High‐Frequency Continuous Monitoring to Track Vapor Intrusion Resulting From Naturally Occurring Pressure Dynamics

Vapor intrusion characterization efforts can be challenging due to complexities associated with background indoor air constituents, preferential subsurface migration pathways, and response time and representativeness limitations associated with conventional low‐frequency monitoring methods. For sites experiencing trichloroethylene (TCE) vapor intrusion, the potential for acute risks poses additional challenges, as the need for rapid response to exposure exceedances becomes critical in order to minimize health risks and associated liabilities. Continuous monitoring platforms have been deployed to monitor indoor and subsurface concentrations of key volatile constituents, atmospheric pressure, and pressure differential conditions that can result in advective transport. These systems can be comprised of multiplexed laboratory‐grade analytical components integrated with telemetry and geographical information systems for automatically generating time‐stamped renderings of observations and time‐weighted averages through a cloud‐based data management platform. Integrated automatic alerting and responses can also be engaged within one minute of risk exceedance detection. The objectives at a site selected for testing included continuous monitoring of vapor concentrations and related surface and subsurface physical parameters to understand exposure risks over space and time and to evaluate potential mechanisms controlling risk dynamics which could then be used to design a long‐term risk reduction strategy. High‐frequency data collection, processing, and automated visualization efforts have resulted in greater understanding of natural processes such as dynamic contaminant vapor intrusion risk conditions potentially influenced by localized barometric pumping induced by temperature changes. For the selected site, temporal correlation was observed between dynamic indoor TCE vapor concentration, barometric pressure, and pressure differential. This correlation was observed with a predictable daily frequency even for very slight diurnal changes in barometric pressure and associated pressure differentials measured between subslab and indoor regimes and suggests that advective vapor transport and intrusion can result in elevated indoor TCE concentrations well above risk levels even with low‐to‐modest pressure differentials. This indicates that vapor intrusion can occur in response to diurnal pressure dynamics in coastal regions and suggests that similar natural phenomenon may control vapor intrusion dynamics in other regions, exhibiting similar pressure, geochemical, hydrogeologic, and climatic conditions. While dynamic indoor TCE concentrations have been observed in this coastal environment, questions remain regarding whether this hydrogeologic and climatic setting represent a special case, and how best to determine when continuous monitoring should be required to most appropriately minimize exposure durations as early as possible. ©2017 Wiley Periodicals, Inc.     

Characterization of airborne particles at a high-btu coal-gasification pilot plant

Airborne particles in fugitive emissions have been measured at a slagging fixed-bed coal-gasification pilot plant using lignite. Sampling was conducted during shutdown operations and opening of the gasifier following an aborted startup. Aerosol collected with a Sierra high-volume impactor was subjected to analysis by gas chromatography, mass spectrometry, and scanning electron microscopy; aerosol collected with an Andersen low-volume impactor was subjected to flameless atomic absorption analysis. The data show that the bulk of the trace organic material is associated with small particles: these data are similar to data on ambient air reported in the literature. Particle morphologies resemble those of fly ash from coal combustion, including smooth spheres, vesicular spheres, and crystalline material. Trace element size distributions are bimodal and resemble data for ambient air. Pb-containing particles are generally submicron, while particles containing Al, Fe, and other crustal species are mostly of supermicron size. Aluminum-based aerosol enrichment factors calculated from the lignite composition show that the composition of the aerosol resembles that of the coal, with the exception of modest enrichments of Mg, Na, As, and Pb in the submicron size range. Aerosol enrichment factors based on the earth's crustal composition are somewhat greater than those based on coal composition for several elements, suggesting potential errors in using crustal enrichment data to investigate chemical fractionation during aerosol formation.     

Characterization of airborne trace metal and trace organic species from coal gasification

Fugitive emissions from a slagging fixed-bed coal-gasification pilot plant were analyzed by flameless atomic absorption spectrophotometry, gas chromatography, and mass spectrometry for trace metal and trace organic species. Analysis of the size distributions of airborne particulate matter inside the plant showed an abundance of large metal-containing particles; outdoor distributions in the vicinity of the plant resembled the indoor distributions, suggesting the importance of the gasifier in influencing ambient air quality. This conclusion was further supported by identification of similar organic compounds inside and outside the plant. Trace element enrichment factors based on the earth's crustal composition were greater than those based on the composition of the lignite used in the gasifier, showing the importance of characterizing the proper source material when inverstigating chemical fraction during aerosol formation. Enrichments in the present study were much greater than those found in previous sampling during aborted start-up and cleaning procedures, where normal operating temperatures had not yet been reached. Both studies showed evidence of enrichment factors which decreased with increasing particle size. Although much of the airborne mass was associated with large particles having low respirability, the high concentrations of some metals indoors suggests that further assessment of potential occupational exposures is warranted.     

Vapor Intrusion Monitoring Method Cost Comparisons: Automated Continuous Analytical Versus Discrete Time‐Integrated Passive Approaches

Vapor intrusion characterization efforts are challenging due to complexities associated with indoor background sources, preferential subsurface migration pathways, indoor and shallow subsurface concentration dynamics, and representativeness limitations associated with manual monitoring and characterization methods. For sites experiencing trichloroethylene (TCE) vapor intrusion, the potential for acute risks poses additional challenges, as the need for rapid response to acute toxicity threshold exceedances is critical in order to minimize health risks and associated liabilities. Currently accepted discrete time‐integrated vapor intrusion monitoring methods that employ passive diffusion–adsorption and canister samplers often do not result in sufficient temporal or spatial sampling resolution in dynamic settings, have a propensity to yield false negative and false positive results, and are not able to prevent receptors from acute exposure risks, as sample processing times exceed exposure durations of concern. Multiple lines of evidence have been advocated for in an attempt to reduce some of these uncertainties. However, implementation of multiple lines of evidence do not afford rapid response capabilities and typically rely on discrete time‐integrated sample collection methods prone to nonrepresentative results due to concentration dynamics. Recent technology innovations have resulted in the deployment of continuous monitoring platforms composed of multiplexed laboratory grade analytical components integrated with quality control features, telemetry, geographical information systems, and interpolation algorithms for automatically generating geospatial time stamped renderings and time‐weighted averages through a cloud‐based data management platform. Automated alerts and responses can be engaged within 1 minute of a threshold exceedance detection. Superior temporal and spatial resolution also results in optimized remediation design and mitigation system performance confirmation. While continuous monitoring has been acknowledged by the regulatory community as a viable option for providing superior results when addressing spatial and temporal dynamics, until very recently, these approaches have been considered impractical due to cost constraints and instrumentation limitations. Recent instrumentation advancements via automation and multiplexing allow for rapid and continuous assessment and response from multiple locations using a single instrument. These advancements have reduced costs to the point where they are now competitive with discrete time‐integrated methods. In order to gain more regulatory and industry support for these viable options, there is an immediate need to perform a realistic cost comparison between currently approved discrete time‐integrated methods and newly fielded continuous monitoring platforms. Regulatory support for continuous monitoring platforms will result in more effectively protecting the public, provide property owners with information sufficient to more accurately address potential liabilities, reduce unnecessary remediation costs for situations where risks are minimal, lead to more effective and surgical remediation strategies, and allow practitioners to most effectively evaluate remediation system performance. To address this need, a series of common monitoring scenarios and associated assumptions were derived and cost comparisons performed. Scenarios included variables such as number of monitoring locations, duration, costs to meet quality control requirements, and number of analyses performed within a given monitoring campaign. Results from this effort suggest that for relatively larger sites where five or more locations will be monitored (e.g., large buildings, multistructure industrial complexes, educational facilities, or shallow groundwater plumes with significant spatial footprints under residential neighborhoods), procurement of continuous monitoring services is often less expensive than implementation of discrete time‐integrated monitoring services. For instance, for a 1‐week monitoring campaign, costs‐per‐analysis for continuous monitoring ranges from approximately 1 to 3 percent of discrete time‐integrated method costs for the scenarios investigated. Over this same one‐week duration, for discrete time‐integrated options, the number of sample analyses equals the number of data collection points (which ranged from 5 to 30 for this effort). In contrast, the number of analyses per week for the continuous monitoring option equals 672, or four analyses per hour. This investigation also suggests that continuous automated monitoring can be cost‐effective for multiple one‐week campaigns on a quarterly or semi‐annual basis in lieu of discrete time‐integrated monitoring options. In addition to cost benefits, automated responses are embedded within the continuous monitoring service and, therefore, provide acute TCE risk‐preventative capabilities that are not possible using discrete time‐integrated passive sampling methods, as the discrete time‐integrated services include analytical efforts that require more time than the exposure duration of concern. ©2016 Wiley Periodicals, Inc.     

Vapor intrusion risk evaluation using automated continuous chemical and physical parameter monitoring

Vapor intrusion risk characterization efforts are challenging due to complexities associated with background indoor air constituents, preferential subsurface migration pathways, and representativeness limitations associated with traditional randomly timed time‐integrated sampling methods that do not sufficiently account for factors controlling concentration dynamics. The U.S. Environmental Protection Agency recommends basing risk related decisions on the reasonable maximum exposure (RME). However, with very few exceptions, practitioners have not been applying this criterion. The RME will most likely occur during upward advective flux conditions. As such, for RME determinations, it is important to sample when upward advective flux conditions are occurring. The most common vapor intrusion assessment efforts include randomly timed sample collection events, and therefore do not accurately yield RME estimates. More specifically, researchers have demonstrated that randomly timed sampling schemes can result in false negative determinations of potential risk corresponding to RMEs. For sites experiencing trichloroethylene (TCE) vapor intrusion, the potential for acute risks poses additional challenges, as there is a critical need for rapid response to exposure exceedances to minimize health risks and liabilities. To address these challenges, continuous monitoring platforms have been deployed to monitor indoor concentrations of key volatile constituents, atmospheric pressure, and pressure differential conditions that can result in upward toxic vapor transport and entry into overlying buildings. This article demonstrates how vapor intrusion RME‐based risks can be successfully and efficiently determined using continuous monitoring of concentration and parameters indicating upward advective chemical flux. Time series analyses from multiple selected 8‐ and 24‐hr time increments during upward advective TCE flux conditions were performed to simulate results expected from the most commonly employed sampling methods. These analyses indicate that, although most of the selected time increments overlap within the same 24‐hr window, results and conclusions vary. As such, these findings demonstrate that continuous monitoring of concentration and parameters such as differential pressure and determination of a time‐weighted concentration average over a selected duration when upward advective flux is occurring can allow for a realistic RME‐based risk estimate.     

Herbicide impact on Hormosira banksii gametes measured by fluorescence and germination bioassays

The innovative bioassay described here involves chlorophyll a fluorescence measurements of gametes from the macroalgae, Hormosira banksii, where gametes (eggs) were exposed to Diuron, Irgarol and Bromacil. Response was assessed as percent inhibition from control of effective quantum yield (DeltaF/Fm') of photosystem II, herein referred to as % PSII Inhibition. This was measured with the dual-channelled pulse amplitude modulated (PAM) fluorometer, ToxY-PAM. The fluorescence bioassay was run simultaneously with an established H. banksii germination bioassay to compare sensitivity, precision, and time-to-result. The fluorescence bioassay gave highly sensitive results evidenced by EC(50)s (% PSII Inhibition) for Diuron, Irgarol and Bromacil being three, four and three orders of magnitude (respectively) lower than EC50s generated from the germination bioassays. Precision of the fluorescence bioassay was demonstrated with low coefficient of variations (<30%) for all three toxicants. With regard to time, the fluorescence bioassay gave results within 6h, as opposed to more than 50h for the germination bioassay.     

Stationary sources of airborne lead: a comparison of emissions data for southern California

Estimates for the air releases of lead from stationary point sources are considered for the South Coast Air Basin of California. We have examined four databases published by U.S. Environmental Protection Agency, the California Air Resources Board, and the South Coast Air Quality Management District. Our analysis indicates that none of the databases includes every emitting facility in the South Coast Air Basin of California and that other discrepancies among the databases exist. Additionally, the data have been analyzed for temporal variation, and some of the California Air Resources Board data are not current. The South Coast Air Quality Management District inventory covers 12 times more facilities in 2001 than in 1996. From this analysis, we conclude that all four of the databases would benefit by sharing data, increasing transparency, analyzing uncertainty, and standardizing emission estimation methods.     

Ocean fertilization for geoengineering: A review of effectiveness,environmental impacts and emerging governance

Dangerous climate change is best avoided by drastically and rapidly reducing greenhouse gas emissions. Nevertheless, geoengineering options are receiving attention on the basis that additional approaches may also be necessary. Here we review the state of knowledge on large-scale ocean fertilization by adding iron or other nutrients, either from external sources or via enhanced ocean mixing. On the basis of small-scale field experiments carried out to date and associated modelling, the maximum benefits of ocean fertilization as a negative emissions technique are likely to be modest in relation to anthropogenic climate forcing. Furthermore, it would be extremely challenging to quantify with acceptable accuracy the carbon removed from circulation on a long term basis, and to adequately monitor unintended impacts over large space and time-scales. These and other technical issues are particularly problematic for the region with greatest theoretical potential for the application of ocean fertilization, the Southern Ocean. Arrangements for the international governance of further field-based research on ocean fertilization are currently being developed, primarily under the London Convention/London Protocol.     

Spatial-temporal variability of aerosol sources based on chemical composition and particle number size distributions in an urban settlement influenced by metallurgical industry

Environmental Science and Pollution Research - The Moravian-Silesian region of the Czech Republic with its capital city Ostrava is a European air pollution hot spot for airborne particulate matter...     

The Effect of Channelization on Floodplain Sediment Deposition and Subsidence Along the Pocomoke River,Maryland1

Kroes, Daniel E. and Cliff R. Hupp, 2010. The Effect of Channelization on Floodplain Sediment Deposition and Subsidence Along the Pocomoke River, Maryland. Journal of the American Water Resources Association (JAWRA) 46(4): 686-699. DOI: 10.1111/j.1752-1688.2010.00440.x Abstract: The nontidal Pocomoke River was intensively ditched and channelized by the mid-1900s. In response to channelization; channel incision, head-cut erosion, and spoil bank perforation have occurred in this previously nonalluvial system. Six sites were selected for study of floodplain sediment dynamics in relation to channel condition. Short- and long-term sediment deposition/subsidence rates and composition were determined. Short-term rates (four years) ranged from 0.6 to 3.6 mm/year. Long-term rates (15-100+ years) ranged from −11.9 to 1.7 mm/year. ¹³⁷Cs rates (43 years) indicate rates of 0.24 to 7.4 mm/year depending on channel condition. Channelization has limited contact between streamflow and the floodplain, resulting in little or no sediment retention in channelized reaches. Along unchannelized reaches, extended contact and depth of river water on the floodplain resulted in high deposition rates. Drainage of floodplains exposed organic sediments to oxygen resulting in subsidence and releasing stored carbon. Channelization increased sediment deposition in downstream reaches relative to the presettlement system. The sediment storage function of this river has been dramatically altered by channelization. Results indicate that perforation of spoil banks along channelized reaches may help to alleviate some of these issues.