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1.
Watson RJ Butler EC Clementson LA Berry KM 《Journal of environmental monitoring : JEM》2005,7(1):37-42
A method using flow-injection, gas-diffusion, derivatisation and then fluorescent detection has been established for ammonium ion determination in seawater. The fluorescent derivative formed by reacting ortho-phthaldialdehyde (OPA) and sulfite with ammonia gives high sensitivity while removing potential interferences. This is required to measure the low concentrations of ammonium often seen in the open ocean. The experimental conditions (flow-rate, reagent concentrations, membrane configurations, etc.) were manipulated to improve performance. For a sample throughput of 30 samples h(-1), the limit of detection was 7 nM, the coefficient of variation was 5.7% at 800 nM, and the calibration curve was linear to at least 4 micromol L(-1). Interferences were minimised by a gaseous diffusion step. Volatile small molecular-weight amines as interferents were discriminated against by this method. They neither passed through the membrane as efficiently as ammonia, nor reacted as readily with OPA when sulfite was the reductant. Contamination by ammonia from laboratory and shipboard sources complicates application of the method to natural waters, especially measurement of low concentrations (<100 nM) in open-ocean waters. Steps to overcome contamination are described in detail. Some results are presented for ammonium determination in Southern Ocean and Huon Estuary (Tasmania) waters. 相似文献
2.
Beef cattle feedlots face serious environmental challenges associated with manure management, including greenhouse gas, odor, NH3, and dust emissions. Conditions affecting emissions are poorly characterized, but likely relate to the variability of feedlot surface moisture and manure contents, which affect microbial processes. Odor compounds, greenhouse gases, nitrogen losses, and dust potential were monitored at six moisture contents (0.11, 0.25, 0.43, 0.67, 1.00, and 1.50 g H2O g(-1) dry matter [DM]) in three artificial feedlot soil mixtures containing 50, 250, and 750 g manure kg(-1) total (manure + soil) DM over a two-week period. Moisture addition produced three microbial metabolisms: inactive, aerobic, and fermentative at low, moderate, and high moisture, respectively. Manure content acted to modulate the effect of moisture and enhanced some microbial processes. Greenhouse gas (CO2, N2O, and CH4) emissions were dynamic at moderate to high moisture. Malodorous volatile fatty acid (VFA) compounds did not accumulate in any treatments, but their persistence and volatility varied depending on pH and aerobic metabolism. Starch was the dominant substrate fueling both aerobic and fermentative metabolism. Nitrogen losses were observed in all metabolically active treatments; however, there was evidence for limited microbial nitrogen uptake. Finally, potential dust production was observed below defined moisture thresholds, which were related to manure content of the soil. Managing feedlot surface moisture within a narrow moisture range (0.2-0.4 g H2O g(-1) DM) and minimizing the accumulation of manure produced the optimum conditions that minimized the environmental impact from cattle feedlot production. 相似文献
3.
The moisture and manure contents of soils at cattle feedlot surfaces vary spatiotemporally and likely are important factors in the persistence of Escherichia coli O157 in these soils. The impacts of water content (0.11-1.50 g H2O g(-1) dry feedlot surface material [FSM]) and manure level (5, 25, and 75% dry manure in dry FSM) on E. coli O157:H7 in feedlot soils were evaluated. Generally, E. coli O157:H7 numbers either persisted or increased at all but the lowest moisture levels examined. Manure content modulated the effect of water on E. coli growth; for example, at water content of 0.43 g H2O g(-1) dry FSM and 25% manure, E. coli O157:H7 increased by 2 log10 colony forming units (CFU) g(-1) dry FSM in 3 d, while at 0.43 g H2O g(-1) dry FSM and 75% manure, populations remained stable over 14 d. Escherichia coli and coliform populations responded similarly. In a second study, the impacts of cycling moisture levels and different drying rates on naturally occurring E. coli O157 in feedlot soils were examined. Low initial levels of E. coli O157 were reduced to below enumerable levels by 21 d, but indigenous E. coli populations persisted at >2.50 log10 CFU g(-1) dry FSM up to 133 d. We conclude that E. coli O157 can persist and may even grow in feedlot soils, over a wide range of water and manure contents. Further investigations are needed to determine if these variables can be manipulated to reduce this pathogen in cattle and the feedlot environment. 相似文献
4.
Janina Seemann Cindy T. González Rodrigo Carballo-Bolaños Kathryn Berry Georg A. Heiss Ulrich Struck Reinhold R. Leinfelder 《Environmental monitoring and assessment》2014,186(3):1747-1763
Environmental and biological reef monitoring was conducted in Almirante Bay (Bahía Almirante) in Bocas del Toro, Panama, to assess impacts from anthropogenic developments. An integrated monitoring investigated how seasonal temperature stress, turbidity, eutrophication and physical impacts threatened reef health and biodiversity throughout the region. Environmental parameters such as total suspended solids [TSS], carbon isotopes (δ13C), C/N ratios, chlorophyll a, irradiance, secchi depth, size fractions of the sediments and isotope composition of dissolved inorganic carbon [DIC] of the water were measured throughout the years 2010 and 2011 and were analysed in order to identify different impact sources. Compared to data from Collin et al. (Smithsonian Contributions to the Marine Sciences 38:324–334, 2009) chlorophyll a has doubled at sites close to the city and the port Almirante (from 0.46–0.49 to 0.78–0.97 μg l?1) and suspension load increased, visible by a decrease in secchi depth values. Visibility decreased from 9-13 m down to 4 m at the bay inlet Boca del Drago, which is strongly exposed to river run off and dredging for the shipping traffic. Eutrophication and turbidity levels seemed to be the determining factor for the loss of hard coral diversity, most significant at chlorophyll a levels higher than 0.5 μg l?1 and TSS levels higher than 4.7 mg l?1. Hard coral cover within the bay has also declined, at some sites down to <10 % with extremely low diversities (7 hard coral species). The hard coral species Porites furcata dominated the reefs in highly impacted areas and showed a strong recovery after bleaching and a higher tolerance to turbidity and eutrophication compared to other hard coral species in the bay. Serious overfishing was detected in the region by a lack of adult and carnivorous fish species, such as grunts, snappers and groupers. Study sites less impacted by anthropogenic activities and/or those with local protection showed a higher hard coral cover and fish abundance; however, an overall loss of hard coral diversity was observed. 相似文献
5.
As local governments have moved toward adopting sustainability policies, there have been some cases where local Tea Parties have emerged as aggressive and strident opponents of such changes. Looking broadly at the Tea Party movement across the United States and systematically measuring its influence in urban America, we assess each Tea Party chapter’s capacity – its ability to convert resources into meaningful political advocacy. Data is derived from surveys of political elites in 50 cities as well as from determining the level of sustainability programming in each of these same cities. Evidence demonstrates that the Tea Party has not had a significant impact on city policymaking in the area of sustainability. Rather, the typical Tea Party chapter appears to be at best a modest presence in local politics. 相似文献
6.
Small-and large-scale farm operators and applicators urgently need user-friendly and cost-effective on-site methods to treat dilute-formulated herbicide-laden wastewater (i.e., rinsate). In this study, we investigated solvent-regenerable synthetic adsorbents, Ambersorb® 563 adsorbent, Ambersorb 572 adsorbent, and Ambersorb 575 adsorbent, as alternatives to activated carbon (Filtrasorb ® 400) for cleanup of water containing Dual 8E (a.i., metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide]) or Banvel 4L (a.i., dicamba [3,6-dichloro-2-methoxybenzoic acid]). Batch-type adsorption experiments were conducted to compare adsorptive capacities of the various adsorbents. Adsorption maxima, obtained from adsorption isotherms, indicated that of the Ambersorb adsorbents tested, Ambersorb 572 adsorbent generally exhibited the highest adsorptive capacities for the herbicides tested and was comparable to Filtrasorb 400. Solvent (methanol) regenerability studies demonstrated that herbicide was readily recovered from Ambersorb 572 adsorbent and Filtrasorb 400. In general, metolachlor was more readily recoverable than dicamba. In fixed-bed column studies, Ambersorb 572 adsorbent exhibited twice the adsorptive capacity of Filtrasorb 400. Fixed-bed columns were more effective in removing metolachlor from herbicide containing water regardless of the adsorbent used. Multicycling of Ambersorb 572 adsorbent resulted in 30% loss of adsorptive capacity for dicamba as Banvel 4L and no loss of adsorptive capacity for metolachlor as Dual 8E. Working capacity was reached after three adsorption-regeneration cycles. Fixed-bed columns packed with solvent-regenerable adsorbents may prove useful as part of an on-site wastewater disposal system. 相似文献
7.
8.
Berry ED Woodbury BL Nienaber JA Eigenberg RA Thurston JA Wells JE 《Journal of environmental quality》2007,36(6):1873-1882
Determining the survival of zoonotic pathogens in livestock manure and runoff is critical for understanding the environmental and public health risks associated with these wastes. The occurrence and persistence of the bacterial pathogens Escherichia coli O157:H7 and Campylobacter spp. in a passive beef cattle feedlot runoff control-vegetative treatment system were examined over a 26-mo period. Incidence of the protozoans Cryptosporidium spp. and Giardia spp. was also assessed. The control system utilizes a shallow basin to collect liquid runoff and accumulate eroded solids from the pen surfaces; when an adequate liquid volume is attained, the liquid is discharged from the basin onto a 4.5-ha vegetative treatment area (VTA) of bromegrass which is harvested as hay. Basin discharge transported E. coli O157, Campylobacter spp., and generic E. coli into the VTA soil, but without additional discharge from the basin, the pathogen prevalences decreased over time. Similarly, the VTA soil concentrations of generic E. coli initially decreased rapidly, but lower residual populations persisted. Isolation of Cryptosporidium oocysts and Giardia cysts from VTA samples was infrequent, indicating differences in sedimentation and/or transport in comparison to bacteria. Isolation of generic E. coli from freshly cut hay from VTA regions that received basin discharge (12 of 30 vs. 1 of 30 control samples) provided evidence for the risk of contamination; however, neither E. coli O157 or Campylobacter spp. were recovered from the hay following baling. This work indicates that the runoff control system is effective for reducing environmental risk by containing and removing pathogens from feedlot runoff. 相似文献
9.
Alan Randall Berry Ives Clyde Eastman 《Journal of Environmental Economics and Management》1974,1(2):132-149
An empirical case study of the benefits of abatement of aesthetic environmental damage associated with the Four Corners power plant and Navajo mine using the bidding game technique is presented. Bidding games were carefully designed to avoid the potential problems inherent in that technique. The results indicate the existence of substantial benefits from abatement of this aesthetic environmental damage. Aggregate bid curves, marginal bid curves, and estimates of the income elasticity of bid are presented. The effectiveness of the bidding game technique is discussed. 相似文献
10.
Mark J. Pettenati Margaret Berry Vandana Shashi J. Hartley Bowen Margaret Harper 《黑龙江环境通报》2001,21(6):435-440
The prenatal diagnosis of a complete trisomy of the long arm of chromosome 1 is reported. Major ultrasound findings included: nuchal thickening, bi-temporal narrowing, a single choroid plexus cyst, andmild ventriculomegaly. There was a mass in the chest and abdomen, pleural effusion, ascites and a hyperechoic bowel. Skin edema was present. The fetus died at 26 weeks' gestation. A literature review is presented of 17 de novo and two inherited cases with only trisomy 1q. Of note is the fact that 3/5 prenatally detected 1q trisomies have teratomas. A review of the literature reveals a dismal outcome fortrisomy 1q cases if the duplication involves bands 1q25→q32. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献