Validation of QuEChERS method for the determination of 36 pesticide residues in fruits and vegetables from Ghana,using gas chromatography with electron capture and pulsed flame photometric detectors

In this study, “Quick, Easy, Cheap, Effective, Rugged and Safe” ‘QuEChERS’ method was modified for the determination of 36 pesticides fortified at (0.01–1.0) mg kg^?1 in three vegetables and a fruit (lettuce, carrot, tomatoes and pineapples respectively) from Ghana. The method involved extraction with acetonitrile, phase separation with primary secondary amine and magnesium sulfate; the final injection solution was reconstituted in ethyl acetate. Organochlorine and synthetic pyrethroids residues were detected with electron capture detector whereas organophosphorus, pulsed flame photometric detector was used. The recoveries at different concentration levels (0.01, 0.1 and 1.0 mg kg^?1) were in the range of 83% and 93% with relative standard deviation ranging from 2% to 10% (n = 5) and the coefficient of determination (R²) was greater than 0.99 for all the 36 pesticides. The method was successfully tested on 120 real samples from Accra markets and this proved to be useful for monitoring purposes particularly in laboratories that have no gas chromatography-mass spectrometry and liquid chromatography-mass spectrometry.     

Modelling the connection between energy consumption and carbon emissions in North Africa: Evidence from panel models robust to cross-sectional dependence and slope heterogeneity

Environment, Development and Sustainability - This paper explored the link between energy consumption and carbon emissions in North Africa through an Environmental Kuznets Curve (EKC) framework....     

Pesticide residues in fruits and vegetables in Ghana: a review

Pesticides are known to improve agriculture yield considerably leading to an increase in its application over the years. The use of pesticides has shown varying detrimental effects in humans as well as the environment. Presently, enough evidence is available to suggest their misuse and overuse in the last few decades in most developing nations primarily due to lack of education, endangering the lives of farmers as well as the entire population and environment. However, there is paucity of data especially over long durations in Ghana resulting in the absence of effective monitoring programs regarding pesticide application and subsequent contamination in fruits and vegetables. Therefore, this review discusses comprehensively pesticide type and use, importation, presence in fruits and vegetables, human exposure, and poisoning in Ghana. This is to alert the scientific community in Ghana of the need to further research into the potential implications of pesticide residues in food commodities in order to generate a comprehensive and reliable database which is key in drafting policies simultaneous with food regulation, suitable monitoring initiatives, assessment, and education to minimize their effects thereon.     

Farmers' perceptions of constraints to plantain production in Ghana

SUMMARY

Plantain (Musa AAB), a primary food crop in Ghana, is a key component in sustainable agricultural systems in high rainfall zones. Recently, there has been a substantial yield decline and reduction in plantation life. To elucidate the context in which intervention strategies should be developed, a Participatory Rural Appraisal (PRA) was conducted at five villages in the major plantain-producing belt of Ghana. The importance of plantain as a preferred food was confirmed, although farmers tended to sell plantain for cash income, using cheaper, less preferred alternatives for home consumption. Farmers identified decreasing soil fertility, the high cost of labour for weeding, pests and diseases, lack of good quality planting material and marketing-related issues as the major production constraints. Due to declining productivity in less fertile regions, plantain has been replaced with other food crops such as cassava and maize. Farmers overestimated the importance of insect pests but were unaware of the extensive damage that could be caused by nematodes and the foliar disease, black sigatoka. They observed, however, that pest damage is more severe when soil fertility is poor. Clearly, integrated pest management is likely to be most effective when practiced within the context of cropping systems management; sustainable strategies that are being developed for resource-limited plantain farmers in Ghana are discussed.     

非洲的小规模渔业、人口动态和资源利用--以加纳莫里为例

我们研究莫里的人口动态和渔业资源的开发和持续利用问题.莫里是加纳中部靠近海岸角的一个有2万人口的以捕鱼为生的小镇.莫里的情况说明人口动态和渔业资源之间的关系要比"马尔萨斯过度捕捞说"复杂得多.这其中的原因包括:西非沿岸上升流不断变化的生物物理特征;全年中捕捞活动性质和数量上的变化;市场状况和鱼产品的异地需求;捕捞活动有规律的迁移以及规范当地和迁移目的地渔业资源使用的制度.莫里的人口和资源的关系可能是渔业资源和经济变化影响了人口迁移而不是人口压力影响了渔业资源.渔业管理政策必须考虑当地渔民影响之外的过程和因素.     

(Mal)Adaptation opportunism: when other interests take over stated or intended climate change adaptation objectives (and their unintended effects)

This paper introduces the terminology of (mal)adaptation opportunism – a situation in which projects undertaken in the name of climate change adaptation (CCA) are overrun by interests other than the stated or intended objectives of the CCA project. A goal of CCA projects is to reduce poverty and promote social justice. The case of the threat of displacement of the community of Kewunor by the Trasacco Estate Development Company (TEDC), after the construction of the Ada Sea Defense System (AdSDS) of Ghana as a CCA, is illustrative of this concept of (mal)adaptation opportunism. Through a narrative presentation of eight different accounts concerning this issue, I demonstrate how (mal)adaptation opportunism arises and is often motivated by economic interests. This case illustrates how economic interests can take over not only CCA projects but also their maladaptive effects.     

Effect of silica additive on the thermal stability of catalysts for NOx abatement

The aim of the plesent investigation was to study the effect of SiO₂ addition on the thermal deactivation of V₂O₅/WO₃/TiO₂ catalysts used for NOx pollution abatement. The results suggest that the degradation of the catalytic properties is strongly correlated to the structural ageing which is, in turn, mainly related to the anatase–rutile phase transformation and to the WO₃ phase segregation. The addition of SiO₂ strongly influences the temperature at which these phenomena occur. In fact, it was found that the introduction of this oxide stabilizes the material, retarding the collapse of surface area, and increases the temperature of the anatase to rutile phase transition.     

HYDROLOGIC ENGINEERING TECHNIQUES FOR REGIONAL WATER RESOURCES PLANNING1

The emphasis upon comprehensive regional water resources planning in the past decade has encouraged the hydrologic engineer to take advantage of improvements in technology to develop new hydrologic engineering techniques for use in regional planning studies. The new techniques are necessary because the traditional hydro-logic engineering techniques are not always consistent with the increased scope and diversified objectives of regional planning studies. The Hydrologic Engineering Center has been involved in aiding in the development of some of these new techniques as the result of studies that have been made in cooperation with other Corps of Engineers offices. Most of the new techniques being developed emphasize computational procedures developed specifically for use with electronic computers. Applications of new techniques range from framework studies to planning of day-to-day operation criteria. Studies recently completed or in progress include: (1) development of a regional flood control site screening plan for the North Atlantic Region study; (2) use of streamflow simulation for planning and operation of the Missouri River mainstem projects; (3) development of an operation plan for the Arkansas-White-Red Rivers Reservoir System; (4) standard project flood and flood frequency estimates for the Colorado River Basin Framework Study; and several other projects which are described in more detail in the following paragraphs. One of the initial efforts in regional analysis was the formulation of procedures for determining standard project flood estimates for southern California coastal streams using generalized criteria. Techniques were developed that were readily adaptable to the computer and which would determine representative unit hydrographs, losses and standard project precipitation for any location in the study area. The resulting standard project flood estimates were consistent with the accuracy required for framework studies; however, they could be refined easily for design studies. As a result of the recent drought in the Northeastern United States, a study was made to evaluate both present and future water supply reservoirs in that region. The study consisted of computerized studies of the hypothetical operation of a large number of reservoirs as a system. The reservoirs were on many different streams throughout the region and had varying constraints, depending upon the stream and the state in which the reservoir was located. Since only preliminary data was available on the proposed reservoirs, it was not possible to refine the studies to a large degree. However, the models of each system can be easily refined as more accurate design data become available. The development of a computer-aided screening procedure for use in evaluating several hundred potential reservoir sites for the Missouri River Basin Comprehensive Framework Study is a third example of regional analysis. The adopted procedures used available physical, hydrologic, and climatologic data in estimating reservoir storage requirements throughout the basin. Because the procedure is based upon the techniques often used in more refined studies, it is expected that the results of the screening study will be very useful in future planning and design work. Shortcomings of some of the traditional techniques have helped in the development of new techniques. For maximum usefulness the new techniques should: (1) be consistent with the scope, objectives, and requirements of the overall study; (2) use all available physical, hydrologic, and climatologic data without requiring extensive data which may not be available; (3) take full advantage of the capabilities of the computer and associated data processing systems; and (4) produce results which form a firm basis for future, more detailed, planning and design studies instead of being limited in usefulness largely to the study at hand.     

Synthesis of Biobased Soft-Packaging Polyesters from 2,5 Thiophenedicarboxylic Acid

Journal of Polymers and the Environment - Demand for light-packaging materials for food and beverages is on the rise globally, especially in developing countries where several depend on packaged...