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71.
Alvarenga P Palma P Gonçalves AP Baião N Fernandes RM de Varennes A Vallini G Duarte E Cunha-Queda AC 《Chemosphere》2008,72(11):1774-1781
A greenhouse pot experiment was conducted to evaluate the effect of sewage sludge (SS), of sugar beet sludge (SBS), or of a combination of both, in the remediation of a highly acidic (pH 3.6) metal-contaminated soil, affected by mining activities. The SS was applied at 100 and 200 Mg ha(-1) (dry weight basis), and the SBS at 7 Mg ha(-1). All pots were sown with Italian ryegrass (Lolium multiflorum Lam.). After 60 d of growth, shoot biomass was quantified and analysed for Cu, Pb and Zn. The pseudo-total and bioavailable contents of Cu, Pb and Zn and the enzymatic activities of beta-glucosidase, acid phosphatase, cellulase, protease and urease were determined in the soil mixtures. Two indirect acute bioassays with leachates from the soil (luminescent inhibition of Vibrio fischeri and Daphnia magna immobilization) were also used. The SS, in particular when in combination with SBS, corrected soil acidity, while increasing the total organic matter content and the cation exchange capacity. The application of SS led to a decrease in the level of effective bioavailable metals (extracted by 0.01 M CaCl(2), pH 5.7, without buffer), but caused an increase in their potential bioavailability (extracted by a solution of 0.5M NH(4)CH(3)COO, 0.5 M CH(3)COOH and 0.01 M EDTA, pH 4.7). Plant biomass increased more than 10 times in the presence of 100 Mg SS ha(-1), and more than five times with the combined use of 100 Mg SS ha(-1) and SBS, but a considerable phytotoxic effect was observed for the application rate of 200 Mg SS ha(-1). Copper, Pb and Zn concentrations in the shoots of L. multiflorum decreased significantly when using 100 Mg SS ha(-1) or SBS. The activities of beta-glucosidase, urease and protease increased with increasing SS applications rates, but cellulase had a reduced activity when using 200 Mg ha(-1)SS. Both amendments were able to suppress soil toxicity to levels that did not affect D. magna, but increased the soil leachate toxicity towards V. fischeri, especially with the application of 200 Mg SS ha(-1). This study showed that for this type of mine soils, and when using SS of similar composition, the maximum SS application rate should be 100 Mg ha(-1), and that liming the SS amended soil with SBS did not contribute to a further improvement in soil quality. 相似文献
72.
大气光化学烟雾反应机理比较(Ⅰ)O3和NOx的比较 总被引:8,自引:0,他引:8
在相同初始和排放条件下,对四种应用较广的光化学烟雾反应机理(CB4-99,RADM2,RACM,SAPRC99)进行了比较.研究发现对于O3,在低VOCs/NOx时,四种机理模拟结果相关较小,平均相对标准偏差为7%,在高VOCs/NOx时,平均相对标准偏差为26%,差距较大;对于NOx,多数情况下RACM和RADM2的模拟结果较高,CB4-99和SAPRC99的模拟值偏低,其原因主要来源于不同机理中O3的生成对NOx及VOCs的敏感性不同而造成的.在用模式模拟O3和NOx时,应特别注意机理不同而带来的模拟结果差异. 相似文献
73.
74.
基于2008—2012年污染源环境统计数据,采用Spearman秩相关系数法等分析南水北调中线陕西水源区污废水及污染物年排放总量变化趋势,借助ArcGIS空间分析功能表征水源区污染源排放的空间分布特征。结果表明:2008—2012年水源区污废水和NH_3-N年排放总量呈显著上升趋势,COD、As、Pb、Cd、Cr和Hg年排放总量呈抛物线型变化,总体上COD、Pb、Cd年排放总量增加,As、Cr和Hg年排放总量降低。水源区污废水及污染物排放量空间差异明显,污废水、COD和NH_3-N排放涉及流域所有区县,其排放量从干流到流域边缘呈现较明显的梯度变化,即位于流域中心或地级市行政中心的区县排放量明显高于位于流域边缘的区县;As、Pb、Cd、Cr和Hg排放量呈现明显的区域分布,主要分布在勉县等8个区县。 相似文献
75.
Heavy metal pollution is an increasing environmental problem in Chinese regions undergoing rapid economic and industrial development, such as the Pearl River Delta (PRD), southern China. We determined heavy metal concentrations in surface soils from the PRD. The soils were polluted with heavy metals, as defined by the Chinese soil quality standard grade II criteria. The degree of pollution decreased in the order Cd?>?Cu?>?Ni?>?Zn?>?As?>?Cr?>?Hg?>?Pb. The degree of heavy metal pollution by land use decreased in the order waste treatment plants (WP)?>?urban land (UL)?>?manufacturing industries (MI)?>?agricultural land (AL)?>?woodland (WL)?>?water sources (WS). Pollution with some of the metals, including Cd, Cu, Ni, and Zn, was attributed to the recent rapid development of the electronics and electroplating industries. Cd, Hg, and Pb (especially Cd) pose high potential ecological risks in all of the zones studied. The soils posing significantly high and high potential ecological risks from Cd covered 73.3 % of UL, 50 % of MI and WP land, and 48.5 % of AL. The potential ecological risks from heavy metals by land use decreased in the order UL?>?MI?>?AL?>?WP?>?WL?>?WS. The control of Cd, Hg, and Pb should be prioritized in the PRD, and emissions in wastewater, residue, and gas discharges from the electronics and electroplating industry should be decreased urgently. The use of chemical fertilizers and pesticides should also be decreased. 相似文献
76.
区域环境风险评估研究进展 总被引:3,自引:0,他引:3
简述了区域环境风险及区域环境风险评估的内涵,以及国内外区域环境风险评估研究发展进程及现状,指出了现阶段区域环境风险评估存在的问题,提出应重点开展区域环境风险发生机理、定量表征区域环境风险方法等研究的展望。 相似文献
77.
V. Vijayasree Hebsy Bai S. Naseema Beevi Thomas Biju Mathew Thomas George George Xavier 《Environmental monitoring and assessment》2015,187(5):299
Dissipation and decontamination of chlorantraniliprole (Coragen 18.5 SC) in brinjal and okra fruits were studied following field application at single and double doses of 30 and 60 g ai ha?1, and the residues of the insecticide was estimated using LC-MS/MS. Initial residues of chlorantraniliprole at single and double doses on the fruits of brinjal were 0.72 and 1.48 mg kg?1, while on okra fruits, the residues were 0.48 and 0.91 mg kg?1, respectively. The residues reached below detectable level of 0.01 mg kg?1 on the 10th day. Half-life of chlorantraniliprole at 30 and 60 g ai ha?1 on brinjal was 1.58 and 1.80 days with the calculated waiting period of 0.69 and 2.38 days, whereas on okra, the values were 1.60 and 1.70 and 0 and 1.20 days, respectively. The extent of removal of chlorantraniliprole using simple decontaminating techniques at 2 h and 3 days after spraying was 40.99–91.37 % and 29.85–89.12 %, respectively, from brinjal fruits and 47.78–86.10 % and 41.77–86.48 %, respectively, from okra fruits. 相似文献
78.
Spatial and seasonal distribution of nitrogen in marsh soils of a typical floodplain wetland in Northeast China 总被引:3,自引:0,他引:3
Bai J Wang Q Deng W Gao H Tao W Xiao R 《Environmental monitoring and assessment》2012,184(3):1253-1263
Horizontal and profile distributions of nitrogen in marsh soils in different seasons were studied in a typical site within
the Erbaifangzi wetland in Northeast China. Results showed that there was higher spatial heterogeneity for nitrate nitrogen
(NO3--_{3}^{-}-N) and ammonium nitrogen (NH4+_{4}^{+}–N), as well as available nitrogen (AN), in surface soils in July compared to that in September. Relative to July, the mean
nitrogen contents in surface soils were slightly higher in September; however, in November, soils contained significantly
lower NO3--_{3}^{-}-N and NH4+_{4}^{+}–N, higher AN, organic nitrogen (Org-N), and total nitrogen (TN). Except for mineral nitrogen, no significant differences
were observed between Org-N and TN contents in September and November. Nitrogen contents generally declined exponentially
with depth along soil profiles in three sampling dates (July, September, and November), except for a significant accumulation
peak of NO3--_{3}^{-}-N at the 20–30 cm depth in September. However, NH4+_{4}^{+}–N contents showed a vertical alternation of “increasing and decreasing” in both July and September, while nearly kept constant
with depth in November. The depth ranking of nitrogen showed the shallowest distribution for AN, followed by Org-N and TN,
while deeper distributions for NO3--_{3}^{-}-N and NH4+_{4}^{+}–N. TN, Org-N, and AN were significantly correlated with soil organic matter and total phosphorus. Soil pH values were significantly
correlated with TN and AN contents in surface soils. Clay contents showed significant correlations with nitrogen contents
except for NO3--_{3}^{-}-N in surface soils and NH4+_{4}^{+}–N in profile soils. However, soil moisture was not significantly correlated with nitrogen contents among all soil samples. 相似文献
79.
Kong S Lu B Ji Y Zhao X Bai Z Xu Y Liu Y Jiang H 《Journal of environmental monitoring : JEM》2012,14(3):791-803
15 road and 14 soil dust samples were collected from an oilfield city, Dongying, from 11/2009-4/2010 and analyzed by inductively coupled plasma-mass spectroscopy (ICP-MS) for V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb within PM(2.5), PM(10) and PM(100) fractions synchronously. Metal concentrations, sources and human health risk were studied. Results showed that both soil and road dust exhibited higher values for Mn and Zn and lower values for Co and Cd for the three fractions. Mass concentration ratios of PM(2.5)/PM(10) and PM(10)/PM(100) for metals in road and soil dust indicate that most of the heavy metals tend to concentrate in fine particles. Geoaccumulation index and enrichment factors analysis showed that Cu, Zn and Cd exhibited moderate or heavy contamination and significant enrichment, indicating the influence of anthropogenic sources. Vanadium, Cr, Mn and Co were mostly not enriched and were mainly influenced by crustal sources. For Ni, As and Pb, they ranged from not enriched to moderately enriched and were influenced by both crustal materials and anthropogenic sources. The conclusions were confirmed by multivariate analysis methods. Principle component analysis revealed that the major sources were vehicle emission, industrial activities, coal combustion, agricultural activities and crustal materials. The risk assessment results indicated that metal ingestion appeared to be the main exposure route followed by dermal contact. The most likely cause for cancer and other health risks are both the fine particles of soil and road dusts. 相似文献
80.
Kong S Ji Y Lu B Bai Z Chen L Han B Li Z 《Journal of environmental monitoring : JEM》2012,14(3):852-865
Mass concentrations and chemical components (18 elements, 9 ions, organic carbon [OC] and elemental carbon [EC]) in atmospheric PM(10) were measured at five sites in Fushun during heating, non-heating and sand periods in 2006-2007. PM(10) mass concentrations varied from 62.0 to 226.3 μg m(-3), with 21% of the total samples' mass concentrations exceeding the Chinese national secondary standard value of 150 μg m(-3), mainly concentrated in heating and sand periods. Crustal elements, trace elements, water-soluble ions, OC and EC represented 20-47%, 2-9%, 13-34%, 15-34% and 13-25% of the particulate matter mass concentrations, respectively. OC and crustal elements exhibited the highest mass percentages, at 27-34% and 30-47% during heating and sand period. Local agricultural residuals burning may contribute to EC and ion concentrations, as shown by ion temporal variation and OC and EC correlation analysis. Heavy metals (Cr, Ni, Zn, Cu and Mn) from coal combustion and industrial processes should be paid attention to in heating and sand periods. The anion/cation ratios exhibited their highest values for the background site with the influence of stationary sources on its upper wind direction during the sand period. Secondary organic carbon were 1.6-21.7, 1.5-23.0, 0.4-17.0, 0.2-33.0 and 0.2-21.1 μg m(-3), accounting for 20-77%, 44-88%, 4-77%, 8-69% and 4-73% of OC for the five sampling sites ZQ, DZ, XH, WH and SK, respectively. From the temporal and spatial variation analysis of major species, coal combustion, agricultural residual burning and industrial emission including dust re-suspended from raw material storage piles were important sources for atmospheric PM(10) in Fushun at heating, non-heating and sand periods, respectively. It was confirmed by principal component analysis that coal combustion, vehicle emission, industrial activities, soil dust, cement and construction dust and biomass burning were the main sources for PM(10) in this coal-based city. 相似文献