Volatilization of Chemicals from Drinking Water to Indoor Air: The Role of Residential Washing Machines

ABSTRACT

Previous research has indicated that residential washing machines are potential sources of pollution due to the associated use of chemicals found in consumer products, for example, ethanol in laundry detergent and chlorine in bleach.^1,2 Washing machines may also emit hazardous air pollutants found in contaminated drinking water. To better understand the extent and impact of chemical emissions from tap water, 26 experiments were completed using a residential washing machine and a cocktail of chemical tracers representing a wide range of physicochemical properties. Variable operating conditions for these experiments included water temperature, amount of clothes present in the machine, water volume, and level of washwater agitation. Chemical stripping efficiencies and mass transfer coefficients were determined during each cycle (fill, wash, and rinse) of a normal washing machine event. Headspace ventilation rates were determined using an isobutylene tracer gas. Mass transfer rates were significantly influenced by operating parameters as exhibited by a wide range of chemical stripping efficiencies. Stripping efficiencies ranged from 0.74 to 36% for acetone, 8.2 to 99% for toluene, 10 to 99% for ethylbenzene, and 6.9 to 100% for cyclohexane.     

Evaluation of preservation methods for nutrient species collected by automatic samplers

Automatic samplers are a common method of data collection for numerous monitoring projects in the South Florida region and elsewhere. Although total phosphorus (TP) is the primary parameter of interest within this region, nitrogen species such as ammonia nitrogen (NH₄-N), nitrate+nitrite nitrogen (NO_x-N), and total kjeldahl nitrogen (TKN) are also collected and analyzed. Federal and state quality assurance guidelines require nutrient samples to be preserved by acidification with H₂SO₄ to a pH < 2 and stored immediately at 4 °C. However, the remoteness of manysampling locations in South Florida makes it difficult to supplyelectricity for the refrigeration of samples collected by autosamplers. In addition, the use of propane-powered refrigerated autosamplers is a costly and ineffective solution in the South Florida climate. Consequently, while samples collected at these remote locations are routinely pre-preservedwith acid, they are not cooled to 4 °C for a period fromone to seven days. This study evaluated if a statistically significant difference ( = 0.05) existed between concentrations of nitrogen species from a common source samplethat was either: processed immediately; refrigerated to 4 °C for seven days; or not refrigerated for seven days.In all cases, the collected sample was pre-preserved by adding 1 mL of 50% H₂SO₄ to each 1 L discrete sample container before each 7 day testing period. Differences in concentrations of the calculated parameter total nitrogen (TN)were also investigated.Analyses using the Wilcoxon Signed-Rank Test showed no significant differences among the three treatment groups for NO_x-N, TKN, TN and TP. Significant differences were observedwhen the NH₄-N samples that were processed immediately werepaired with NH₄-N samples that were left unrefrigerated or refrigerated for seven days. Information from this study can be used by researchers and managers in evaluating the usefulness of nutrient water quality data that is collected when sample refrigeration is not available.     

Indoor particle size distributions in homes with open fires and improved Patsari cook stoves

Particulate pollution has been clearly linked with adverse health impacts from open fire cookstoves, and indoor air concentrations are frequently used as a proxy for exposures in health studies. Implicit are the assumptions that the size distributions for the open fire and improved stove are not significantly different, and that the relationship between indoor concentrations and personal exposures is the same between stoves. To evaluate the impact of these assumptions size distributions of particulate matter in indoor air were measured with the Sioutas cascade impactor in homes using open fires and improved Patsari stoves in a rural Purepecha community in Michoacan, Mexico. On average indoor concentrations of particles less than 0.25 μm were 72% reduced in homes with improved Patsari stoves, reflecting a reduced contribution of this size fraction to PM_2.5 mass concentrations from 68% to 48%. As a result the mass median diameter of indoor PM_2.5 particulate matter was increased by 29% with the Patsari improved stove compared to the open fire (from 0.42 μm to 0.59 μm, respectively). Personal PM_2.5 exposure concentrations for women in homes using open fires were approximately 61% of indoor concentration levels (156 μg m^?3 and 257 μg m^?3 respectively). In contrast personal exposure concentrations were 77% times indoor air concentration levels for women in homes using improved Patsari stoves (78 μg m^?3and 101 μg m^?3 respectively). Thus, if indoor air concentrations are used in health and epidemiologic studies significant bias may result if the shift in size distribution and the change in relationship between indoor air concentrations and personal exposure concentrations are not accounted for between different stove types.     

Mitigation of the heat island effect in urban New Jersey

Implementation of urban heat island (UHI) mitigation strategies such as increased vegetative cover and higher-albedo surface materials can reduce the impacts of biophysical hazards in cities, including heat stress related to elevated temperatures, air pollution and associated public health effects. Such strategies also can lower the demand for air-conditioning-related energy production. Since local impacts of global climate change may be intensified in areas with UHIs, mitigation strategies could play an increasingly important role as individuals and communities adapt to climate change. We use CITYgreen, a GIS-based modeling application, to estimate the potential benefits of urban vegetation and reflective roofs as UHI mitigation strategies for case study sites in and around Newark and Camden, New Jersey.

The analysis showed that urban vegetation can reduce health hazards associated with the UHI effect by removing pollutants from the air. Less affluent, inner-city neighborhoods are the ones in which the hazard potential of the UHI effect is shown to be greatest. However, these neighborhoods have less available open space for tree planting and therefore a lower maximum potential benefit. As the climate warms, these neighborhoods may face greater consequences due to interactions between the UHI effect and global climate change. Results also show that urban vegetation is an effective and economically efficient way to reduce energy consumption and costs at the sites.     

(137)Cs inter-plant concentration ratios provide a predictive tool for coral atolls with distinct benefits over transfer factors

Inter-plant concentration ratios (IPCR) [Bqg(-1)(137)Cs in coral atoll tree food crops/Bqg(-1)(137)Cs in leaves of native plant species whose roots share a common soil volume] can replace transfer factors (TF) to predict (137)Cs concentration in tree food crops in a contaminated area with an aged source term. The IPCR strategy has significant benefits relative to TF strategy for such purposes in the atoll ecosystem. IPCR strategy applied to specific assessments takes advantage of the fact that tree roots naturally integrate (137)Cs over large volumes of soil. Root absorption of (137)Cs replaces large-scale, expensive soil sampling schemes to reduce variability in (137)Cs concentration due to inhomogeneous radionuclide distribution. IPCR [drinking-coconut meat (DCM)/Scaevola (SCA) and Tournefortia (TOU) leaves (native trees growing on all atoll islands)] are log-normally distributed (LND) with geometric standard deviation (GSD)=1.85. TF for DCM from Enewetak, Eneu, Rongelap and Bikini Atolls are LND with GSDs of 3.5, 3.0, 2.7, and 2.1, respectively. TF GSD for Rongelap copra coconut meat is 2.5. IPCR of Pandanus fruit to SCA and TOU leaves are LND with GSD=1.7 while TF GSD is 2.1. Because IPCR variability is much lower than TF variability, relative sampling error of an IPCR field sample mean is up 6- to 10-fold lower than that of a TF sample mean if sample sizes are small (10-20). Other IPCR advantages are that plant leaf samples are collected and processed in far less time with much less effort and cost than soil samples.     

Consumer product-related eye injury in the United States, 1998-2002

PROBLEM: Eye injury is currently a leading cause of visual impairment and monocular blindness in the United States. Information regarding consumer products associated with eye injuries can have important implications for the prevention of these injuries. METHODS: The National Electronic Injury Surveillance System (NEISS) was used to describe the types of consumer products associated with emergency department treated eye injuries in the United States from 1998 through 2002. RESULTS: The leading product type associated with eye injuries was welding equipment followed by household cleaners, basketball equipment, workshop equipment, and adhesives. Eye injuries attributed to hardware, tools, construction, sports, toys, and lawn equipment were more common among males. In females, eye injuries attributable to chemicals, housewares, storage and organization, and bed and bath items were more common. Differences were also apparent across the age spectrum. CONCLUSION: This study identified specific products and categories of products frequently associated with eye injury and prevention initiatives should focus on these items. IMPACT ON INDUSTRY: This study has identified consumer products associated with eye injuries requiring medical treatment in the United States. Manufacturers of these products could be encouraged to add or strengthen safety messages regarding the potential for eye injury.     

NEW HAMPSHIRE WATER LAW: AN INTERPRETIVE OVERVIEW1

ABSTRACT: New Hampshire's riparian water law, first modified judicially, has been more drastically changed by recent legislative and administrative action. As it stands, however, the judicially enforced doctrine of reasonable use appears to be utterly inadequate to handle increasing water demands. The protection of the public interest has imposed substantial limitations on the use of riparian water rights, all under the guise of the exercise of the police power, i.e., the protection of the public health, safety, and welfare. The efficient use of the state's water resources has been further crippled by the widespread and indiscriminate exercise of eminent domain. As a result, the state is now considering the imposition of a permit system that has the potential to streamline the allocation of water. Such a system should take into consideration the public interest factors that have recently frustrated the exercise of riparian rights and the effective use of the state's water resources.     

Why do lay people believe that satisfaction and performance are correlated? possible sources of a commonsense theory

Decades of research have shown that the correlation between job satisfaction and job performance is modest in magnitude, yet lay people are thought to believe strongly that satisfied or ‘happy’ employees are more productive at work. This paper first documents the strength and pervasiveness of belief in several versions of the happy–productive worker hypothesis (Study 1), then proposes and explores potential substantive explanations for these beliefs (Study 2). It is possible that lay people base their beliefs on genuinely stronger relationships that occur at a different level of analysis than usually studied by researchers, and/or that exist between satisfaction‐like and performance‐like variables other than the constructs typically investigated by scholars. Study 2 provides data relevant to several of these possibilities. The most compelling findings were at the within‐person level of analysis. The average within‐person correlation between momentary task satisfaction and concurrent perceived task performance was 0.57. Individuals feel more satisfied than usual when they believe they are performing better than usual for them. If lay persons mistakenly generalize from their own within‐person experiences of satisfaction–performance covariation to the between‐persons level, this relationship may be the basis for the strong lay belief that satisfied workers perform better. Copyright © 2003 John Wiley & Sons, Ltd.