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21.
Twenty-one samples were collected during the dry season (26 January–28 February 2004) at 12 sites in and around Addis Ababa, Ethiopia and analyzed for particulate matter with aerodynamic diameter <10 μm (PM10) mass and composition. Teflon-membrane filters were analyzed for PM10 mass and concentrations of 40 elements. Quartz-fiber filters were analyzed for chloride, sulfate, nitrate, and ammonium ions as well as elemental carbon (EC) and organic carbon (OC) content. Measured 24-h PM10 mass concentrations were <100 and 40 μg m−3 at urban and suburban sites, respectively. PM10 lead concentrations were <0.1 μg m−3 for all samples collected, an important finding because the government of Ethiopia had stopped the distribution of leaded gasoline a few months prior to this study. Mass concentrations reconstructed from chemical composition indicated that 34–66% of the PM10 mass was due to geologically derived material, probably owing to the widespread presence of unpaved roads and road shoulders. At urban sites, EC and OC compounds contributed between 31% and 60% of the measured PM10 while at suburban sites carbon compounds contributed between 24% and 26%. Secondary sulfate aerosols were responsible for <10% of the reconstructed mass in urban areas but as much as 15% in suburban sites, where PM10 mass concentrations were lower. Non-volatile particulate nitrate, a lower limit for atmospheric nitrate, constituted <5% and 7% of PM10 at the urban and suburban sites, respectively. At seven of the 12 sites, real-time PM10 mass, real-time carbon monoxide (CO), and instantaneous ozone (O3) concentrations were measured with portable nephelometers, electrochemical analyzers, and indicator test sticks, respectively. Both PM10 and CO concentrations exhibited daily maxima around 7:00 and secondary peaks in the late afternoon and evening, suggesting that those pollutants were emitted during periods associated with motor-vehicle traffic, food preparation, and heating of homes. The morning concentration maxima were likely accentuated by stable atmospheric conditions associated with overnight surface temperature inversions. Ozone concentrations were measured near mid-day on filter sample collection days and were in all cases <45 parts per billion.  相似文献   
22.
Sediment samples were collected from Tinishu Akaki River (TAR), Lake Awassa, and Lake Ziway, Ethiopia for determination of mercury. The air-dried samples were analyzed for mercury with a differential atomic absorption spectrometer after thermal evaporation of bound mercury converting it to its atomic form. Certified reference materials (CRMs) of sediments and soils were used to validate the method. The recovery of mercury from CRMs and sediments was in the range of 95–100%. The limit of detection for the determination of mercury was 50?ng?kg?1. The concentration of total mercury in the sediments varied from 3.9 to 110?µg?kg?1 for TAR, 14 to 67?µg?kg?1 for Lake Awassa, and 17 to 110?µg?kg?1 for Lake Ziway. It was found that the total mercury concentrations in all samples were below the United States Environmental Protection Agency guideline of 200?µg?kg?1.  相似文献   
23.
A total of thirty three water samples were collected from Tinishu Akaki River, Lake Awassa, and Lake Ziway, Ethiopia. Multi-element determination of trace elements (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Ag, Cd, Sn, Hg, and Pb) in water samples was carried out by inductively coupled plasma-mass spectrometry after acidification with 1% HNO3. The concentration (in µg?L?1) of the elements were in the range of 1.0–19, <0.42–83, 1.1–1580, <45–1760, <0.11–2.0, 0.43–13, 0.77–13, 6–300, <0.94–2.0, <0.3–1.5, <0.012–0.63, 0.13–4.8, <0.29, and 0.2–7.2 for V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Ag, Cd, Sn, Hg, and Pb, respectively. The concentrations of all the quantified elements, with the exception of Mn, were in the range of the permissible limits of the Ethiopian, European Community, and World Health Organization for both drinking water quality guidelines and irrigation water guidelines. The accuracy of the method was validated by analyzing trace elements in water standard reference material (SRM 1643e). The measured values of trace elements in the SRM agreed well with the certified values at the 95% confidence level.  相似文献   
24.
Environmental Geochemistry and Health - Khat (Catha edulis) chewing is widespread in the region of East Africa. Even low levels of organochlorine pesticides (OCPs) in khat could induce public...  相似文献   
25.
Environmental Science and Pollution Research - Developing strategies that counter the ongoing homogenization trends of home-garden agroforestry systems is required to maintain diversity and...  相似文献   
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