Building Greater Transparency in Supply Chains to Advance Sustainability

As company supply chains grow larger, more dispersed, and more complex, companies and their stakeholders are increasingly interested in knowing more about these supply chains and requesting greater transparency regarding them. This article examines several aspects that can assist companies in building greater transparency in supply chains, including supply chain mapping, traceability, third‐party certification, and goal setting, as well as reporting on their progress toward achieving these efforts. In addition, this article provides summaries of how several companies are building greater transparency in their supply chains, efforts that also help companies better manage the environmental impacts from their supply chains.     

Accretion of Nutrients and Sediment by a Constructed Stormwater Treatment Wetland in the Lake Tahoe Basin

This unique study evaluates the cumulative 16‐year lifetime performance of a wetland retention basin designed to treat stormwater runoff. Sediment cores were extracted prior to basin excavation and restoration to evaluate accretion rates and the origin of materials, retention characteristics of fine particulate matter, and overall pollutant removal efficiency. The sediment and organic layers together accreted 3.2 cm of depth per year, and 7.0 kg/m²/yr of inorganic material. Average annual accretion rates in g/m²/yr were as follows: C, 280; N, 17.7; P, 3.74; S, 3.80; Fe, 194; Mn, 2.68; Ca, 30.8; Mg, 30.7; K, 12.2; Na, 2.54; Zn, 0.858; Cu, 0.203; and B, 0.03. The accretion of C, N, P and sediment was comparable to nonwastewater treatment wetlands, overall, and relatively efficient for stormwater treatment wetlands. Comparison of particle size distribution between sediment cores and suspended solids in stormwater runoff indicated the wetland was effective at removing fine particles, with sediment cores containing 25% clay and 56% silt. A majority of the accretion of most metals and P could be attributed to efficient trapping of allochthonous material, while over half the accretion of C and N could be attributed to accumulation of autochthonous organic matter. Stormwater treatment was shown to be effective when physical properties of a retention basin are combined with the biological processes of a wetland, although sediment accretion can be relatively rapid.     

Drought,water access,and urban agriculture: a case study from Silicon Valley

In California, the growing popularity of urban agriculture (UA) has unfolded against a backdrop of historic drought. While UA is often celebrated as an urban sustainability strategy, it must be able to persist during drought if it is to perform these functions. Using Santa Clara County – the geographic core of Silicon Valley – as a case study, we use interviews and surveys to explore the implications of drought for UA. We show how developing an understanding of water access for UA during a drought requires examining the social and institutional context of water management and use. In metropolitan California, the highly decentralised water supply system combined with the diverse institutional arrangements that support UA create an uneven landscape of water access. Consequently, the pressure to change water-consuming practices – that is, the stress that institutional drought responses place on different water users – is geographically and socially differentiated. Among UA water users, responses to drought have also varied, in part because the possibilities for change are constrained by the sociotechnical arrangements of UA sites and the different purposes of UA.     

Determination of the utility of groundwater with respect to the geochemical parameters: a case study from Tuticorin District of Tamil Nadu (India)

In modern living, rapid development has created an increase in demand for groundwater. An endeavor has been made to understand the hydrogeochemical parameters to determine the utility of groundwater. This situation is severe in coastal hard rock aquifers due to the influence of salinity ingression and other anthropogenic influence. A total of 135 groundwater samples were collected from the coastal aquifer of the Tuticorin district and analyzed for major cations and anions during premonsoon (PRM) and postmonsoon (POM). The ions analyzed were used to determine the drinking, agricultural and domestic utility of groundwater. The electrical conductivity (EC) contour shows that the groundwater quality is poor along the coast. The parameters were compared with WHO (Guidelines for drinking water quality recommendations, WHO, Geneva, 2004) standard for drinking purpose. A groundwater classification method has been developed for groundwater in the area using a dynamic water quality index (WQI). On the basis of the WQI so computed, groundwater in the area has been spatially classified into “excellent,” “good,” “poor” and “very poor” to “Unsuitable” water types variation lithologywise. Corrosivity ratio and hardness were noted to be higher and found to be unsuitable in majority of the regions for domestic purpose. Higher fluoride concentration was noted in the central part of the study area represented by complex geology comprising of the hornblende biotite gneiss and charnockite. Sodium percentage (Na%), sodium absorption ratio, residual sodium carbonate, Wilcox (Classification and use of irrigation waters, US Department of Agriculture, Washington, 1955), permeability index, residual sodium bicarbonate, magnesium hazard, Kelly’s ratio and potential salinity also indicate that most of the groundwater samples are not suitable for irrigation purposes.     

Rapid Cleanup of Chlorinated Solvent Source Zones: Synergies Between Chemical and Biological Degradation

A chlorinated volatile organic compound (cVOC) source area approximately 25 by 100 ft in a heavily industrialized urban area was characterized with groundwater tetrachloroethene (PCE) concentrations up to 9,180 μg/L. This is approximately 6 percent of PCE's aqueous solubility, indicative of the presence of residual dense, nonaqueous phase liquid. The resulting dissolved‐phase plume migrated off‐site. Biotic and abiotic dechlorination using a combination of a food‐grade organic carbon‐based electron donor and zero‐valent iron suspended in a food‐grade emulsifying agent reduced the source area PCE concentrations by 98 percent within 27 weeks, with minimal downgradient migration of daughter products dichloroethene and vinyl chloride. Combining biological dechlorination with iron‐based chemical dechlorination is synergistic, enhancing treatment aggressiveness, balancing pH, and optimizing degradation of both DNAPL and dissolved‐phase cVOCs. © 2013 Wiley Periodicals, Inc.     

Effect of Fiber Surface Treatments on Thermo-Mechanical Behavior of Poly(Lactic Acid)/Phormium Tenax Composites

In the present study, Phormium Tenax fiber reinforced PLA composites were processed by injection molding and twin screw compounding with a fiber content ranging from 10 to 30 wt%. Three surface treatment methods have been used to improve the Phormium Tenax fiber-matrix interfacial bonding that are as follows: (1) aqueous alkaline solution, (2) silane coupling agent, and (3) a combination of alkaline and silane treatment. The mechanical, thermal and morphological properties of the resulting composites were investigated. The results have shown that the moduli of surface treated fiber reinforced composites are lower than the ones obtained for untreated composites (as a consequence of the decrease in fiber modulus caused by the chemical treatments) and no significant increase in strength was observed for any of the composites compared to neat PLA. SEM micrographs of composite fractured surfaces confirmed an improvement in the interfacial strength, which was insufficient nonetheless to significantly enhance the mechanical behavior of the resulting composites. Results from thermogravimetric analysis and differential scanning calorimetry suggest that surface treatment of Phormium affects the ability of PLA to cold crystallize, and the thermal stability of the composites at the different fiber contents was reduced with introduction of alkali and silane treated Phormium fibers.     

Source apportion of atmospheric particulate matter: a joint Eulerian/Lagrangian approach

PM_2.5 samples were collected during an annual monitoring campaign (January 2012–January 2013) in the urban area of Naples, one of the major cities in Southern Italy. Samples were collected by means of a standard gravimetric sampler (Tecora Echo model) and characterized from a chemical point of view by ion chromatography. As a result, 143 samples together with their ionic composition have been collected. We extend traditional source apportionment techniques, usually based on multivariate factor analysis, interpreting the chemical analysis results within a Lagrangian framework. The Hybrid Single-Particle Lagrangian Integrated Trajectory Model (HYSPLIT) model was used, providing linkages to the source regions in the upwind areas. Results were analyzed in order to quantify the relative weight of different source types/areas. Model results suggested that PM concentrations are strongly affected not only by local emissions but also by transboundary emissions, especially from the Eastern and Northern European countries and African Saharan dust episodes.     

Toward a robust analytical method for separating trace levels of nano-materials in natural waters: cloud point extraction of nano-copper(II) oxide

Cloud point extraction (CPE) factors, namely Triton X-114 (TX-114) concentration, pH, ionic strength, incubation time, and temperature, were optimized for the separation of nano-sized copper(II) oxide (nCuO) in aqueous matrices. The kinetics of phase transfer was studied using UV–visible spectroscopy. From the highest separation rate, the most favorable conditions were observed with 0.2 %?w/v of TX-114, pH?=?9.0, ionic strength of 10 mM NaCl, and incubation at 40 °C for 60 min, yielding an extraction efficiency of 89.2?±?3.9 % and a preconcentration factor of 86. The aggregate size distribution confirmed the formation of very large nCuO–micelle assemblies (11.9 μm) under these conditions. The surface charge of nCuO was also diminished effectively. An extraction efficiency of 91 % was achieved with a mixture of TX-100 and TX-114 containing 30 wt.% of TX-100. Natural organic and particulate matters, represented by humic acid (30 mg/L) and micron-sized silica particles (50 mg/L), respectively, did not significantly reduce the CPE efficiency (<10 %). The recovery of copper(II) ions (20 mg/L) in the presence of humic acid was low (3–10 %). The spiked natural water samples were analyzed either directly or after CPE by inductively coupled plasma mass spectrometry following acid digestion/microwave irradiation. The results indicated the influence of matrix effects and their reduction by CPE. A delay between spiking nCuO and CPE may also influence the recovery of nCuO due to aggregation and dissolution. A detection limit of 0.04 μg Cu/L was achieved for nCuO.     

A review of plant–pharmaceutical interactions: from uptake and effects in crop plants to phytoremediation in constructed wetlands

Pharmaceuticals are commonly found both in the aquatic and the agricultural environments as a consequence of the human activities and associated discharge of wastewater effluents to the environment. The utilization of treated effluent for crop irrigation, along with land application of manure and biosolids, accelerates the introduction of these compounds into arable lands and crops. Despite the low concentrations of pharmaceuticals usually found, the continuous introduction into the environment from different pathways makes them ‘pseudo-persistent’. Several reviews have been published regarding the potential impact of veterinary and human pharmaceuticals on arable land. However, plant uptake as well as phytotoxicity data are scarcely studied. Simultaneously, phytoremediation as a tool for pharmaceutical removal from soils, sediments and water is starting to be researched, with promising results. This review gives an in-depth overview of the phytotoxicity of pharmaceuticals, their uptake and their removal by plants. The aim of the current work was to map the present knowledge concerning pharmaceutical interactions with plants in terms of uptake and the use of plant-based systems for phytoremediation purposes.