Air pollution modelling in Erzurum city

Various techniques have been applied to air pollution modelling. In this study, a model was developed by applying a continuity equation to the air control volume over Erzurum city centre. Model parameters were calculated by regression analysis, using SO2 and particle concentrations taken in 1989-1990 and 1990-1991 winter seasons. Multiple correlation coefficients, R2, for all analyses were of the same order of 97%. According to this model, daily polluting concentrations are not only influenced by daily meterological parameters but also by the values of previous days. The proposed model allows estimation of daily polluting concentrations by means of meteorological data.     

Biosynthesis and Characterization of Laccase Catalyzed Poly(Catechol)

Enzymatic polymerization of catechol was conducted batch-wise using laccase enzyme produced by the culture Trametes versicolor (ATCC 200801). The polymerization reaction was carried out in 1:1 (v/v) aqueous-acetone solution, buffered at pH 5.0 with sodium acetate (50 mM) in a sealed, temperature-controlled reactor at 25°C. The molecular weight of the produced polymer was determined with GPC. FT-IR, DSC, and TGA were employed to investigate the structure and thermal behavior of synthesized poly(catechol). It was found that catechol units were linked together with ether bonds and thermal stability of the catechol increased in the poly(catechol) polymeric structure effectively. The number average molecular weight of poly(catechol) was found as 813 ± 3 Da with a very narrow polydispersity value of 1.17 showing selective polymerization of catechol by the enzyme.     

Comparison of periphytic biofilm and filter-feeding bivalve metal bioaccumulation (Cd and Zn) to monitor hydrosystem restoration after industrial remediation: a year of biomonitoring

Despite a significant decrease in the metallic waste emissions from an industrial site and a remediation process initiated in 2007, the Riou-Mort watershed (southwest France) still exhibits high Cd and Zn concentrations. Metal wastes have long been proven to significantly disturb aquatic communities. In this study, bioaccumulation capacities and responses to the chemical improvement of the hydrosystem were assessed for a year along the contamination gradient through the comparison of two biological models: Corbicula fluminea and periphytic biofilms, both considered as good bioindicators. Bioaccumulation results confirmed the persistence of water contamination in Corbicula fluminea and biofilms with, respectively, maximum Cd concentrations reaching 80.6 and 861.2 μg gDW(-1), and Zn concentrations 2.0 and 21.3 mg gDW(-1). Biofilms exhibited bioaccumulation in close correlation with water contamination, while Corbicula fluminea presented Cd bioaccumulation clearly regulated by water temperature and metal concentrations, affecting the ventilatory activity, as revealed by condition indices measurements. Also, a linear regression using Cd bioaccumulation and temperature () showed that below approximately 6 °C Corbicula fluminea did not appear to accumulate metals. Bioconcentration factors (BCFs) were higher in biofilms in comparison with Corbicula fluminea and showed the great accumulation capacity of suspended particulate matter in biofilms. However, bioaccumulation capacities are known to be influenced by many factors other than metal concentrations, such as temperature, water oxygenation or plankton and nutrient concentrations. Thus, this study demonstrates the power of a combined assessment using both Corbicula fluminea and biofilms as bioindicators to give a more integrated view of water quality assessment. Finally, when comparing our results with previous studies, the start of hydrosystem restoration could be shown by decreasing bioaccumulation in organisms.     

Colloidal mobilization from soil and transport of uranium in (sub)-surface waters

An analytical methodology was developed to characterize the colloidal distribution of trace elements of interest in environmental waters sampled in a same site and enables the different colloidal distributions from waters to be compared. The purpose was to provide consistent information related to the origin and nature of colloids responsible for the transport of trace element(s). The work was motivated by the observed enhanced mobility of uranium in soil. The colloidal size continuum was investigated by a multi-technique approach involving asymmetric flow field-flow fractionation (AF4) coupled with ultraviolet spectroscopy (UV), multi angle light scattering (MALS), and atomic mass spectrometry (ICPMS). To take into consideration the size and shape variability specific to each sample, the size distributions were established from the gyration radii measured from MALS, also considering the size information from standard nanospheres fractionated by AF4. A new parameter called “shape index” was proposed. It expresses the difference in hydrodynamic behavior between analytes and spherical particles taken as reference. Under AF4 diffusion conditions, it can be considered as an evaluator of the deviation from the sphericity of the fractionated analytes. AF4-UV-MALS-ICPMS enabled the dimensional and chemical characteristics of the colloidal size continuum to be obtained. As a “proof of concept”, the developed methodology was applied at a field scale, in a reference study site. In order to have a “dynamic understanding”, the investigation was based on the joint characterization of colloids from surface waters and soil leachates from static and dynamic processes. In the water samples of the study site, the continuum of gyration radius ranged from a few nanometers up to 200 nm. Colloids containing iron, aluminum, and organic carbon were involved in the uranium transport in the soil column and surface waters. The colloidal uranium concentration in the surface water increased from the upstream location (approximately 13 ng (U) L^?1) to the downstream location (approximately 60 ng (U) L^?1).

     

Interrelationships among foreign direct investments,renewable energy,and CO2 emissions for different European country groups: a panel ARDL approach

Environmental Science and Pollution Research - This study estimated unbalanced panel data analysis to investigate the relationship among CO2 emissions, GDP, renewable and non-renewable energy...     

Determination of toxic metals in leather by wavelength dispersive X-ray fluorescence (WDXRF) and inductively coupled plasma optical emission spectrometry (ICP OES) with emphasis on chromium

The tanning industry is one of the largest environmental polluters due to high generation waste in all production processes, but the tanning is particularly worrisome due to the use of significant amounts of chromium. Cr is an element potentially toxic to both health and the environment, depending on the concentration and the oxidation state. Cr(VI) can come in contact with human skin when using leather goods, which can cause allergies and dermatitis, besides being carcinogenic. Considering that approximately 90% of the world production of leather is performed with Cr salts, the determination of this element in leather is necessary to avoid exposure to the risks that the element can provide. The main goal of this study was the development of an alternative analytical method for the determination of Cr in leathers (ovine and bovine leather tanned with Cr and vegetable tannin) using wavelength dispersive X-ray fluorescence (WDXRF) for direct solid analysis. Besides performing analysis of the chemical composition and determination of Al, As, Ba, Ca, Cd, Cr, Cu, Fe, Mg, Ni, Pb, Sb, Sr, Ti, and Zn in leather by inductively coupled plasma optical emission spectrometry (ICP OES). Principal component analysis (PCA) was also used in the evaluation of the WDXRF and ICP OES data sets. WDXRF calibration models for Cr presented satisfactory figures of merit and the analysis of the leathers revealed an alarming concentration of total Cr in the samples reaching 21,353 mg kg^?1.     

Urban development,environmental vulnerability and CRZ violations in India: impacts on fishing communities and sustainability implications in Mumbai coast

Coastal Regulations in India are traced back to the UN Conference on Human Environment, held in Stockholm in 1972. The Environment Protection Act (EPA) 1986 was enacted to implement India’s commitments as a signatory. The Coastal Regulation Zone (CRZ) Notification of 1991 was made under the provisions of the EPA in order to protect coastal environments and social and livelihood security of fishing community. This paper assesses the effects of CRZ rules and violations in the Mumbai Metropolitan Region, which has experienced tremendous growth due to the rapid industrialization and urbanization. This process has led to the destruction of mangroves and other important species of fish which play a crucial role in sustaining the coastal ecology and urban biodiversity; high population density and uneven growth have exacerbated adverse environmental and socioeconomic consequences. The Koli (fishing community) in this region faces huge problems of survival and sustenance in small-scale fishing, due to the rampant commercial fishing by big trawlers and large-scale dumping of waste materials by the industries surrounding the vicinity into the sea. In small but significant ways, the fishing communities through their traditional commons-based resource management and livelihood systems protect the coastal ecology and help the cities in reducing their carbon footprints. On the basis of primary field research in Thane–Mulund Creek Bhandup, Chimbai, and Sewri, this paper attempts to assess CRZ violations taking place on coastal areas and is causing damage to the coastal ecology. The research specifically has focused on the particular fishing-related activities and spaces—such as: jetties, parking of boats, access to sea, weaving and drying of nets, landing grounds, drying and cleaning of fish that are more affected by encroachment of seashore area and by CRZ rules violations. It evaluates the actions taken by Maharashtra Coastal Zone Management Authority and Bombay Municipal Corporation while implementing rules and making Integrated Coastal Zone Management plan for management of marine environment. It raises broader issues relating to the contradictions and complementarities involved in ICZM plans vis-a-vis management of biodiversity, within a larger context of rapid urbanization and demands for real estate growth. The paper argues that urban biodiversity management requires clear valuation of the long-term ecological and socioeconomic benefits of sustenance of coastal ecology and related livelihoods.     

Enhancing viability of biofuel-based decentralized power projects for rural electrification in India

Decentralized power generation, using locally available biofuels from non-edible oilseeds, is an option for rural electrification in many developing countries. However, due to prevailing high price of non-edible oilseeds, such as Jatropha curcas, the cost of electricity generation is very high. This paper provides detailed financial analysis of straight vegetable oil (SVO)-based decentralized power project and proposes an innovative model for enhancing their financial viability. While for implementing agency operational cost recovery is the key for viability, affordable tariff is crucial for end-users. The paper attempts to estimate minimum desired price of electricity from the stakeholders' (producer and users) perspective using data gathered from selected operational SVO-based power generation projects in India. Analysis carried out in this paper indicates that operating the decentralized power plant at higher capacity utilization factor, by introduction of productive load, and differentiated tariffs for commercial and domestic consumers may not alone be sufficient to achieve the financial viability. The paper proposes an innovative integrated model of using biogas, obtained from the by-product de-oiled cake of non-edible oilseeds, as a feedstock for power generation, instead of using the SVO in engines. This reduces the fuel cost of power generation, thereby helping to bring down the tariff within the paying capacity of rural consumers. The main produce, viz. extracted non-edible oil, which was otherwise used as fuel for generating power, can be sold in local market for earning revenue, thereby enhancing the project’s economic viability. This paper sets forth the proposed integrated model as a viable biofuel-based decentralized power project for sustainable rural development in areas with adequate availability of oilseeds.     

Nineteenth-century land-use legacies affect contemporary land abandonment in the Carpathians

Regional Environmental Change - Historical land use may shape landscapes for centuries into the future, but it remains unclear how much land-use legacies affect contemporary land use. Knowing for...     

The effects of alginate microspheres on phytoremediation and growth of Lemna minor in the presence of Cd

Today, the removal of increased amount of contaminant concentrations in nature such as metals, nanoparticles, has become an essential issue to struggle with. In this paper, both the toxic effects of non-essential Cd on Lemna minor in presence of alginate microspheres and metal removal capacity of Cd-exposed L. minor and microspheres were investigated. Three test groups were constructed: group (L) containing Lemna, group (M) containing alginate microsphere and group (L?+?M) containing alginate microsphere and Lemna. Five different levels of Cd concentrations were added into these groups. Estimation models were constructed to estimate Cd removal capacities of L. minor and microspheres, and time-concentration-dependent growth (GRC) rates of both microsphere-containing and non-containing groups were modelled by regression analysis. It was seen that microspheres alone only had no positive or negative effects on Lemna growth. It was observed that, for all test groups the time-dependent growth rate has both increase–decrease trends in general. The toxicity effect of Cd on Lemna growth was reduced by adding microspheres into medium. Furthermore, the results stated that test groups containing only microspheres (M, 0–97.56%) and consortium groups (M?+?L, 0–98.26%) were slightly more successful in Cd removal process compared to Lemna (L) groups (L, 0–97.32%).