with taxes on energy and natural resources. 相似文献
57.
Protected Areas and Conservation of Biodiversity in the Tropics 总被引:7,自引:0,他引:7
G. Arturo Sánchez-Azofeifa Carlos Quesada-Mateo † Pablo Gonzalez-Quesada † S. Dayanandan ‡ AND Kamaljit S. Bawa§ 《Conservation biology》1999,13(2):407-411
Abstract: We compared deforestation rates and the extent of fragmentation inside and outside protected areas in the Sarapiquí region of Costa Rica. We determined deforestation rates using remotely sensed images with supervised classification. We georeferenced the processed images and then transformed them to vector format for final mapping and parameter quantification. The deforestation rate in protected areas was low and declined sharply from 0.56% annually between 1976 and 1986 to 0.16% from 1991 to 1995. Outside the protected areas, the rate decreased from 3.6% in 1976–1986 to 2.8% in 1986–1991, but it increased again to 3.2% in 1991–1995. Fragmentation outside the protected areas increased considerably: the number of patches increased from 537 in 1976 to 1231 in 1996, while during the same period the average size of patches decreased from 0.95 to 0.25 km2 . Forest landscapes in the Sarapiquí region are likely to lose considerable biodiversity because of the past forest loss and fragmentation even without further increases in deforestation and fragmentation. 相似文献
58.
Arturo Torres-Dosal Rebeca Isabel Martinez-Salinas Diego Hernandez-Benavides Francisco Javier Perez-Vazquez Cesar Ilizaliturri-Hernandez Ivan Nelinho Perez-Maldonado 《Environmental monitoring and assessment》2012,184(12):7551-7559
In Mexico, 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) was used until the year 2000, principally in agriculture and anti-paludal program health campaigns. The southeastern region of Mexico was an important area of malaria, and from 1957 DDT was applied indoors every 6?months, with a coverage of 2?g/m2. The current study was performed in Tabasco, a Mexican state located in the southeastern region of Mexico. DDT and 1,1-dichloro-2,2-bis(4-chlorophenyl)ethene (DDE) were analyzed by gas chromatography/mass spectrometry. In general, low levels were found in household outdoor samples; the levels of DDT ranged from not detectable to 0.048?mg/kg, and of DDE from 0.001 to 0.068?mg/kg. An important finding was that, in all communities where DDT in blood was analyzed, exposure to DDT was found, indicating both past and present exposure. Although the levels found in this study were lower than other studies in Mexico, there is a need to evaluate whether the people living in the study area are at risk. 相似文献
59.
Abstract: Systematic consideration of uncertainty in data, model structure, and other factors is generally unaddressed in most Total Maximum Daily Load (TMDL) calculations. Our previous studies developed the Management Objectives Constrained Analysis of Uncertainty (MOCAU) approach as an uncertainty analysis technique specifically for watershed water quality models, based on a synthetic case. In this study, we applied MOCAU to analyze diazinon loading in the Newport Bay watershed (Southern California). The study objectives included (1) demonstrating the value of performing stochastic simulation and uncertainty analysis for TMDL development, using MOCAU as the technique and (2) evaluating the existing diazinon TMDL and generating insights for the development of scientifically sound TMDLs, considering uncertainty. The Watershed Analysis Risk Management Framework model was used as an example of a complex watershed model. The study revealed the importance and feasibility of conducting stochastic watershed water quality simulation for TMDL development. The critical role of management objectives in a systematic uncertainty assessment was well demonstrated. The results of this study are intuitive to TMDL calculation, model structure improvement and sampling strategy design. 相似文献
60.
Martijn Mes Marco Schutten Arturo Pérez Rivera 《Waste management (New York, N.Y.)》2014,34(9):1564-1576
We consider the problem of collecting waste from sensor equipped underground containers. These sensors enable the use of a dynamic collection policy. The problem, which is known as a reverse inventory routing problem, involves decisions regarding routing and container selection. In more dense networks, the latter becomes more important. To cope with uncertainty in deposit volumes and with fluctuations due to daily and seasonal effects, we need an anticipatory policy that balances the workload over time. We propose a relatively simple heuristic consisting of several tunable parameters depending on the day of the week. We tune the parameters of this policy using optimal learning techniques combined with simulation. We illustrate our approach using a real life problem instance of a waste collection company, located in The Netherlands, and perform experiments on several other instances. For our case study, we show that costs savings up to 40% are possible by optimizing the parameters. 相似文献