Effluents and residues from industrial sites for carbon dioxide capture: a review

The adverse effects of climate change calls for the rapid transformation of manufacturing processes to decrease the emissions of carbon dioxide. In particular, a lower carbon footprint can be achieved by capturing carbon dioxide at the site of emission. Here we review the use of industrial effluents, waste and residues to capture carbon dioxide. Waste include steelmaking slag, municipal solid waste incinerator ashes, combustion fly ash, black liquor, paper mill waste, mining waste, cement waste, construction and demolition waste, waste from the organic industry, and flue gas desulfurization gypsum waste. Capture capacities range from 2 to 800 kg of carbon dioxide per ton of waste, depending on processes, waste type and conditions. Cement waste and flue gas desulfurization gypsum waste show the highest capture capacity per ton of waste.

     

Assessment of enrichment factors and grain size influence on the metal distribution in riverbed sediments (Anll��ns River, NW Spain)

The metals distribution in the bed sediments of the Anllóns River was studied, with special emphasis on the evaluation of the metal distribution as a function of the granulometric fraction chosen for the analysis. Statistical significant differences between the distribution of K, Ca, Cr, Mn, As, Rb, Sr and Nb in the bulk (<2 mm) and fine fraction (<63 μm) were not found. Fe, Ni, Cu, Ga, Zr, Zn and Pb commonly appear in higher concentrations in the fine fraction, whereas Ti appears in higher concentrations in the bulk fraction. In general, it was observed that contamination phenomena tend to equalise the concentrations of both fractions, and this was mainly explained as the result of two processes. First, the formation of coatings over sands and, second, the formation of large aggregates (pseudo-sands) at sites located over basic rocks, whose chemical behaviour is closer to that of clays and could be responsible for significant adsorption processes. Normalisation techniques to evaluate contamination were applied by testing Nb, Sr, Rb or Ga as normaliser elements and by using crustal or shale average values for background concentrations. The most satisfactory result was obtained when using shale average values and Ga as the normaliser element. Arsenic was identified as the main contaminant of the basin, exceeding in all cases the low-effect reference values proposed by sediment quality guidelines and in two cases the medium-effect reference values. These sites were identified by multivariate techniques, which allow differentiating site 10 as affected by anthropogenic inputs related to past mining activities.     

An environmental measurement for a dynamic and endogenous global environmental Kuznets curve in the global context

Environmental Science and Pollution Research - Planetary boundaries (PB) is a novel conceptual framework that assesses the state of processes fundamental to the stability of the Earth system....     

Resistant weeds were controlled by the combined use of herbicides and bioherbicides

The intensive and abundant use of synthetic herbicides has been questioned in recent decades due to the strong dependence and also the resistance effects that are identified in weeds. Several grain crops suffer from the weed control system because many of the weeds are already resistant to the main herbicides that are used. In recent years, there has been a large gap in the market without the addition of new synthetic herbicides with mechanisms of action that differ from those already existing. The objective of this short piece is to address and overcome this challenge and bring an innovative and alternative solution that proposes a synergistic action system between bioherbicides produced by the fungus Trichoderma koningiopsis and synthetic herbicides (2,4‐dichlorophenoxyacetic acid, glyphosate, and ammonium glufosinate). The plants included in this study were Bidens pilosa (amor seco, or in the United States, beggar ticks or Spanish needle), Euphorbia heterophylla (adeus‐brasil), and Conyza bonariensis (margaridinha‐do‐campo, or, in the United States, hairy fleabane or asthmaweed). It was verified that, in the application of the biocomposites in the presence of chemical herbicides, potentiation of the phytotoxic action (100%) occurred under the target plants, emphasizing phytotoxicity to the weed, C. bonariensis, which is currently resistant to available herbicides. The bioherbicides studied have promising characteristics to be explored in the biocontrol of weeds.     

Movements and environmental preferences of the shortfin mako, <Emphasis Type="Italic">Isurus oxyrinchus</Emphasis>, in the southeastern Pacific Ocean

Nine individuals of shortfin mako, Isurus oxyrinchus, were tracked in the southeastern Pacific Ocean, off northern Chile, by means of pop-up satellite archival tags. No common pattern was observed in their trajectories, apart from a movement onshore of all the fish tracked during June–August. The average estimated rate of movement was of c. 27 km day⁻¹. Data were collected and processed for a total of 341 days, including 33 days for one recaptured fish specimen, allowing high-resolution archived data to be downloaded. The fish spent most of their time in the mixed layer but undertook dives down to 888 m. Ambient temperatures ranged between 4.6 and 24.1°C, and the sea surface temperatures recorded ranged from 13.4 to 24.1°C during the study period. No clear diel pattern in depth behavior was observed, but mean vertical distribution was deeper during the daytime. Moreover, a foraging pattern, consisting of rapid descents below the thermocline followed by slower ascents, was generally observed during daylight hours. Dissolved oxygen concentration and water temperature seem to be the main factors affecting the vertical range of the species in the area. This is the first study on electronic tagging of the shortfin mako in the southeastern Pacific Ocean and covers the longest total tracking period reported so far for this species.     

Analytic Modeling of Rainwater Harvesting in the Brazilian Semiarid Northeast

During the past two decades, government efforts to provide water access to rural communities in Brazil's semiarid Northeast region have focused on building systems to capture and store rainwater, most importantly through the One Million Cisterns Program (P1MC). This article presents an analytic model based on daily precipitation data to evaluate the sustainability of rainwater capture. Application of this model to analysis of the P1MC reveals the heterogeneous climate in this region causes large spatial variability in the effectiveness of this program. In addition, the size of the area of capture, the run‐off coefficient of the roofs, and the amount of first‐flush diversion also have important effects. This analysis demonstrates while rainwater capture can offer sufficient water for drinking, as a stand‐alone solution it cannot meet P1MC objectives of guaranteeing sustainable and universal access to water for drinking, cooking, and basic hygiene in all regions and years.     

Bottom-up control of consumers leads to top-down indirect facilitation of invasive annual herbs in semiarid Chile

The abundance of exotic plants is thought to be limited by competition with resident species (including plants and generalist herbivores). In contrast, observations in semiarid Chile suggest that a native generalist rodent, the degu (Octodon degus), may be facilitating the expansion of exotic annual plants. We tested this hypothesis with a 20-year data set from a World Biosphere Reserve in mediterranean Chile. In this semiarid environment, rainfall varies annually and dramatically influences cover by both native and exotic annual plants; degu population density affects the composition and cover of exotic and native annual plants. In low-rainfall years, cover of both native and exotic herbs is extremely low. Higher levels of precipitation result in proportional increases in cover of all annual plants (exotic and native species), leading in turn to increases in degu population densities, at which point they impact native herbs in proportion to their greater cover, indirectly favoring the expansion of exotic plants. We propose that bottom-up control of consumers at our site results in top-down indirect facilitation of invasive annual herbs, and that this pattern may be general to other semiarid ecosystems.     

Impact of Urban Growth and High Residential Irrigation on Streamflow and Groundwater Levels in a Peri‐Urban Semiarid Catchment

The impact of urbanization on groundwater is not simple to understand, as it depends on a variety of factors such as climate, hydrogeology, water management practices, and infrastructure. In semiarid landscapes, the urbanization processes can involve high water consumptions and irrigation increases, which in turn may contribute to groundwater recharge. We assessed the hydrological impacts of urbanization and irrigation rates in an Andean peri‐urban catchment located in Chile, in a semiarid climate. For this purpose, we built and validated a coupled surface–groundwater model that allows the verification of a strong stream–aquifer interaction in areas with shallow groundwater, higher than some sewers and portions of the stream. Moreover, we also identified a significant local recharge associated with pipe leaks and inefficient urban irrigation. From the evaluation of different future scenarios, we found a sustainable water conservation scenario will decrease the current groundwater levels, while the median flow reduces from 408 to 389 L/s, and the low flow (Q_95%) from 43 to 22L/s. Overall, our results show the relevance of integrating the modeling of surface and subsurface water resources at different spatial and temporal scales, when assessing the effect of urban development and the suitability of urban water practices.     

Landscape--wildfire interactions in southern Europe: implications for landscape management

Every year approximately half a million hectares of land are burned by wildfires in southern Europe, causing large ecological and socio-economic impacts. Climate and land use changes in the last decades have increased fire risk and danger. In this paper we review the available scientific knowledge on the relationships between landscape and wildfires in the Mediterranean region, with a focus on its application for defining landscape management guidelines and policies that could be adopted in order to promote landscapes with lower fire hazard. The main findings are that (1) socio-economic drivers have favoured land cover changes contributing to increasing fire hazard in the last decades, (2) large wildfires are becoming more frequent, (3) increased fire frequency is promoting homogeneous landscapes covered by fire-prone shrublands; (4) landscape planning to reduce fuel loads may be successful only if fire weather conditions are not extreme. The challenges to address these problems and the policy and landscape management responses that should be adopted are discussed, along with major knowledge gaps.     

Landscape evaluation in conservation: molecular sampling and habitat modeling for the Iberian lynx.

Conservation of endangered species requires comprehensive understanding of their distribution and habitat requirements, in order to implement better management strategies. Unfortunately, this understanding is often difficult to gather at the short term required by rapidly declining populations of many rare vertebrates. We present a spatial habitat modeling approach that integrates a molecular technique for species detection with landscape information to assess habitat requirements of a critically endangered mammalian carnivore, the Iberian lynx (Lynx pardinus), in a poorly known population in Spain. We formulated a set of model hypotheses for habitat selection at the spatial scale of home ranges, based on previous information on lynx requirements of space, vegetation, and prey. To obtain the required data for model selection, we designed a sampling protocol based on surveys of feces and their molecular analysis for species identification. After comparing candidate models, we selected a parsimonious one that allowed (1) reliable assessment of lynx habitat requirements at the scale of home ranges, (2) prediction of lynx distribution and potential population size, and (3) identification of landscape management priorities for habitat conservation. This model predicted that the species was more likely to occur in landscapes with a higher percentage of rocky areas and higher cover of bushes typical of mature mediterranean shrubland mosaics. Its accuracy for discriminating lynx presence was approximately 85%, indicating high predictive performance. Mapping model predictions showed that only 16% of the studied areas constitute potential habitat for lynx, even though the region is dominated by large extents of well-preserved native vegetation with low human interference. Habitat was mostly clumped in two nearby patches connected by vegetation adequate for lynx dispersal and had a capacity for 28-62 potential breeding territories. The lynx population in Sierra Morena is probably the largest persisting today, but it is still critically small for optimism about its long-term persistence. Model results suggest habitat conservation and restoration actions needed for preserving the species, including reconciliation of hunting management with preservation of mature shrubland over large areas (particularly in rocky landscapes). The approach presented here can be applied to many other species for which the ecological information needed to develop sound habitat conservation strategies is lacking.