东营市海岸带区域综合承载力评估

随着人类对海岸带开发强度的不断提高,海岸带资源、环境问题日益突出,海岸带可持续发展成为人类共识,海岸带区域综合承载力研究作为该区域可持续发展的基础性研究,可以为海岸带区域合理开发与管理提供重要理论支撑。本文选取东营市海岸带为研究区域,以海岸带湿地遥感解译数据、浅海水质监测数据及社会经济统计数据为数据源,运用状态空间法计算了研究区2010—2014年海岸带区域的综合承载力;对东营市与潍坊市、滨州市的海岸带区域综合承载力进行了比较分析;预测了2016—2020年东营市海岸带区域综合承载力;依据研究结果探讨了海岸带可持续利用的未来途径。结果表明:在过去的2010—2014年和预测的2016—2020年东营市海岸带区域综合承载力均处于超载状态,但总趋势是向好的;同时,2010—2014年东营市海岸带在吸引外资、港口发展、海岸带生态系统服务价值、浅海海域水环境方面具有明显优势,但社会公共服务投入不平衡、不稳定。与2016—2020年东营市海岸带区域综合承载力预测结果相比较而言,2011年东营市海岸带区域综合承载力超载最明显,与该年环境压力大和社会投入不足有关。2014年东营市各县区海岸带区域综合承载力均处于超载状态,广饶县超载最明显;同时各县区自然、社会、经济发展水平差异较大,市辖区社会经济指标优于各县区。东营市海岸带区域综合承载力相比潍坊市、滨州市在资源、环境、生态方面具有明显优势,但在社会支撑方面投入不足,因此可以通过保持资源、生态优势,弥补社会投入不足等措施提高东营市海岸带可持续利用水平。     

铁矿石烧结烟气脱硫灰处理含铬废水

在分析铁矿石烧结烟气脱硫灰成分的基础上,利用脱硫灰中的亚硫酸盐还原废水中的Cr(Ⅵ),再加碱中和,通过沉淀去除铬。在初始废水pH 1.0、脱硫灰加入量0.06 g/mg(以Cr(Ⅵ)计)、振荡转速160 r/min、振荡时间25 min、中和pH 7.5的最佳工艺条件下处理模拟含铬废水,Cr(Ⅵ)质量浓度由10.00 mg/L降至0.18 mg/L,去除率达98.2%。最佳工艺条件下处理3种实际含铬废水,处理后出水的Cr(Ⅵ)和总铬的质量浓度及pH均满足GB 8978—1996《污水综合排放标准》。实现了对脱硫灰的综合利用、化害为利和以废治废的目标。     

生物炭对小麦种子萌发与幼苗生长的植物毒理效应

为明确生物炭对植物的毒性效应,以石英砂+生物炭水浸提液培养方法研究不同剂量生物炭对小麦种子萌发与幼苗生长的影响。结果表明:在不同剂量(0.0、10.0、20.0、40.0、80.0、160.0 g·kg~(-1))生物炭水浸提液处理下,虽然小麦发芽率较对照组无显著性变化(P0.05),但根、芽生长表现出低剂量促进高剂量抑制,且在160.0 g·kg~(-1)时抑制率最大,分别为18.11%和22.22%。在幼苗的生长期(11 d),高剂量生物炭对幼苗根生长的抑制作用增强,160.0 g·kg~(-1)处理下抑制率显著增加至55.59%(P0.05)。此外,当生物炭剂量较低时,小麦幼苗根、叶中超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)活力增加;随生物炭剂量的增加,3种抗氧化酶活力降低,丙二醛(MDA)含量升高,幼苗生长出现生理损伤,表现出明显植物毒性效应。     

环境雌激素生物效应的作用机制研究进展

环境雌激素(environmental estrogens,EEs)种类繁多,来源多样且分布广泛,大量工业添加剂、食品添加剂和农药类物质已被证实具有雌激素活性。EEs对人体生殖、神经、免疫等系统的生物毒性已经引起了公众的普遍关注。近年来的研究表明,EEs不仅结合雌激素核受体(nuclear estrogen receptor,n ER),还可以活化雌激素膜受体(membrane estrogen receptor,m ER),干扰正常的雌激素信号通路。本文总结了EEs通过n ER、m ER介导的多种雌激素基因组和非基因组信号途径及其产生的生物学效应,综述了在其毒理学作用机理基础上发展的环境样品的雌激素活性评估和EEs混合物的联合作用研究,以期为该类污染物的筛查、风险评估和进一步的机制研究提供参考。     

Enantioselective apoptosis and oxidative damage induced by individual isomers of profenofos in primary hippocampal neurons

The purpose of this study was to investigate the apoptosis-related cytotoxic effects and molecular mechanisms of individual isomers of profenofos (PFF) on primary hippocampal neurons at 1.0 to 20 mg L^?1. The cell viability and lactate dehydrogenase (LDH) efflux indicated that (?)­PFF exposure was associated with more toxic effects than (+)­PFF above the concentration of 5 mg L^?1 (P < 0.5). Flow cytometric results showed that the percentages of apoptotic cells incubated with 20 mg L^?1 (?)­PFF, (+)­PFF and rac-PFF for 24 h reached 23.4%, 9.2% and 14.2% (P < 0.01), respectively. Hippocampal neurons incubated with (?)­PFF, (+)­PFF and rac-PFF exhibited a dose-dependent accumulation of intracellular reactive oxygen species (ROS) and malondialdehyde (MDA) and a dose-dependent inhibition of superoxide dismutase (SOD), catalase (CAT) and glutathione peroxidase (GPx) activity, implying that the defense system of the tests induces oxidative damage. A statistically significant difference was observed between the two enantiomers at 5 mg L^?1 and above. Moreover, the results showed that (?)­PFF exposure caused a significant loss in mitochondrial transmembrane potential (MMP), an upregulation of Ca²⁺ and Bax protein expression, a downregulation of Bcl-2 protein expression, and the activation of caspase-3 and caspase-9 in a dose-dependent manner; (+)­PFF and rac-PFF exhibited these effects to a lesser degree. All results suggest that PFF induced apoptosis in rat hippocampal neurons via the mitochondria-mediated pathway, and oxidative stress is one of the factors of PFF-induced apoptosis. In addition, (?)­PFF appears to play an important role in oxidative stress and apoptosis, indicating that enantioselectivity should be considered when assessing ecotoxicological effects and health risks of chiral pesticides.     

Isolation and identification of 3-bromocarbazole-degrading bacteria

In this study, a bacterial strain, CH-1, capable of degrading 3-bromocarbazole (3-BCZ) was isolated from a polluted soil. Based on its physio-biochemical characteristics and 16S rRNA genes, strain CH-1 was identified as a Stenotrophomonas sp. Strain CH-1 was able to degrade 70% of 50 mg/L 3-BCZ within 8 d at pH 7.0 and 30°C in mineral salt medium (MSM). During the process, the main intermediate metabolite was identified as (2E, 4Z)-6-(2-amino-5-bromophenyl)-2-hydroxy-6-oxhexa-2, 4-dienoic by gas (2E, 4Z)-6-(2-amino-5-bromophenyl)-2-hydroxy-6-oxhexa-2,4-dienoic via gas chromatograph-mass spectrometry (GC-MS) analysis. The metabolite disappeared after 14 d, suggesting that the metabolite can also be degraded by strain CH-1. 3-BCZ is a new persistent organic pollutant. This is the first report of the biodegradation of 3-BCZ. The results indicated that strain CH-1 may be a promising bacterial candidate for the bioremediation of environments polluted with polyhalogenated carbazoles (PHCs).     

近45 a来我国农业气象灾害变化特征及其对粮食产量的影响

利用农业部种植业管理司发布的数据,针对近45 a(1970~2014年)来我国农业气象灾害变化特征及其对粮食产量影响的问题,采用数理统计和偏相关分析方法进行了研究。结果表明:黑龙江、山东和河南是受灾和成灾面积最大的省份;山西和内蒙古是受灾率和成灾率最高的两个省份;旱灾是我国主要的气象灾害,洪涝灾害波动明显,沿海地区台风灾害持续上升;东北地区旱灾比重增加,低温灾害有所减轻;华东地区洪涝、低温和台风灾害比重增加;华北地区低温和风雹呈现上升趋势;华南地区台风灾害增长显著;西北地区风雹和低温增加;西南地区旱灾和洪涝走势相反;中南地区旱灾减轻,洪涝加重;气象灾害直接影响到粮食总产量,干旱和洪涝灾害影响尤为明显;气象灾害与粮食产量的关系呈现出先上升后下降趋势。     

The cause and influence of self-cementing properties of fine recycled concrete aggregates on the properties of unbound sub-base

The use of coarse recycled concrete aggregates (CRCA) in conjunction with fine recycled concrete aggregates (FRCA) as sub-base materials has been widely studied. Although research results indicate that it is feasible to employ both CRCA and FRCA as granular sub-base, the influence of the unhydrated cement in the adhered mortar of the RCA on the properties of the sub-base materials has not been thoroughly studied. Generally, it is known that the strength of the sub-base materials prepared with RCA increases over time. However, this mechanism, known as the self-cementing properties, is not well understood and is believed to be governed by the properties of the fine portion of the RCA (<5mm). This paper presents an investigation on the cause of the self-cementing properties by measuring X-ray diffraction patterns, pH values, compressive strength and permeability of various size fractions of the FRCA obtained from a commercially operated construction and demolition waste recycling plant. Their influence on the overall sub-base materials was determined. The results indicate that the size fractions of <0.15 and 0.3-0.6mm (active fractions) were most likely to be the principal cause of the self-cementing properties of the FRCA. However, the effects on the properties of the overall RCA sub-base materials were minimal if the total quantity of the active fractions was limited to a threshold by weight of the total fine aggregate.     

区域能源效率测算及影响分析——基于三阶段DEA方法

文章运用三阶段DEA方法,测算了2010～2017年间全国30个省、市能源效率,并将剔除环境要素和随机扰动影响的效率值与传统DEA分析结果进行比较.结果显示,剔除环境要素和随机扰动之前,我国绝大多数省规模效率高于纯技术效率,导致规模效率被高估,存在投入不足的情况;通过三阶段DEA结果,中国地区间规模报酬都处于递增趋势,...     

垃圾焚烧烟气高温净化反应产物的收尘技术

利用石灰作吸收剂在较高温度段净化垃圾焚烧烟气中所含的酸性气体,并及时进行收尘有利于焚烧炉的安全、经济运行。本实验在实验室规模的旋风分离器实验台上,对中、高温烟气工况下石灰净化HCl气体后的反应产物的分离效率以及反应产物的粒径变化规律进行了研究。试验结果表明:高温下石灰颗粒尤其是反应后的产物存在着团聚现象,并且产物团聚现象随烟气温度升高而加剧,进而显著地影响了分离效率,使450～760℃范围内的分离效率提高到94%以上。