全文获取类型
收费全文 | 20898篇 |
免费 | 259篇 |
国内免费 | 189篇 |
专业分类
安全科学 | 656篇 |
废物处理 | 847篇 |
环保管理 | 3361篇 |
综合类 | 2734篇 |
基础理论 | 5490篇 |
环境理论 | 5篇 |
污染及防治 | 5797篇 |
评价与监测 | 1336篇 |
社会与环境 | 949篇 |
灾害及防治 | 171篇 |
出版年
2022年 | 147篇 |
2021年 | 179篇 |
2020年 | 123篇 |
2019年 | 178篇 |
2018年 | 309篇 |
2017年 | 291篇 |
2016年 | 474篇 |
2015年 | 396篇 |
2014年 | 567篇 |
2013年 | 1813篇 |
2012年 | 699篇 |
2011年 | 926篇 |
2010年 | 720篇 |
2009年 | 851篇 |
2008年 | 982篇 |
2007年 | 1022篇 |
2006年 | 887篇 |
2005年 | 740篇 |
2004年 | 736篇 |
2003年 | 712篇 |
2002年 | 700篇 |
2001年 | 816篇 |
2000年 | 615篇 |
1999年 | 340篇 |
1998年 | 280篇 |
1997年 | 256篇 |
1996年 | 316篇 |
1995年 | 323篇 |
1994年 | 289篇 |
1993年 | 274篇 |
1992年 | 248篇 |
1991年 | 203篇 |
1990年 | 238篇 |
1989年 | 209篇 |
1988年 | 212篇 |
1987年 | 189篇 |
1986年 | 165篇 |
1985年 | 176篇 |
1984年 | 204篇 |
1983年 | 207篇 |
1982年 | 203篇 |
1981年 | 201篇 |
1980年 | 163篇 |
1979年 | 186篇 |
1978年 | 128篇 |
1977年 | 110篇 |
1976年 | 97篇 |
1975年 | 100篇 |
1973年 | 97篇 |
1972年 | 107篇 |
排序方式: 共有10000条查询结果,搜索用时 156 毫秒
871.
Pedro N. Carvalho M. Clara P. Basto C. Marisa R. Almeida Hans Brix 《Environmental science and pollution research international》2014,21(20):11729-11763
Pharmaceuticals are commonly found both in the aquatic and the agricultural environments as a consequence of the human activities and associated discharge of wastewater effluents to the environment. The utilization of treated effluent for crop irrigation, along with land application of manure and biosolids, accelerates the introduction of these compounds into arable lands and crops. Despite the low concentrations of pharmaceuticals usually found, the continuous introduction into the environment from different pathways makes them ‘pseudo-persistent’. Several reviews have been published regarding the potential impact of veterinary and human pharmaceuticals on arable land. However, plant uptake as well as phytotoxicity data are scarcely studied. Simultaneously, phytoremediation as a tool for pharmaceutical removal from soils, sediments and water is starting to be researched, with promising results. This review gives an in-depth overview of the phytotoxicity of pharmaceuticals, their uptake and their removal by plants. The aim of the current work was to map the present knowledge concerning pharmaceutical interactions with plants in terms of uptake and the use of plant-based systems for phytoremediation purposes. 相似文献
872.
873.
Masoud Fallah Shorshani Céline Bonhomme Guido Petrucci Michel André Christian Seigneur 《Environmental science and pollution research international》2014,21(8):5297-5310
Methods for simulating air pollution due to road traffic and the associated effects on stormwater runoff quality in an urban environment are examined with particular emphasis on the integration of the various simulation models into a consistent modelling chain. To that end, the models for traffic, pollutant emissions, atmospheric dispersion and deposition, and stormwater contamination are reviewed. The present study focuses on the implementation of a modelling chain for an actual urban case study, which is the contamination of water runoff by cadmium (Cd), lead (Pb), and zinc (Zn) in the Grigny urban catchment near Paris, France. First, traffic emissions are calculated with traffic inputs using the COPERT4 methodology. Next, the atmospheric dispersion of pollutants is simulated with the Polyphemus line source model and pollutant deposition fluxes in different subcatchment areas are calculated. Finally, the SWMM water quantity and quality model is used to estimate the concentrations of pollutants in stormwater runoff. The simulation results are compared to mass flow rates and concentrations of Cd, Pb and Zn measured at the catchment outlet. The contribution of local traffic to stormwater contamination is estimated to be significant for Pb and, to a lesser extent, for Zn and Cd; however, Pb is most likely overestimated due to outdated emissions factors. The results demonstrate the importance of treating distributed traffic emissions from major roadways explicitly since the impact of these sources on concentrations in the catchment outlet is underestimated when those traffic emissions are spatially averaged over the catchment area. 相似文献
874.
J. Gasperi C. Sebastian V. Ruban M. Delamain S. Percot L. Wiest C. Mirande E. Caupos D. Demare M. Diallo Kessoo Kessoo M. Saad J. J. Schwartz P. Dubois C. Fratta H. Wolff R. Moilleron G. Chebbo C. Cren M. Millet S. Barraud M. C. Gromaire 《Environmental science and pollution research international》2014,21(8):5267-5281
This study aimed at: (a) providing information on the occurrence and concentration ranges in urban stormwater for a wide array of pollutants (n?=?77); (b) assessing whether despite the differences between various catchments (land use, climatic conditions, etc.), the trends in terms of contamination level are similar; and (c) analyzing the contribution of total atmospheric fallout (TAF) with respect to sources endogenous to this contamination. The studied contaminants include conventional stormwater contaminants (polycyclic aromatic hydrocarbons (PAHs), Zn, Cu, Pb, etc.), in addition to poorly or undocumented pollutants such as nonylphenol and octylphenol ethoxylates (NPnEO and OPnEO), bisphenol A (BPA), polybrominated diphenyl ethers (PBDEs), a wide variety of pesticides, and various metals of relevance (As, Ti, Sr, V). Sampling and analysis were performed using homogeneous methods on three urban catchments with different land use patterns located in three distinct French towns. For many of these pollutants, the results do not allow highlighting a significant difference in stormwater quality at the scale of the three urban catchments considered. Significant differences were, however, observed for several metals (As, Cr, Cu, Ni, Sr and Zn), PAHs, and PBDEs, though this assessment would need to be confirmed by further experiments. The pollutant distributions between dissolved and particulate phases were found to be similar across the three experimental sites, thus suggesting no site dependence. Lastly, the contributions of TAF to stormwater contamination for micropollutants were quite low. This finding held true not only for PAHs, as previously demonstrated in the literature, but also for a broader range of molecules such as BPA, NPnEO, OPnEO, and PBDEs, whose high local production is correlated with the leaching of urban surfaces, buildings, and vehicles. 相似文献
875.
D. Medas P. Lattanzi F. Podda C. Meneghini A. Trapananti A. Sprocati M. A. Casu E. Musu G. De Giudici 《Environmental science and pollution research international》2014,21(11):6775-6782
An amorphous Zn biomineralization (“white mud”), occurring at Naracauli stream, Sardinia, in association with cyanobacteria Leptolyngbya frigida and diatoms, was investigated by electron microscopy and X-ray absorption spectroscopy. Preliminary diffraction analysis shows that the precipitate sampled on Naracauli stream bed is mainly amorphous, with some peaks ascribable to quartz and phyllosilicates, plus few minor unattributed peaks. Scanning electron microscopy analysis shows that the white mud, precipitated in association with a seasonal biofilm, is made of sheaths rich in Zn, Si, and O, plus filaments likely made of organic matter. Transmission electron microscopy analysis shows that the sheaths are made of smaller units having a size in the range between 100 and 200 nm. X-ray absorption near-edge structure and extended X-ray absorption fine structure data collected at the Zn K-edge indicate that the biomineral has a local structure similar to hemimorphite, a zinc sorosilicate. The differences of this biomineral with respect to the hydrozincite biomineralization documented about 3 km upstream in the same Naracauli stream may be related to either variations in the physicochemical parameters and/or different metabolic behavior of the involved biota. 相似文献
876.
Zukhra C. Kadirova Mirabbos Hojamberdiev Ken-ichi Katsumata Toshihiro Isobe Nobuhiro Matsushita Akira Nakajima Kiyoshi Okada 《Environmental science and pollution research international》2014,21(6):4309-4319
TiO2-supported activated carbon felts (TiO2–ACFTs) were prepared by dip coating of felts composed of activated carbon fibers (ACFs) with either polyester fibers (PS-A20) and/or a polyethylene pulp (PE-W15) in a TiO2 aqueous suspension followed by calcination at 250 °C for 1 h. The as-prepared TiO2–ACFTs with 29–35 wt.% TiO2 were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and N2 adsorption. The TiO2–ACFT(PS-A20) samples with 0 and 29 wt.% TiO2 were microporous with specific surface areas (S BET) of 996 and 738 m2/g, respectively, whereas the TiO2–ACFT(PE-W15) samples with 0 and 35 wt.% TiO2 were mesoporous with S BET of 826 and 586 m2/g, respectively. Adsorption and photocatalytic activity of the as-prepared samples were evaluated by measuring adsorption in the dark and photodegradation of gaseous acetaldehyde (AcH) and methylene blue (MB) in aqueous solution under UV light. The TiO2 loading caused a considerable decrease in the S BET and MB adsorption capacity along with an increase in MB photodegradation and AcH mineralization. Lemna minor was chosen as a representative aquatic plant for ecotoxicity tests measuring detoxification of water obtained from the MB photodegradation reaction with the TiO2–ACFT samples under UV light. 相似文献
877.
William C. Porter M. Aslam K. Khalil Christopher L. Butenhoff Mansour Almazroui Abdulrahman K. Al-Khalaf Mohammed Saleh Al-Sahafi 《Journal of the Air & Waste Management Association (1995)》2014,64(7):817-826
Air pollution has been an increasing concern within the Kingdom of Saudi Arabia and other Middle Eastern countries. In this work the authors present an analysis of daily ozone (O3), nitrogen oxide (NOx), and particulate matter (<10 μm aerodynamic diameter; PM10) concentrations for two years (2010 and 2011) at sites in and around the coastal city of Jeddah, as well as a remote background site for comparison. Monthly and weekly variations, along with their implications and consequences, were also examined. O3 within Jeddah was remarkably low, and exhibited the so-called weekend effect—elevated O3 levels on the weekends, despite reduced emissions of O3 precursors on those days. Weekend O3 increases averaged between 12% and 14% in the city, suggesting that NOx/volatile organic compound (VOC) ratios within cities such as Jeddah may be exceptionally high. Sites upwind or far removed from Jeddah did not display this weekend effect. Based on these results, emission control strategies in and around Jeddah must carefully address NOx/VOC ratios so as to reduce O3 at downwind locations without increasing it within urban locations themselves. PM10 concentrations within Jeddah were elevated compared with North American cites of similar climatology, though comparable to other large cities within the Middle East.
Implications:Daily concentrations of O3, PM10, and NOx in and around the city of Jeddah, Saudi Arabia, are analyzed and compared with those of other reference cities. Extremely low O3 levels, along with a significant urban weekend effect (higher weekend O3, despite reduced NOx concentrations), is apparent, along with high levels of PM10 within the city. Urban O3 in Jeddah was found to be lower than that of other comparable cities, but the strong weekend effect suggests that care must be taken to reduce downwind O3 levels without increasing them within the city itself. Further research into the emissions and chemistry contributing to the reduced O3 levels within the city is warranted. 相似文献
878.
Cristina Barazzetti Barbieri Jorge Eduardo Souza Sarkis Luiz Antonio Martinelli Isabella C. A. C. Bordon Horst Mitteregger Jr. Marcos Antônio Hortellani 《Environmental Forensics》2014,15(2):134-146
A forensic approach was used to evaluate sediments from Portão Stream, including analysis of metals, carbon (C) and nitrogen (N) stable isotopes, and C:N ratios. Samples collected at various points located along the stream were tested in order to investigate a possible illegal leachate input. The studied stream is heavily impacted by sewage and industrial discharges from two cities along its course. Among the metals analyzed, chromium (Cr) was noticeably the main pollutant, showing the highest levels, above regulatory limits, downstream from some potential sources of effluents enriched with this metal. Isotope analyses revealed a general trend of depletion in the heavier isotope along the stream for C and N. The exception was one point near a hazardous waste landfill, where relatively more enriched δ13C and δ15N values were found. The isotope and metal analysis results indicated that this site was affected by a particular source, demonstrating the combination of these parameters could be used for the discrimination of sources in a heavily polluted stream. Nevertheless, further investigations are necessary to provide a comprehensive evaluation of the biogeochemical processes involved in the incorporation of leachate in sediments to use this analysis as evidence for the illegal leachate discharge. 相似文献
879.
Amvrossios C. Bagtzoglou Eric D. Kenney April Hiscox David R. Miller 《Environmental Forensics》2014,15(2):147-158
This work applies optimization and an Eulerian inversion approach presented by Bagtzoglou and Baun in 2005 in order to reconstruct contaminant plume time histories and to identify the likely source of atmospheric contamination using data from a real test site for the first time. Present-day distribution of an atmospheric contaminant plume as well as data points reflecting the plume history allow the reconstruction and provide the plume velocity, distribution, and probable source. The method was tested to a hypothetical case and with data from the Forest Atmosphere Transfer and Storage (FACTS) experiment in the Duke experimental forest site. In the scenarios presented herein, as well as in numerous cases tested for verification purposes, the model conserved mass, successfully located the peak of the plume, and managed to capture the motion of the plume well but underestimated the contaminant peak. 相似文献
880.
C. Hort V. Platel S. Sochard A.T. Luengas Munoz M. Ondarts A. Reguer 《Journal of the Air & Waste Management Association (1995)》2014,64(12):1403-1409
Bioprocesses, such as biofiltration, are commonly used to treat industrial effluents containing volatile organic compounds (VOCs) at low concentrations. Nevertheless, the use of biofiltration for indoor air pollution (IAP) treatment requires adjustments depending on specific indoor environments. Therefore, this study focuses on the convenience of a hybrid biological process for IAP treatment. A biofiltration reactor using a green waste compost was combined with an adsorption column filled with activated carbon (AC). This system treated a toluene-micropolluted effluent (concentration between 17 and 52 µg/m3), exhibiting concentration peaks close to 733 µg/m3 for a few hours per day. High removal efficiency was obtained despite changes in toluene inlet load (from 4.2 × 10?3 to 0.20 g/m3/hr), which proves the hybrid system’s effectiveness. In fact, during unexpected concentration changes, the efficiency of the biofilter is greatly decreased, but the adsorption column maintains the high efficiency of the entire process (removal efficiency [RE] close to 100%). Moreover, the adsorption column after biofiltration is able to deal with the problem of the emission of particles and/or microorganisms from the biofilter.
ImplicationsIndoor air pollution is nowadays recognized as a major environmental and health issue. This original study investigates the performance of a hybrid biological process combining a biofilter and an adsorption column for removal of indoor VOCs, specifically toluene. 相似文献