全文获取类型
收费全文 | 802篇 |
免费 | 41篇 |
国内免费 | 308篇 |
专业分类
安全科学 | 68篇 |
废物处理 | 50篇 |
环保管理 | 41篇 |
综合类 | 507篇 |
基础理论 | 120篇 |
污染及防治 | 263篇 |
评价与监测 | 44篇 |
社会与环境 | 23篇 |
灾害及防治 | 35篇 |
出版年
2023年 | 17篇 |
2022年 | 40篇 |
2021年 | 31篇 |
2020年 | 32篇 |
2019年 | 26篇 |
2018年 | 39篇 |
2017年 | 29篇 |
2016年 | 40篇 |
2015年 | 41篇 |
2014年 | 55篇 |
2013年 | 87篇 |
2012年 | 70篇 |
2011年 | 62篇 |
2010年 | 67篇 |
2009年 | 71篇 |
2008年 | 54篇 |
2007年 | 52篇 |
2006年 | 44篇 |
2005年 | 23篇 |
2004年 | 23篇 |
2003年 | 28篇 |
2002年 | 20篇 |
2001年 | 28篇 |
2000年 | 27篇 |
1999年 | 14篇 |
1998年 | 18篇 |
1997年 | 18篇 |
1996年 | 16篇 |
1995年 | 23篇 |
1994年 | 17篇 |
1993年 | 12篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 8篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 1篇 |
1985年 | 2篇 |
1961年 | 1篇 |
排序方式: 共有1151条查询结果,搜索用时 15 毫秒
851.
Xiaofeng Liu Lin Peng Huiling Bai Ling Mu Chongfang Song 《Environmental geochemistry and health》2014,36(3):531-542
The purpose of this study was to characterize the occurrence and size distributions of ten species of polycyclic aromatic hydrocarbons (PAHs) in the ambient air of coking plants. Particulate-matter samples of four size fractions, including ≤2.1, 2.1–4.2, 4.2–10.2, and ≥10.2 μm, were collected using a Staplex234 cascade impactor during August 2009 at two coking plants in Shanxi, China. The PAHs were analyzed by a gas chromatograph equipped with a mass-selective detector. The concentrations of total particulate-matter PAHs were 1,412.7 and 2,241.1 ng/m3 for plants I and II, and the distributions showed a peak within the 0.1–2.1 μm size range for plant I and the 0.1–4.2 μm for plant II. The size distributions of individual PAHs (except fluoranthene) exhibited a considerable peak within the 0.1–2.1 μm size range in coking plant I, which can be explained by the gas–particle partition mechanism. The ambient air of the coking plant was heavily polluted by PAHs associated with fine particles (≤2.1 μm), and benzo[b]fluoranthene made the largest contribution to total PAHs. The exposure levels of coking-plant workers to PAHs associated with fine particles were higher than to PAHs associated with coarse particles. Benzo[b]fluoranthene, benzo[a]pyrene, and dibenzo[a,h]anthracene should be the primary pollutants monitored in the coking plant. This research constitutes a significant contribution to assessing the exposure risk of coking-plant workers and providing basic data for PAH standards for ambient air in coking plants. 相似文献
852.
6种苯系物对球等鞭金藻和新月菱形藻的生长抑制 总被引:1,自引:0,他引:1
海洋环境中苯系物污染主要来源于海洋溢油事故以及沿海石油化工企业的废水排放。为探究苯系物对海洋微藻的毒性作用,选择球等鞭金藻和新月菱形藻作为受试生物,分别考察了苯、甲苯、乙基苯、邻-二甲苯、间-二甲苯和对-二甲苯6种苯系物对2种海洋微藻生长的影响。结果表明,在0.25~64.0 mg·L-1暴露浓度下,6种苯系物对2种微藻生长具有显著的抑制作用,随着暴露浓度的升高,抑制作用明显增强。苯、甲苯、乙基苯、邻-二甲苯、间-二甲苯、对-二甲苯对球等鞭金藻的24 h的半数效应浓度(24 h-EC50)分别为:17.07、12.88、7.58、0.55、0.36、0.27 mg·L-1;对新月菱形藻的24 h-EC50值分别为:1.03、0.68、0.46、0.40、0.42、0.38 mg·L-1。上述研究结果为确定苯系物海洋环境质量标准、保护海洋生态环境提供了基础数据。 相似文献
853.
Yanxi CHEN Zhiguang NIU Jiaqi BAI Yufei WANG 《Frontiers of Environmental Science & Engineering》2014,8(5):767-775
The water supply network (WSN) system is a critical element of civil infrastructure systems. Its complexity of operation and high number of components mean that all parts of the system cannot be simply assessed. Earthquakes are the most serious natural hazard to a WSN, and seismic risk assessment is essential to identify its vulnerability to different stages of damage and ensure the system safety. In this paper, using a WSN located in the airport area of Tianjin in northern China as a case study, a quantitative vulnerability assessment method was used to assess the damage that the water supply pipelines would suffer in an earthquake, and the finite element software ABAQUS and fuzzy mathematic theory were adopted to construct the assessment method. ABAQUS was applied to simulate the seismic damage to pipe segments and components of the WSN. Membership functions based on fuzzy theory were established to calculate the membership of the components in the system. However, to consider the vulnerability of the whole system, fuzzy cluster analysis was used to distinguish the importance of pipe segments and components. Finally, the vulnerability was quantified by these functions. The proposed methodology aims to assess the performance of WSNs based on pipe vulnerabilities that are simulated and calculated by the model and the mathematical method based on data of damage. In this study, a whole seismic vulnerability assessment method for a WSN was built, and these analyses are expected to provide necessary information for a mitigation plan in an earthquake disaster. 相似文献
854.
For decades, the importance of highway work zone safety has increased considerably with the continual increase in the number of highway work zones present on highways for repairs and expansion. Rural work zones on two-lane highways are particularly hazardous and cause a significant safety concern due to the disruption of regular traffic flow. In this study, researchers determined motorists’ responses to warning signs in rural, two-lane highway work zones. The researchers divided vehicles into three classes (passenger car, truck, and semitrailer) and compared the mean change in speed of these classes based on three different sign setups: portable changeable message sign (PCMS) OFF, PCMS ON with the message of Slow Down, Drive Safely, and a temporary traffic sign (W20-1, “Road Work Ahead”). Field experiments were conducted on two two-lane work zones with flagger control. Statistical analyses were performed to determine whether there was a significant interaction between motorists’ responses and the sign setups. Data analysis results show that a visible PCMS, either turned on or off, was most effective in reducing truck speeds in rural, two-lane work zones. The temporary traffic sign (W20-1) was more effective in reducing the vehicle speeds of passenger car and semitrailer. Results of this research project will help traffic engineers to better design the two-lane work zone setup and take necessary safety countermeasures to prevent vehicle crashes. 相似文献
855.
856.
857.
858.
醛类化合物分子结构与对鼠急性毒性关系 总被引:1,自引:0,他引:1
通过检索美国国立职业与卫生研究所化学物质毒性效应登录 ( RTECS) 1998年版光盘系统 ,搜集了 88种醛类化合物对大鼠急性毒性口服 LD50 数据 ,并利用遗传神经网络建立了醛类化合物分子结构与对大鼠急性毒性关系的 BP神经网络模式 ,模式的交互检验相关系数达 0.83~ 0.87,具有较强的预报能力 .遗传神经网络是由遗传算法和神经网络耦合而成 ,文章详细讨论了遗传神经网络的构造以及利用遗传神经网络建立 QSAR模型的方法 . 相似文献
859.
废轮胎的热解及其产物分析 总被引:16,自引:0,他引:16
研究了废轮胎热解产生的三相 (气、液、固 )产率与裂解温度的关系 ,气相组成与温度的关系 ,以及氢氧化钠作为催化剂加入热解体系对三相产率和气体组成的影响 .实验表明 ,轮胎橡胶的热稳定性分为 :~ 200℃,200℃~300℃及300℃以上3个区域 .在200℃以上时 ,随着温度升高 ,固体产率减少 ,气体产率增加 ,液体产物的产率在 500℃左右出现一个峰值 .加入 4%NaOH作催化剂以后 ,在相同的温度下固态碳黑和液态油的产率均有所提高 ,而相应混合气的产率降低 .实验确定了所用混合胶粉主要为合成橡胶 .不同温度下热解所产生的液体产物的红外谱图及裂解色谱图表明 ,300℃时主要是助剂分解,400℃左右主要是聚异戊二烯(天然胶)开始裂解,600℃以上残留物开始裂解. 相似文献
860.
有机物对重金属在粘土中吸附行为的影响 总被引:43,自引:4,他引:39
实验选用填埋场垃圾降解过程中“产酸阶段”和“产甲烷阶段”产生的己酸和腐殖酸及重金属 Cd、Pb、Ni、Zn和 Mn为研究对象 ,研究有机物存在对粘土吸附重金属的影响 .结果表明 :粘土对纯重金属的吸附随着溶液 p H值升高而增强 ;对己酸的吸附随着溶液 p H值升高而增强 ,对腐殖酸的吸附随着溶液 p H值升高而减弱 .当溶液中己酸和重金属共存时 ,由于竞争吸附使得粘土对重金属的吸附能力普遍有较小幅度的下降 ;当溶液中存在腐殖酸和重金属共存时 ,粘土对重金属的吸附能力增强 ,主要是由于酸性条件下富里酸发生解离后与重金属络合 ,其络合物与粘土颗粒有一定的结合能力 ,增强了粘土对重金属的吸附能力 . 相似文献