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961.
采用聚合物前驱体法制备了Ti/SnO2-Sb2O3电极,再通过恒电流电沉积法制备了 Ti/SnO2-Sb2O3/PbO2和Ti/SnO2-Sb2O3/MnO2电极。采用SEM技术对3种金属氧化物电极表面的形貌进行了表征,并分别以3种电极为阳极进行了苯酚的电催化氧化实验。实验结果表明:电解时间为2.5 h时,Ti/SnO2-Sb2O3电极、Ti/SnO2-Sb2O3/PbO2电极和Ti/SnO2-Sb2O3/MnO2电极对苯酚的降解率分别为85.9%,83.2%,44.6%;苯酚在3种电极上的电催化氧化反应均遵循一级反应动力学方程;苯酚在Ti/SnO2-Sb2O3 电极和Ti/SnO2-Sb2O3/PbO2电极上的反应速率较快,并具有较高的析氧电位;Ti/SnO2-Sb2O3/PbO2电极具有更好的耐腐蚀性和更长的使用寿命。 相似文献
962.
963.
964.
Shipeng Dong Liang Mao Siqiang Luo Lei Zhou Yiping Feng Shixiang Gao 《Environmental science and pollution research international》2014,21(3):2358-2366
Concentrations of aqueous-phase nonylphenol (NP), a well-known endocrine-disrupting chemical, are shown to be reduced effectively via reaction with lignin peroxidase (LiP) or horseradish peroxidase (HRP) and hydrogen peroxide. We systematically assessed their reaction efficiencies at varying conditions, and the results have confirmed that the catalytic performance of LiP toward NP was more efficient than that of HRP under experimental conditions. Mass spectrum analysis demonstrated that polymerization through radical–radical coupling mechanism was the pathway leading to NP transformation. Our molecular modeling with the assistance of ab initio suggested the coupling of NP likely proceeded via covalent bonding between two NP radicals at their unsubstituted carbons in phenolic rings. Data from acute immobilization tests with Daphnia confirm that NP toxicity is effectively eliminated by LiP/HRP-catalyzed NP removal. The findings in this study provide useful information for understanding LiP/HRP-mediated NP reactions, and comparison of enzymatic performance can present their advantages for up-scale applications in water/wastewater treatment. 相似文献
965.
微波再生载苯酚活性炭过程中再生产物分析 总被引:1,自引:0,他引:1
研究了载氮气和无载气2种条件下,微波再生载苯酚活性炭过程中再生产物的成分和苯酚随再生过程的去向分布。结果表明,无载气时,微波功率越高,再生反应器内温度越高,吸附质的高温裂解反应越彻底,再生产物以挥发性气体为主,有机质种类很少;而当微波功率较低或载氮气再生时,反应器内温度相对较低,苯酚难以被彻底分解,再生产物中含多种复杂的链状或环状有机物。此外,载氮气时,经气提、挥发而去除的苯酚量约占总吸附量的一半,再生炭上无苯酚残留,活性炭吸附性能可完全恢复乃至优化;无载气时,经挥发而去除的苯酚量只有19.9%,其余大量苯酚则在微波作用下裂解或缩合为其他物质随尾气而去除,且再生炭上仍有少量苯酚未被解吸出来。因此,前者活性炭再生的效果优于后者。 相似文献
966.
There is much discussion within the sustainable development community regarding climate stabilization and particularly, finding
environmentally equitable ways to address emission reductions. Knowing the current level of emission is only one variable
in this complex picture. While the rate of emissions is clearly a problem, the overall increase in GHG concentration in the
atmosphere is ultimately the main driver of anthropogenic warming. Therefore, it is also important to understand the cumulative
emissions, those which have taken us to the current condition. This research presents a case study of six countries to compare
the emissions per capita and cumulative emissions during the past 200 years. It is known that carbon emissions are closely
related to economic activities, but here we show that some countries have reached per capita emissions plateaus at different
levels while others are still rising. Specifically, one approach toward socioeconomic development, in terms of energy–economy,
reaches a plateau at 10 Mt carbon per person, which the United Kingdom and South Korea have attained. The US occupies another
emission regime at 20 Mt carbon per person. Developing economies such as India and China are considerably below these levels,
and unless they follow other integrated economic/environmental solutions, they will continue to increase their per capita
emissions during development. 相似文献
967.
Keigo Akimoto Fuminori Sano Takashi Homma Kenichi Wada Miyuki Nagashima Junichiro Oda 《Sustainability Science》2012,7(2):157-168
This study focuses on analyses of greenhouse gas (GHG) emission reductions, from the perspective of interrelationships among
time points and countries, in order to seek effective reductions. We assessed GHG emission reduction potentials and costs
in 2020 and 2030 by country and sector, using a GHG emission reduction-assessment model of high resolution regarding region
and technology, and of high consistency with intertemporal, interregional, and intersectoral relationships. Global GHG emission
reduction potentials relative to baseline emissions in 2020 are 8.4, 14.7, and 18.9 GtCO2eq. at costs below 20, 50, and 100 $/tCO2eq., corresponding to +19, −2, and −7 %, respectively, relative to 2005. The emission reduction potential for 2030 is greater
than that for 2020, mainly because many energy supply and energy-intensive technologies have long lifetimes and more of the
current key facilities will be extant in 2020 than in 2030. The emission reduction potentials in 2030 are 12.6, 22.0, and
26.6 GtCO2eq. at costs below 20, 50, and 100 $/tCO2eq., corresponding to +19, −2, and −7 %, respectively, relative to 2005. The emission reduction potential for 2030 is greater
than that for 2020, mainly because many energy supply and energy-intensive technologies have long lifetimes and more of the
current key facilities will be extant in 2020 than in 2030. The emission reduction potentials in 2030 are 12.6, 22.0, and
26.6 GtCO2eq. at costs below 20, 50, and 100 /tCO2eq., corresponding to +33, +8, and −3 %, respectively, relative to 2005. Global emission reduction potentials at a cost below
50 $/tCO2eq. for nuclear power and carbon capture and storage are 2.3 and 2.2 GtCO2eq., respectively, relative to baseline emissions in 2030. Longer-term perspectives on GHG emission reductions toward 2030
will yield more cost-effective reduction scenarios for 2020 as well. 相似文献
968.
There are few papers in the literature focusing on the issue of the optimal depletion of exhaustible resources in the framework of variable time preference. This paper attempts to analyze the pure consumption of exhaustible resource under hyperbolic time preference, and to discuss the optimal depletion rate and the effect of the protection of the exhaustible resource under different commitment abilities. The results of model show that the case of the hyperbolic discount with the full commitment of the government is equivalent to the case of constant discount of the social planner problem. In that case, the optimal depletion rate and the initial consumption of exhaustible resource are the slowest. On the contrary, they are the highest and the myopic behaviors lead to excessive consumption of exhaustible resources inevitably without commitment. Otherwise, in the case of partial commitment, the results are between the cases of full commitment and of no commitment. Therefore, with the hyperbolic time preference, the optimal depletion rate of resource depends on the commitment ability. Higher commitment ability leads to lower effective rate of time preference, and consequently, lower depletion rate and lower initial depletion value. The improvement of commitment ability can decrease the impatience and myopia behaviors, and contribute to the protection of the exhaustible resources. 相似文献
969.
Pinus roxburghii (chir-pine) and Quercus leucothchophora (banj-oak) are dominant forests of mountainous part of the Uttarakhand Himalaya. The continued anthropogenic disturbance
is opening the canopy, forming canopy gaps and as a result forest fragments are developing. Thus, the present study aims to
analyze variations in species richness and vegetational parameters in relation to canopy gaps in forests. Total species richness
was greater in open canopied forest compared to moderate and close canopied forests. In comparison between oak and pine forest,
it was greater in oak forest while the proportion of common species was low between oak—pine forests. Mean species richness
did not significantly vary from one canopy gap to another as well as in oak and pine dominated forest. This indicated that
dominant forest types played an important role to form the community structure. The shrubs richness were greater in closed
canopy and between the forests it was greater in pine forest. Tree and shrub density was low in open canopy while herb density
was high in moderate canopy. Thus, this study indicated that the dominant canopy species play an important role in deciding
the community structures especially the distribution of under canopy species. These parameters should be considered for conservation
and maintenance of plant biodiversity of a region. 相似文献
970.