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281.
MajorionchemistryandcontrolofweatheringofBhimtalLake,HumaunHimalaya,India¥ManpreetSingh;B.K.Das(CentreofAdvancedStudyinGeolog... 相似文献
282.
Sujit Das T. Randall Curlee Colleen G. Rizy Susan M. Schexnayder 《Resources, Conservation and Recycling》1995,14(3-4)
Changes in the trends in the material composition of domestic and imported automobiles and the increasing cost of landfilling the non-recyclable portion of automobiles (automobile shredder residue or ASR) pose questions about the future of automobile recycling in the United States. In response to these challenges, new and innovative approaches to automobile recycling are being developed. This paper presents the findings of a recent study to examine the impacts of these changes on the life cycle energy consumption of automobiles and on the quantity of waste that must be disposed of. Given the recycle status quo, trends in material composition and the viability of recycling the non-metallic components of the typical automobile are of secondary importance when compared to the energy consumed during the life of the automobile. The energy savings resulting from small changes in the fuel efficiency of a vehicle overshadow potential energy losses associated with the adoption of new and possibly non-recyclable materials. Under status quo conditions, the life cycle energy consumed by the typical automobile is projected to decrease from 599 million Btus in 1992 to 565 million Btus in 2000. Energy consumed during the manufacture of the typical car will increase from about 120 to 140 million Btus between 1992 and 2000, while energy used during vehicle operation will decrease from 520 to 480 million Btus. This study projects that energy saved at the recycle step will increase from 41 million Btus in 1992 to 55 million Btus in 2000. This study also investigated the energy impacts of several potential changes to the recycle status quo, including the adoption of technologies to retrieve the heat value of ASR by incineration and the recycle of some or all thermoplastics in the typical automobile. The study estimates that under optimistic conditions —i.e., the recycling of all thermoplastics and the incineration with heat recovery of all remaining ASR —about 8 million Btus could be saved per automobile —i.e., an increase from about 55 to 63 million Btus. In the more realistic scenario —i.e., the recycling of easy-to-remove thermoplastic components (bumper covers and dash-boards) —the potential energy savings are about 1 million Btus per vehicle. It is estimated that the annual quantity of ASR in the United States could be reduced from about 5 billion pounds to as little as 1 billion pounds of ash if all ASR is incinerated. Alternatively, ASR quantity could be reduced to about 4 billion pounds if all thermoplastics in automobiles are recycled. However, in the case of recycling only thermoplastic bumper covers and dashboards, the quantity of ASR would be reduced by only 0.2 billion pounds. A significant reduction or increase in the size of the ASR waste stream will not in itself have a large impact on the solid waste stream in the United States. 相似文献
283.
As with other construction materials, coal fly ash contains trace metals that can leach into the natural environment. As part of a broader effort to encourage appropriate coal combustion product use in infrastructure applications (e.g., road construction, stabilization, and structural fill), this study evaluated traditional and low‐cost adsorbent alternatives for their capacity to attenuate trace metals. Batch sorption tests were used as a preliminary screen for a wide variety of low cost (e.g., steel byproducts, rubber dust, and compost) and innovative materials (e.g., kudzu, biofilm, and pond weed) as well as conventional materials (activated carbon, alumina, and zeolites). The removal rates were demonstrated in this study by observing the calculated distribution coefficient (Kd) which were determined using a program called MATLAB. Limestone and steel byproducts were found to be particularly effective with large Kd values of 15,740, 1,520, and 540 L kg?1 for cadmium, chromium, and selenium and, for ladle refractory and mill scale, Kd values of 3,910, 670, and 1,760 L kg?1 were observed. Among the three metals tested for this study, it was observed that most low cost and innovative materials removed cadmium quite efficiently; however, the removal of selenium and chromium depended on the substrate and prevailing pH. In general, these results suggest that alternative materials may have relevance in niche applications where leaching is a concern that can be addressed through enhanced attenuation capacity via blending or layering of adsorbents. 相似文献
284.
Mahesh Kumar Sahu Ashim Das Gupta 《Journal of the American Water Resources Association》2001,37(3):675-684
ABSTRACT: Operation of a storage‐based reservoir modifies the downstream flow usually to a value higher than that of natural flow in dry season. This could be important for irrigation, water supply, or power production as it is like an additional downstream benefit without any additional investment. This study addresses the operation of two proposed reservoirs and the downstream flow augmentation at an irrigation project located at the outlet of the Gandaki River basin in Nepal. The optimal operating policies of the reservoirs were determined using a Stochastic Dynamic Programming (SDP) model considering the maximization of power production. The modified flows downstream of the reservoirs were simulated by a simulation model using the optimal operating policy (for power maximization) and a synthetic long‐term inflow series. Comparing the existing flow (flow in river without reservoir operation) and the modified flow (flow after reservoir operation) at the irrigation project, the additional amount of flow was calculated. The reliability analysis indicated that the supply of irrigation could be increased by 25 to 100 percent of the existing supply over the dry season (January to April) with a reliability of more than 80 percent. 相似文献
285.
Radharani Das Binay K. Dutta Valter Maurino Davide Vione Claudio Minero 《Environmental Chemistry Letters》2009,7(4):337-342
In this paper we show that bromide scavenges the ·OH radicals formed upon photolysis of nitrate, before they leave the solvent cage. Bromide can thus inhibit the in-cage recombination between ·OH and ·NO2. The consequence is an increased generation of ·NO2 and nitrite and of Br2 ?· + ·OH, compared to ·OH alone in the absence of bromide. We show that this effect compensates for the lower reactivity of Br 2 ?· compared to ·OH toward certain organic substrates, e.g. phenol and tryptophan. Our findings could lead to a deep revision of the present views of the role of bromide in saltwater photochemistry. 相似文献
286.
Mukesh Singh Avijit Das Debashree Singh Pratiti Maiti Md. Shabbir Anangsha Das 《Environmental Chemistry Letters》2014,12(2):321-327
Water pollution is a major environmental problem worldwide. In particular, shipyards are contaminating waters with iron, lead and copper filings, paints, petrochemical products and solvents. There are only a few reports on the genotoxicity of shipyard contaminants. Here, we study genotoxic effects of surface water from five sites of Hooghly River in West Bengal, India, along the banks of which many shipbuilding and scrap industries are located. Genotoxicity was measured by the detection of micronuclei in Allium cepa and other chromosomal aberrations, as well as damage to genomic DNA of calf thymus. Results show that A. cepa roots treated with contaminated water induced morphological distortions, formation of micronuclei and various types of chromosomal aberrations. The mitotic index was lower than 50 % in the treated samples. The breakage of calf thymus DNA was time-dependent with acute damage of 100 % for overnight incubation as evidenced by agarose gel electrophoresis. We conclude that the workers of local shipbuilding and scrap industries, the residents of nearby areas and the aquatic biodiversity are vulnerable to contaminated waters. 相似文献
287.
Vijaya Balaji Shiben Chandra Debnath Anjan Goswami Shyamal Kumar Das Tapan Kumar Mandal Animesh Kumar Chakraborty 《毒物与环境化学》2013,95(3):527-539
A study on the toxicokinetic behavior, metabolism of chlorpropham, and its effect on cytochrome P450 from liver microsomes was carried out in albino rats after a single and consecutive oral administration at 500?mg?kg?1 body weight for 10 and 20 days. Chlorpropham was detected in the blood at 0.08?h (11.43?±?1.72?µg?mL?1) reaching a maximum concentration at 2?h (30.90?±?2.55?µg?mL?1) and a minimum at 48?h (1.95?±?0.20?µg?mL?1) after a single oral administration of 500?mg?kg?1. The absorption rate constant (K a) was 0.66?±?0.48?h?1. The Vd area (18.01?±?2.78?L?kg?1) and t 1/2 β (12.23?±?1.96?h) values suggested a wide distribution and long persistence of the compound in the body, respectively. The higher ClR (0.82?±?0.00?L?kg?1?h?1) compared to ClH (0.18?±?0.02?L?kg?1?h?1) value indicated that a major portion of chlorpropham was excreted through the urine (30%) compared to the faeces (2.81%). Chlorpropham residue was detected in all tissues of rat at 0.25?h while its metabolite, meta-chloroaniline was detected in liver, kidney, heart, lung, and spleen tissue at 0.25?h. Meta-chloroaniline was not detected in skeletal muscle, brain, fat, and stomach tissue at any time of the observation period. Maximum concentrations of chlorpropham and meta-chloroaniline were detected at 2?h (except in the spleen), and minimum concentrations of chlorpropham at 24 (heart, lung, spleen, skeletal muscle, and stomach) and 48?h (liver, kidney, brain, and fat tissue) respectively; and meta-chloroaniline at 24?h (except heart and spleen). The tissue half-life of chlorpropham in rat varied from 3.80 to 11.60?h. Repeated oral administration of chlorpropham at 500?mg?kg?1 for 10 and 20 days caused an induction of the liver microsomal pellet of rat. 相似文献
288.
Dimethoate, a moderately toxic insecticide, has a wide range of agricultural and domestic applications. Like other organophosphates, dimethoate has anticholinesterase activity. Fish are non-target organisms, inadvertently exposed to pesticides and their metabolic products. The present study includes short-term (96 h) and long-term (36 d) effects of dimethoate exposure on some serum electrolytes Ca2+, Mg2+, and Pi in the freshwater air-breathing catfish Heteropneustes fossilis. The concentration of dimethoate for short-term exposure was 2.24 mg L?1 (75% of 96 h LC50) and for long-term exposure 0.75 mg L?1 (25% of 96 h LC50). The study includes the recovery pattern in serum electrolytes after placing the fish in pesticide-free water. Fish show hypocalcemia, hypermagnesemia, and hyperphosphatemia after short-term and long-term exposure to dimethoate. When placed in pesticide-free water, these electrolytes exhibit recovery towards normalization, indicating significant (p < 0.05) recovery. 相似文献
289.
The study deals with the toxicological impact of cadmium nanoparticles (Cd NPs) on Bacillus subtilis as a model Gram-positive bacterium. Cadmium oxide (CdO) NPs (~22 nm) and cadmium sulfide (CdS) NPs (~3 nm) were used in this study. Both the NPs were found to inhibit the cell viability of B. subtilis when added to the culture at mid-log phase, the viable cell number declined with increasing concentration of Cd NPs. At mid-log phase, 15 mg L?1 CdO NPs inhibited growth by ~50%, whereas at 30 mg L?1 growth completely ceased. Under the same conditions, CdS NPs inhibited growth by ~50% at a concentration of 8 mg L?1, and at 20 mg L?1 growth was completely retarded. The cells changed their morphological features to a filamentous form with increasing Cd NPs exposure time, leading to associated with clumping. NPs treated cells when stained with 4′, 6-diamino-2-phenylindole, showed filamentous multinucleated bead structure, suggesting irregularities in cell division. Increasing intracellular oxidative stress due to Cd NPs exposure might be one of the reasons for the cell morphological changes and toxicity in B. subtilis. 相似文献
290.
Manufacturing of manganese (Mn) compounds, their industrial applications as well as mining overburden, has generated a potential environmental pollutant. Occupational exposure to elevated levels of Mn occurs during mining, welding, smelting and other industrial anthropogenic sources. Chronic and acute exposure of this metal pollutant leads to adverse consequences and is clinically categorized by various symptoms of neurotoxicity including cognitive, psychiatric symptoms, Parkinson's disease, extra pyramidal signs, manganism, dystonia, and motor system dysfunction. The aim of this review is to summarize the possible mechanism underlying Mn compounds-mediated neurotoxicity leading to neurodegenerative diseases. Our review endeavours to examine recent advances in research on Mn-related environmental pollution, Mn-induced poisoning, molecular mechanisms underlying Mn-induced neurotoxicity with case studies as well as current approaches employed for treatment and prevention of Mn exposure. 相似文献