Urban wastewater treatment leads to the generation of large quantities of biosolids. Accumulation of biosolids is a problem
of environmental relevance due to the existence of heavy metals in the biosolids. Determination of total metal in biosolid
provides information relating pollution levels. Determination of their mobilization capacity and behaviour in the environment
is an important task. An experimental approach commonly used for studying the mobility, transport and bioavailability of metal
in biosolids is the use of selective sequential extraction procedure. In the present study an attempt has been made to study
the heavy metal properties in biosolid samples collected from urban wastewater treatment plants located at Mysore, Karnataka.
Few heavy metals selected for the present study are cadmium, chromium, copper, iron, nickel and zinc. The concentration of
these metals in biosolids and their partition in different fractions are studied. The speciation of metals based on the sequential
extraction scheme was carried out. The concentration of heavy metals is lower than that established by European legislation.
The residual fraction has the maximum percentage of heavy metals whereas, only a small fraction of heavy metals (Fe, Zn and
Cd) are extracted in the most soluble fractions, exchangeable and carbonate fractions. 相似文献
A major challenge in recycling of silicon powder from kerf loss slurry waste is the complete removal of metal particles. The traditional acid leaching method is costly and not green. In this paper, a novel approach to recover high-purity Si from the kerf loss slurry waste of solar grade silicon was investigated. The metal impurities were removed with superconducting high gradient magnetic separation technology. The effects of process parameters such as magnetic flux density, slurry density, and slurry flow velocity on the removal efficiency were investigated, and the parameters were optimized. In one lot of control experiments, the silicon content was increased from 90.91 to 95.83%, iron content reduced from 3.24 to 0.57%, and aluminum content from 2.44 to 1.51% under the optimum conditions of magnetic flux density of 4.0 T, slurry density of 20 g/L, and slurry flow velocity of 500 mL/min. The result indicates that the superconducting high gradient magnetic separation technology is a feasible purifying method, and the magnetic separation concentrate could be used as an intermediate product for high-purity Si powder.
A fused silica capillary reactor combined with a heating/cooling stage, a microscope and a digital camera were used to investigate phase behavior during the hydrothermal liquefaction of microalgae (Dunaliella tertiolecta) and model compounds, including soya protein and glycine, starch, glucose and xylose, stearic acid and palmitic acid. Bubbles were generated at 246°C and disappeared at 360°C upon heating when Dunaliella tertiolecta used as feedstocks. Moreover, liquid products were generated at 300°C upon heating and oily liquid products began to separate out at 250°C upon cooling. The phase behavior of soya protein was similar to that of the Dunaliella tertiolecta. Meanwhile, there only observed the bubbles generation during hydrothermal liquefaction of glycine. Heating the starch, glucose and xylose above 350°C generated black solids from carbonization. Stearic acid and palmitic acid only had the process of melting, dissolution, dispersion and precipitation. 相似文献
Western China has lagged a lot in terms of industrial structure and economic development,compared with the national average.And China announced its target of CO_2 emission reduction,i.e.by 2020,CO_2 emission per GDP will drop by40-45%compared with 2005.The target will be incorporated into China's long-term industrial planning.Against this background,this paper will make a comprehensive examination of the industrial development of Western China,aiming to discover a green and compatible way.First,we analyze the spatiotemporal evolution of regional industrial structure for the period 2000-2010.Second,we try to discover the industrial structure optimization path for Western China by employing the Vector Auto Regression model.Lastly,we try to provide some advice and suggestions for further industrial development in Western China.Our examination shows that further industrial development in Western China should pay full attention to resource conservation and recycling,and develop on a green and compatible path. 相似文献
Thermal desorption is widely used for remediation of soil contaminated with volatiles, such as solvents and distillates. In this study, a soil contaminated with semivolatile polychlorinated biphenyls (PCBs) was sampled at an interim storage point for waste PCB transformers and heated to temperatures from 300 to 600 °C in a flow of nitrogen to investigate the effect of temperature and particle size on thermal desorption. Two size fractions were tested: coarse soil of 420–841 μm and fine soil with particles <250 μm. A PCB removal efficiency of 98.0 % was attained after 1 h of thermal treatment at 600 °C. The residual amount of PCBs in this soil decreased with rising thermal treatment temperature while the amount transferred to the gas phase increased up to 550 °C; at 600 °C, destruction of PCBs became more obvious. At low temperature, the thermally treated soil still had a similar PCB homologue distribution as raw soil, indicating thermal desorption as a main mechanism in removal. Dechlorination and decomposition increasingly occurred at high temperature, since shifts in average chlorination level were observed, from 3.34 in the raw soil to 2.75 in soil treated at 600 °C. Fine soil particles showed higher removal efficiency and destruction efficiency than coarse particles, suggesting that desorption from coarse particles is influenced by mass transfer. 相似文献