Removing perfluorooctane sulfonate and perfluorooctanoic acid from solid matrices, paper, fabrics, and sand by mineral acid suppression and supercritical carbon dioxide extraction

The removal of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) from solid matrices has received considerable attention because of the environmental persistence, bioaccumulation, and potential toxicity of these compounds. This study presents a simple method using concentrated HNO₃ as a suppression agent, and methanol-modified supercritical carbon dioxide (Sc-CO₂) extraction for removing PFOS and PFOA from solid matrices. The optimal conditions were 16 M HNO₃ and 20% (v/v) methanol containing Sc-CO₂, under a pressure of 20.3 MPa and a temperature of 50 °C. Extraction time was set at 70 min (40 min for static and 30 min for dynamic extraction). PFOA and PFOS were identified and quantitated by liquid chromatography/mass spectrometry. The extraction efficiencies (with double extractions) were close to 100% for PFOA and 80% for PFOS for both paper and fabric matrices. The extraction efficiencies for sand were approximately 77% for PFOA and 59% for PFOS. The results show that this method is accurate, and effective, and that it provides a promising and convenient approach to remediate the environment of hazardous PFOA and PFOS contamination.     

Effect of metal chlorides on thermal degradation of (waste) polycarbonate

In this study, we investigated how to treat (waste) polycarbonate efficiently to reduce its degraded residue. The study was carried out in an isothermal reactor under continuous nitrogen flow at atmospheric pressure to pyrolyze polycarbonate (PC) alone and in the presence of metal chloride. Some metal chlorides were shown to be catalytic active for the degradation of PC at 400 degrees C, which increased degradation conversion from 8.5% to more than 58.3%. Among those active metal chlorides, ZnCl2 and SnCl2 can produce higher liquid product yields. Effects such as particle size of PC, temperature, the weight ratio of metal chloride/PC, and degradation time on the degradation conversion of PC without and with these two most active metal chlorides were studied. Results of the liquid product analysis by GC/MS demonstrated the product composition of PC degradation over the metal chlorides is much simpler than that of degradation alone. The main liquid product is phenol, p-isopropylphenol, diphenyl carbonate, and bisphenol A for all cases.     

Decoupling analysis of water consumption and economic development of arid and semiarid regions in Northwest China

The contradiction between China's economic development, its need for resources and the protection of the environment is ctitical. Scarce water resources have resulted in a considerable bottleneck restricting the economic development of water-deficient areas. An objective evaluation of the decoupling state of water consumption and economic development has become an important indicator of regional economic sustainable development. Based on panel data from 2000 to 2017 for six provinces in the arid and semiarid regions of Northwest China, the Logarithmic Mean Divisia Index method is employed to decompose the factors of the decoupling index and establish a decoupling relationship model between water consumption and economic development. The reasons that affect the decoupling state of water resource utilization and economic development are herein discussed, and the stability of the decoupling trend is analysed. Based on the overall regional trend, the decoupling state of the arid and semiarid regions in Northwest China improved from weak to strong, but the high decoupling stability index varied among the provinces. The intensity and structure were promotional factors for decoupling water consumption and economic development, and the contribution rate of the intensity factor was higher than that of the structure factor. Income and population were inhibiting factors for decoupling water consumption and economic development, and the contribution rate of the income factor was higher than that of the population factor. Based on these results, corresponding policy recommendations are provided.     

Distributive and procedural justice as predictors of employee outcomes in Hong Kong

This study examines the extent to which employee judgments about distributive and procedural justice predict job satisfaction, intent to stay and evaluation of supervision in Hong Kong. Distributive and procedural justice each plays a role in determining work outcomes of Hong Kong employees. However, some effects of these justice variables differ from results of previous studies in the United States (U.S.). First, in previous U.S. studies, procedural justice moderates the relationship of distributive justice with evaluation of supervision, but not with job satisfaction or intent to stay. For Hong Kong employees, procedural justice moderates the effects of distributive justice on job satisfaction and intent to stay, but not on evaluation of supervision. Second, previous U.S. studies have shown that procedural justice has a larger effect on work outcomes for women, while distributive justice has larger effects on outcomes for men. For Hong Kong employees, the effects of procedural and distributive justice are about the same for men and women. Differences in the effects of distributive and procedural justice between Hong Kong and the U.S. may reflect cultural dimensions, such as collectivism/individualism and power distance, as well as the relative availability of rewards for women in the work force. Practical implications and future research directions are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Influence of vertical greening design of building opening on indoor cooling and ventilation

This study focused on greening designs for building openings. Field experimentation was conducted and Computational Fluid Dynamics (CFD) software was used for simulation in order to analyze the influence of different greening design modes on indoor temperature. A greening design mode suitable for the opening of houses in Kaohsiung was proposed. This study took an architectural space with a pitched roof as the experimental site, where the main variable was the location of the plant facade outside the opening, and the distance between the plant and wall surface, as well as the number of plant layers, was the control variable. A plant (Rose of China) was selected for experimentation, and the indoor temperature distributions under various research module settings were discussed by numerical simulation. The conclusions are described, as follows: (1) The air temperature would be affected by the plants, and the indoor air temperature is reduced (over 0.5°C without direct sunshine in this study). (The difference between the indoor cooling effects with and without plants was 0.89~1.11°C. (2) While the cooling effect of the double-layer plant on indoor air temperature was better than a single-layer plant, the difference was limited and not proportional. (3) The plants should be located as close to the opening as possible, and be arranged partially sparse and partially dense. (4) When the outside wind speed is low, plant greening is highly recommended for cooling.     

Emergy-based fuzzy optimization approach for water reuse in an eco-industrial park

The establishment of an eco-industrial park (EIP) provides opportunity for individual plants to cooperate with each other in order to utilize resources efficiently and thus reduce waste. The goal of an EIP is to “close the loop” through recycling and reuse of material and energy streams. Studies show with current freshwater consumption trends there would be water stress aggravated by global warming in the near future. This paper presents a model to design an EIP water reuse network that considers overall system sustainability as measured with emergy, as well as cost saving desired by individual plants. Case studies from literature are then solved to illustrate the advantage of this method in decision making. The illustrative examples show how the model achieves a compromise among the potentially conflicting fuzzy goals of the various EIP stakeholders.     

Introduction to the special issue on Advances in Life-Cycle Approachesto Business and Resource Management in the Asia-Pacific Region

This special issue of the Journal of Cleaner Production was initiated as a result of the 5th and 6th meetings of the Asia Pacific Roundtable for Sustainable Consumption and Production (APRSCP), which were held in Melbourne, Australia and Hanoi, Vietnam, respectively. A need identified at those meetings was to create another means of communicating the best ideas and papers being presented, to a wider audience. The Asia Pacific region has special development needs given its rapid emergence as a global production hub, but coupled to that are also the rapid social adjustments and shifts in patterns of consumption and production which aren't positive for the environment. This special issue contains eight papers covering the implementation of cleaner production and life cycle principles at the systems and regional planning level. These articles cover urban development, corporate CP programs, supply chain management, eco-industrial networks, and industrial parks, recycling, and understanding the role of human factors in bringing about environmental change.     

Availability and immobilization of 137Cs in subtropical high mountain forest and grassland soils

To understand the behavior of (137)Cs in undisturbed soils after nuclear fallout deposition between the 1940s and 1980s, we investigated the speciation of (137)Cs in soils in forest and its adjacent grassland from a volcano and subalpine area in Taiwan. We performed sequential extraction of (137)Cs (i.e., fractions readily exchangeable, bound to microbial biomass, bound to Fe-Mn oxides, bound to organic matter, persistently bound and residual). For both the forest and grassland soils, (137)Cs was mainly present in the persistently bound (31-41%) and residual (22-62%) fractions. The proportions of (137)Cs labile fractions--bound to exchangeable sites, microbial biomass, Mn-Fe oxides, and organic matter--were lower than those of the recalcitrant fractions. The labile fractions in the forest soils were also higher than those in the grassland soils, especially in the volcanic soil. The results suggest that the labile form of (137)Cs was mostly transferred to the persistently bound and resistant fractions after long-term deposition of fallout. The readily exchangeable (137)Cs fraction was higher in soils with higher organic matter content or minor amounts of 2:1 silicate clay minerals.