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901.
Effect of sublethal treatment of (40% and 60% of 48 h LC50) of deltamethrin+MGK on phospholipid level and rate of lipid peroxidation in nervous and foot tissue of Lymnaea acuminata were studied. Maximum reduction in phospholipid (24.10%) level and increase in rate of lipid peroxidation (586.8%) were observed in foot tissue of snail exposed to 60% of 48 h LC50 of deltamethrin+MGK 264 for 96 h. Alterations in the levels of phospholipids and rate of lipid peroxidation were time and concentration dependent. Use of MGK-264 with deltamethrin increases the toxicity of deltamethrin and their action on membrane phospholipids and rate of lipid peroxidation. 相似文献
902.
Understanding the fundamentals of arsenic adsorption and oxidation reactions is critical for predicting its transport dynamics in groundwater systems. We completed batch experiments to study the interactions of arsenic with a common MnO2(s) mineral, pyrolusite. The reaction kinetics and adsorption isotherm developed from the batch experiments were integrated into a scalable reactive transport model to facilitate column-scale transport predictions. We then completed a set of column experiments to test the predictive capability of the reactive transport model. Our batch results indicated that the commonly used pseudo-first order kinetics for As(III) oxidation reaction neglects the scaling effects with respect to the MnO2(s) concentration. A second order kinetic equation that explicitly includes MnO2(s) concentration dependence is a more appropriate kinetic model to describe arsenic oxidation by MnO2(s) minerals. The arsenic adsorption reaction follows the Langmuir isotherm with the adsorption capacity of 0.053micromol of As(V)/g of MnO2(s) at the tested conditions. The knowledge gained from the batch experiments was used to develop a conceptual model for describing arsenic reactive transport at a column scale. The proposed conceptual model was integrated within a reactive transport code that accurately predicted the breakthrough profiles observed in multiple column experiments. The kinetic and adsorption process details obtained from the batch experiments were valuable data for scaling to predict the column-scale reactive transport of arsenic in MnO2(s)-containing sand columns. 相似文献
903.
Babu SH Kumar KS Suvardhan K Kiran K Rekha D Krishnaiah L Janardhanam K Chiranjeevi P 《Environmental monitoring and assessment》2007,128(1-3):241-249
A procedure was developed for the determination of Cd, Cu, Zn, Co, Ni, Mn, Pb and Mo in water samples by inductively coupled
plasma atomic emission spectrometry (ICP-AES) after preconcentration on a morpholine dithiocarbamate (mor-DTC) supported by
bagasse (Saccharam aphisinaram). The sorbed elements were subsequently eluted with 4,M HNO3 and the acid eluates were analysed by ICP–AES. The influence of various parameters such as pH, flow rate of sample, eluent
concentration, volume of the sample and volume of eluent were investigated to enhance the sensitivity of the present method.
A 20,mL disposable syringe served as preconcentration column. Under the optimal conditions Cd, Cu, Zn, Co, Ni, Mn, Pb and
Mo in aqueous sample was concentrated about 100-fold. The sorption recoveries of elements were higher than 99.6%. The method
is also applied for the analysis of natural and spiked water samples. 相似文献
904.
Tiku DK Kumar A Sawhney S Singh VP Kumar R 《Environmental monitoring and assessment》2007,132(1-3):453-466
India has a large number of paper manufacturing units, with mills varying in size of operations and type of product, scattered
all over the length and breadth of the country. Present study deals with the survey of four different pulp and paper mills
(Mill A, Mill B, Mill C and Mill D) in India, differing in their scale of operation as well as raw material usage. Physico-chemical
characterization of wastewaters produced by different processing units like digestor house liquors, bleaching section, paper
machine backwaters, combined inlet to the ETP and outlet to ETP, for all the four mills, was conducted. Different parameters
like pH, Color, COD, BOD, percent Na, SAR, TDS and Total hardness were analyzed and compared. Highly significant differences
were thus found between all the processing units of all four mills with p values < 0.01. This evaluation showed that though these mills have effluent treatment facilities installed in their premises,
improvements are still needed to increase their efficiencies for treating the discharged wastewaters. 相似文献
905.
Maiti SK 《Environmental monitoring and assessment》2007,125(1-3):111-122
Major environmental impacts of opencast mining are degradation of landscape and aesthetics of the area by creating huge overburden
dumps and deep voids at the mining sites. These overburden dumps are characterised by high rock fragment contents, low moisture
retention capacity, higher bulk density, low nutrients, lower pH and elevated metal concentrations. Overburden dumps are reclaimed
by tree species for stabilising as well as pollution control and overall improvement of the visual aesthetics. A field study
was carried out in the old reclaimed coal mine overburden dumps at KD Heslong project, Central Coalfields, India to study
the physico-chemical changes in the reclaimed overburden dumps and determines the magnitude of trace elements accumulation
in the planted tree species. Total, bioavailable and acid extractable trace metals concentration in minesoils of overburden
dump and topsoil in the mining areas was compared with undisturbed soil. The study showed that tree plantation improves the
moisture contents, bulk density, pH and overall nutrient contents of minesoils. The study revealed that lower pH in the minesoils
increases the bioavailabity of metals but concentration were found within toxic limits. However, ratio between total and bioavailable
metals was found lower in overburden dumps than topsoil due to low pH and lack of organic matter. Out of six tree species
studied, Bambusa shows highest accumulation of Fe and Cr. Bioaccumulation coefficient for Cr and Zn was found 74 times in Bambusa and 83 times in Dalbergia sissoo. The results of the study underscore the need for close monitoring of trace elements in reclaimed overburden dumps. Tree
species like Dalbergia sissoo, Eucalyptus, Cassia seamea, Acaccia mangium and Peltaphorum were found to be the best species for bioreclamation of overburden dumps. 相似文献
906.
There is a paradigm shift from non renewal resources to renewable resources in view of problems of disposal of plastic products
after their life cycle. This paper deals with the approach, preparation and product properties of polymer prepared by using
polysaccharide based biodegradable polymer. Basic material has been prepared by mixing LDPE, LDPE-g-mA (LDPE grafted with
(0.5%) maleic anhydride (1:1)) containing a polar group in the LDPE backbone. Prepared basic material has been compounded
in twin screw extruder with 0, 2.5, 5.0, 7.5, 10.0, 12.5 & 15% of Potato Starch. Thereafter, after conditioning blown film
samples were prepared using extrusion film blowing technique, under temperature profile ranging from 120 to 160 °C. Packaging
films have been prepared with maximum 15% potato starch contents and have been characterized by FTIR, DSC, TGA, and XRD techniques
to ascertain its impact on some structural and thermal properties like thermal stability, flexibility, crystallinity, crystal
size etc. 相似文献
907.
K. Rajeev K. Parameswaran Bijoy V. Thampi Manoj Kumar Mishra Anish Kumar M. Nair S. Meenu 《Atmospheric environment (Oxford, England : 1994)》2010,44(21-22):2597-2604
Every year, during the pre-monsoon period (March–May), a pronounced increase in aerosol optical depth (AOD) is observed over the eastern Arabian Sea, which is attributed to the transport of continental aerosols. This paper presents the altitude distribution of tropospheric aerosols, characteristics of elevated aerosol layers and aerosol radiative heating of the atmosphere during the pre-monsoon season over Trivandrum (8.5°N, 77°E), a station located at the southwest coast of Indian peninsula which is covered by the eastern Arabian Sea plume. Altitude profiles of aerosol backscatter coefficient (βa) and linear depolarization ratio (LDR) reveal two distinct aerosol layers persisting between 0–2 km and 2–4 km. The layer at 2–4 km, which contributes about 25% of the AOD during polluted conditions, contains significant amount of non-spherical aerosols. This layer is prominent only when the advection of dry airmass occurs from the northern parts of the Indian subcontinent and northern Arabian Sea. Role of long-range transport in the development of this aerosol layer is further confirmed using latitude–altitude cross-section of βa observed by CALIPSO. Aerosol content in the layer below 2 km is large when advection of air occurs from the north and east Arabian Sea and is significantly small when it occurs from the southwest Arabian Sea or Indian Ocean. During the highly polluted conditions, aerosols tend to increase the diurnal mean atmospheric radiative heating rate by ~0.8 K day?1 at 500 m and 0.3 K day?1 at 3 km, which are about 80% and 30% of the respective radiative heating in the aerosol-free atmosphere. 相似文献
908.
Sunil Kumar Sharma 《International Journal of Green Energy》2016,13(14):1490-1500
This study forecasts day-ahead wind speed at 15 minute intervals at the site of a wind turbine located in Maharashtra, India. Wind speed exhibits non-stationarity, seasonality and time-varying volatility clustering. Univariate linear and non-linear time series techniques namely MSARIMA, MSARIMA-GARCH and MSARIMA-EGARCH have been employed for forecasting wind speed using data span ranging from 3 days to 15 days. Study suggests that mean absolute percentage error (MAPE) values first decrease with the increase in data span, reaches its minima and then start increasing. All models provide superior forecasting performances with 5 days data span. It is further evident that ARIMA-GARCH model generates lowest MAPE with 5 days data span. All these models provide superior forecasts with respect to current industry practices. This study establishes that employing various linear and non-linear time series techniques for forecasting day-ahead wind speed can benefit the industry in terms of better operational management of wind turbines and better integration of wind energy into the power system, which have huge financial implications for wind power generators in India. 相似文献
909.
Avijit?DasEmail author KVSS?Krishna Rajeev?Kumar Anindya?Das Siladitya?Sengupta Joy?Gopal?Ghosh 《Environmental science and pollution research international》2016,23(22):22454-22466
Lead isotopic ratios (LIR) of eight common food items, street dust, coal, diesel, sediments, lead ore and rainwater from India have been reported for the first time in this paper. This study characterized the source and extent of lead pollution in the different foodstuff consumed in Kolkata, a major metropolis of eastern India. The atmospheric lead input to the food items, sold openly in busy roadside markets of the city, has been quantified. The mean 207/206 and 208/206 LIRs of the eight food items ranged from 0.8847 to 0.8924 and 2.145 to 2.167, respectively. Diesel had the highest mean 207/206 and 208/206 values of 0.9015 and 2.1869, respectively, apart from the lead ore. The food items had a mean lead concentration between 3.78 and 43.35 mg kg?1. The two ratio scatter plots of all the different environmental matrices were spread linearly between the uncontaminated Ichapur sediment and diesel. The 207/206 LIRs of the coal with a mean of 0.8777 did not fall in the linear trend, while the street dust and food samples overlapped strongly. The rainwater sample had a 207/206 LIR of 0.9007. Contaminated sediments in Dhapa, the repository of the city’s municipal garbage, had a mean 207/206 LIR of 0.8658. The corresponding value obtained from the sewage-fed vegetable grown there was 0.8058. The present study indicated that diesel was one of the main contributor to Pb pollution. The atmospheric lead contribution to the food items was in the range of 68.48–86.66 %. 相似文献
910.
Robert Paine Carlos Szembek David Heinold Eladio Knipping Naresh Kumar 《Journal of the Air & Waste Management Association (1995)》2014,64(12):1390-1402
Emissions of pollutants such as SO2 and NOx from external combustion sources can vary widely depending on fuel sulfur content, load, and transient conditions such as startup, shutdown, and maintenance/malfunction. While monitoring will automatically reflect variability from both emissions and meteorological influences, dispersion modeling has been typically conducted with a single constant peak emission rate. To respond to the need to account for emissions variability in addressing probabilistic 1-hr ambient air quality standards for SO2 and NO2, we have developed a statistical technique, the Emissions Variability Processor (EMVAP), which can account for emissions variability in dispersion modeling through Monte Carlo sampling from a specified frequency distribution of emission rates. Based upon initial AERMOD modeling of from 1 to 5 years of actual meteorological conditions, EMVAP is used as a postprocessor to AERMOD to simulate hundreds or even thousands of years of concentration predictions. This procedure uses emissions varied hourly with a Monte Carlo sampling process that is based upon the user-specified emissions distribution, from which a probabilistic estimate can be obtained of the controlling concentration. EMVAP can also accommodate an advanced Tier 2 NO2 modeling technique that uses a varying ambient ratio method approach to determine the fraction of total oxides of nitrogen that are in the form of nitrogen dioxide. For the case of the 1-hr National Ambient Air Quality Standards (NAAQS, established for SO2 and NO2), a “critical value” can be defined as the highest hourly emission rate that would be simulated to satisfy the standard using air dispersion models assuming constant emissions throughout the simulation. The critical value can be used as the starting point for a procedure like EMVAP that evaluates the impact of emissions variability and uses this information to determine an appropriate value to use for a longer term (e.g., 30-day) average emission rate that would still provide protection for the NAAQS under consideration. This paper reports on the design of EMVAP and its evaluation on several field databases that demonstrate that EMVAP produces a suitably modest overestimation of design concentrations. We also provide an example of an EMVAP application that involves a case in which a new emission limitation needs to be considered for a hypothetical emission unit that has infrequent higher-than-normal SO2 emissions.
ImplicationsEmissions of pollutants from combustion sources can vary widely depending on fuel sulfur content, load, and transient conditions such as startup and shutdown. While monitoring will automatically reflect this variability on measured concentrations, dispersion modeling is typically conducted with a single peak emission rate assumed to occur continuously. To realistically account for emissions variability in addressing probabilistic 1-hr ambient air quality standards for SO2 and NO2, the authors have developed a statistical technique, the Emissions Variability Processor (EMVAP), which can account for emissions variability in dispersion modeling through Monte Carlo sampling from a specified frequency distribution of emission rates. 相似文献