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211.
利用白腐真菌漆酶对活性黑KN-B和直接大红2种偶氮染料进行脱色实验。考察反应时间、加酶量、pH值、染料浓度、温度对脱色率的影响,研究了ABTS介体以及金属离子存在下的脱色效果,并分析了漆酶脱色的动力学性能以及其对偶氮染料的降解规律。结果表明,活性黑KN-B和直接大红脱色适宜条件为:反应时间为30 min,加酶量8 U/mL,pH=7,染料浓度分别为50 mg/L和80 mg/L,温度40~45℃。ABTS介体对酶促偶氮染料脱色没有明显促进作用。Fe2+对漆酶脱色有较强的抑制作用;Cu2+对漆酶催化活性黑KN-B促进作用较大,对直接大红影响较小。漆酶对2种染料的脱色反应符合米氏方程,其催化活性黑KN-B和直接大红染料的Km值分别为114.81 mg/L,317.5 mg/L,vmax值分别为6.57 mg/(L·min)和26.0 mg/(L·min)。 相似文献
212.
213.
Probability of intellectual disability is associated with soil concentrations of arsenic and lead 总被引:1,自引:0,他引:1
Background
The association between metals in water and soil and adverse child neurologic outcomes has focused on the singular effect of lead (Pb), mercury (Hg), and arsenic (As). This study describes the complex association between soil concentrations of As combined with Pb and the probability of intellectual disability (ID) in children.Methods
We used a retrospective cohort design with 3988 mother child pairs who were insured by Medicaid and lived during pregnancy and early childhood in South Carolina between 1/1/97 and 12/31/02. The children were followed until 6/1/08, using computerized service files, to identify the diagnosis of ID in medical records and verified by either school placement or disability service records. The soil was sampled using a uniform grid and analyzed for eight metals. The metal concentrations were interpolated using Bayesian Kriging to estimate concentration at individual residences.Results
The probability of ID increased for increasing concentrations of As and Pb in the soil. The Odds Ratio for ID, for one unit change in As was 1.130 (95% confidence interval 1.048-1.218) for Pb was 1.002 (95% confidence interval 1.000-1.004). We identified effect modification for the infants based on their birth weight for gestational age status and only infants who were normal size for their gestational age had increased probability of ID based on the As and Pb soil concentrations (OR for As at normal weight for gestational age = 1.151 (95% CI: 1.061-1.249) and OR for Pb at normal for gestational age = 1.002 (95% CI: 1.002-1.004)). For normal weight for gestational age children when As = 22 mg kg−1 and Pb = 200 mg kg−1 the risk for ID was 11% and when As = 22 mg kg−1and Pb = 400 mg kg−1 the probability of ID was 65%.Conclusion
The probability of ID is significantly associated with the interaction between Pb and As for normal weight for gestational age infants. 相似文献214.
The Quick Easy Cheap Effective Rugged and Safe multiresidue method (QuEChERS) has been validated for the extraction of 15 organochlorine pesticides (OCPs) in completely different matrices of traditional Chinese medicine (TCM). The method employed a rapid, simple and cost-effective procedure. The spiking levels for the recovery experiments were 0.1, 0.5 and 2.0 mg kg−1. Mean recoveries mostly ranged between 76.0% and 114.0% (96.0% on average), and relative standard deviations (RSD) were generally below 10% (4.72% on average). Based on these results, the methodology has been proven to be highly efficient and robust and thus suitable for monitoring the MRL compliance of a wide range of commodity. The contamination status of 15 OCPs on 80 different TCMs marketed in China, and a total of 400 samples were also performed using a previously validated method. 15 OCPs were benzene hexachloride (BHC, including α-BHC, β-BHC, γ-BHC, δ-BHC), hexachlorobenzene, heptachlor, heptachlor epoxide, aldrin, p, p′-DDE, p, p′-DDD, o, p′-DDT, p, p′-DDT, mirex, endrin, dieldrin. This study indicates that the proposed method is useful for analyzing OCPs in TCM. 相似文献
215.
216.
pH、盐度对微生物还原硫酸盐的影响研究 总被引:2,自引:1,他引:1
采用厌氧生物处理工艺,研究了在不同盐度下pH连续降低对硫酸盐还原和有机物去除率的影响。实验结果表明,硫酸盐还原菌有很强的适应pH变化的能力,在pH值达到4以下仍有60%的硫酸盐去除率。NaCl浓度由4g/L增加到50g/L抑制了各厌氧菌的活性,导致硫酸盐和有机物去除率的下降,但硫酸盐还原菌耐受性高于产甲烷菌等其他厌氧菌,在NaCl浓度为50g/L下,硫酸盐去除率能达到50%,而有机物去除率则低于30%。qRT—PCR表明了系统菌落中SRB随着环境的变化情况与化学指标结果相一致,该反应器体系中SRB在整个厌氧菌群落中只占了很小部分。 相似文献
217.
Guang Yang Bo Yang Chao Yuan Weiwei Geng Haizhou Li 《Journal of Polymers and the Environment》2011,19(1):146-151
The effects of manufacturing parameters on mechanical properties of medium density fibreboard (MDF) bonded with modified soy
protein-based glue were studied to find an appropriate manufacture technology. Physical properties of MDF made with different
amount of wax emulsion were measured. Results indicated that water repellent had no obvious influence on physical properties
of soy protein-based MDF boards. The fiberboards bonded with soy protein-based glue showed stronger water resistance properties
than those bonded with urea–formaldehyde (UF) resins. Furthermore, the soy protein-based MDF boards had good quality [25.2%
24 h soak thickness swell (TS), 29.9 MPa modulus of rupture (MOR), 3130 MPa modulus of elasticity (MOE)], which met requirements
of Chinese national standard. Practical processing parameters were obtained by orthogonal experiment, i.e., glue content 8.0%,
hot-press temperature 200 °C, and hot-press time 150 s. 相似文献
218.
微生物燃料电池(MFC)可在阴极实现反硝化、短程反硝化和同步硝化反硝化并产生电能,但在MFC阴极实现同步短程硝化反硝化的研究尚未见到报道。为了探讨MFC阴极同步短程硝化反硝化工艺的性能,将双室曝气阴极MFC与A/O脱氮工艺结合处理人工模拟低碳氮比废水。通过静置运行15 d使得MFC阴极室亚硝态氮得以积累,氨氧化菌得以富集。随即改为连续运行后第21天成功启动同步短程硝化反硝化MFC;阴极出水氨氮浓度为0.3 mg/L,亚硝态氮浓度为15.9 mg/L,硝态氮浓度为0.6 mg/L,亚硝化率达到95%以上,阴极电极自养反硝化去除率达到50%以上,COD去除率达到85%以上。结果表明,将MFC与同步短程硝化反硝化工艺结合,通过阴极室中氧气得电子获得高p H,可以强化同步短程硝化反硝化工艺,完成生物脱氮的同时回收电能,并具有减少外加碱度的优势。 相似文献
219.
鄱阳湖典型苔草湿地生物量季节变化及固碳功能评价 总被引:4,自引:0,他引:4
为进一步评估鄱阳湖湿地碳平衡,量化湿地固碳功能,于2009年9月~2011年5月,在鄱阳湖南矶湿地国家级自然保护区,选择以灰化苔草为建群种的洲滩湿地,采取收获法测定了灰化苔草4个生长季的地上、地下生物量及净初级生产力(NPP)。结果表明:1)苔草地上、地下生物量均具有明显的季节变化模式,变化范围分别为14608~1 77067 、1 80627~4 03256 g/m2;地下生物量与地上生物量的比例变化范围为208~1744,平均值为519。2)苔草地上地下生物量、NPP均表现为春季高于秋季。3)受洲滩淹水时间影响,苔草生物量、NPP具有显著的年际差异, 2010~2011年度苔草NPP仅相当于2009~2010年度的625%;NPP的下降地上部分较地下部分更明显。4)鄱阳湖湿地苔草固碳潜力巨大,2个年度固碳量分别为1 92383,1 23121 gC/m2 相似文献
220.