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41.
Sonia Rodrigues Graham Urquhart Iain Hossack Ma Eduarda Pereira Armando C. Duarte Christine Davidson Andrew Hursthouse Peter Tucker Douglas Roberston 《Environmental Chemistry Letters》2009,7(2):141-148
As part of a harmonised assessment of urban soils (), we investigated the variability of metal content in soils from Aveiro (Portugal) and Glasgow (UK). Samples were collected
from parks and other public open spaces in each city. Metal content (Al, Ca, Cr, Cu, Fe, Mn, Ni, Pb and Zn) and basic soil
parameters (texture, CEC, pH, organic matter) were determined and data investigated using principal component analysis (PCA).
The two cities differ in absolute levels of metal content reflecting industrial and historical development. Factors identified
by PCA included anthropogenic (Cu, Pb, Zn), soil properties and geology, which explain variability when data were assessed
based on metal content, soil properties and land use. This study highlights the contribution from geological background even
in strongly urbanised environments. 相似文献
42.
43.
Plant uptake of non-ionic organic chemicals from soils 总被引:15,自引:0,他引:15
Methodologies utilizing simple properties of chemicals - half-life (T1/2), log octanol-water partition coefficient (log Kow) and Henery's Law constant (Hc) - are developed to screen organic chemicals for potential plant uptake. 相似文献
44.
Baseline resource information in an easily accessible form is a vital starting point for developing coastal zone management.
On behalf of a wide-ranging group of organizations involved in the management of the U.K. maritime zone, the Joint Nature
Conservation Committee (JNCC) is compiling a series of 16 regional volumes. The volumes contain multidisciplinary coastal
zone resource information arranged in ten chapters under the general title ‘Coasts and Seas of the UK’. These volumes form
part of a series of paper and electronic publications of coastal information being produced by JNCC's Coastal Directories
Project and are designed to meet the needs of planners and all others involved in decision-making and management of the coast. 相似文献
45.
Cliff I. Davidson Suresh Santhanam Joseph R. Stetter Richard D. Flotard Elizabeth Gebert 《Environmental monitoring and assessment》1982,1(4):313-335
Airborne particles in fugitive emissions have been measured at a slagging fixed-bed coal-gasification pilot plant using lignite. Sampling was conducted during shutdown operations and opening of the gasifier following an aborted startup. Aerosol collected with a Sierra high-volume impactor was subjected to analysis by gas chromatography, mass spectrometry, and scanning electron microscopy; aerosol collected with an Andersen low-volume impactor was subjected to flameless atomic absorption analysis. The data show that the bulk of the trace organic material is associated with small particles: these data are similar to data on ambient air reported in the literature. Particle morphologies resemble those of fly ash from coal combustion, including smooth spheres, vesicular spheres, and crystalline material. Trace element size distributions are bimodal and resemble data for ambient air. Pb-containing particles are generally submicron, while particles containing Al, Fe, and other crustal species are mostly of supermicron size. Aluminum-based aerosol enrichment factors calculated from the lignite composition show that the composition of the aerosol resembles that of the coal, with the exception of modest enrichments of Mg, Na, As, and Pb in the submicron size range. Aerosol enrichment factors based on the earth's crustal composition are somewhat greater than those based on coal composition for several elements, suggesting potential errors in using crustal enrichment data to investigate chemical fractionation during aerosol formation. 相似文献
46.
Aqueous Hibiscus sabdariffa extracts possess antimicrobial properties with limited information available on their antiviral effects. Aichi virus (AiV) is an emerging foodborne pathogen that causes gastroenteritis. Vaccines are currently unavailable to prevent their disease transmission. The objective of this study was to determine the antiviral effects of aqueous H. sabdariffa extracts against AiV. AiV at ~5 log PFU/ml was incubated with undiluted (200 mg/ml), 1:1 (100 mg/ml) or 1:5 (40 mg/ml) diluted aqueous hibiscus extract (pH 3.6), phosphate-buffered saline (pH 7.2 as control), or malic acid (pH 3.0, acid control) at 37 °C over 24 h. Treatments were stopped by serially diluting in cell-culture media containing fetal bovine serum and titers were determined using plaque assays on confluent Vero cells. Each treatment was replicated thrice and assayed in duplicate. AiV did not show any significant reduction with 1:1 (100 mg/ml) or 1:5 (40 mg/ml) diluted aqueous hibiscus extracts or malic acid after 0.5, 1, or 2 h at 37 °C. However, AiV titers were reduced to non-detectable levels after 24 h with all the three tested concentrations, while malic acid showed only 0.93 log PFU/ml reduction after 24 h. AiV was reduced by 0.5 and 0.9 log PFU/ml with undiluted extracts (200 mg/ml) after 2 and 6 h, respectively. AiV treated with 1:1 (100 mg/ml) and 1:5 (40 mg/ml) diluted extracts showed a minimal ~0.3 log PFU/ml reduction after 6 h. These extracts show promise to reduce AiV titers mainly through alteration of virus structure, though higher concentrations may have improved effects. 相似文献
47.
Julien Sialelli Christine M. Davidson Andrew S. Hursthouse Franco Ajmone-Marsan 《Environmental Chemistry Letters》2011,9(2):197-202
Several physiologically based extraction procedures have been proposed to estimate the fraction of the potentially toxic element
content that would be bioaccessible in the human gastro-intestinal tract following accidental ingestion of soil. Many of these
procedures are complex, they have been applied to a very limited range of soils, and most work has focussed on arsenic and
lead. In the present study, a simplified, two-stage extraction, simulating the human stomach and intestine, was developed
and applied to urban soil samples from ten public-access areas in the City of Torino, Italy. The human oral bioaccessibility
of chromium, copper, nickel, lead and zinc was estimated. Lead and zinc bioaccessibilities were found to be higher in the
stomach, but chromium was more bioaccessible in the intestine. Analyte concentrations were higher in roadside soils than in
soils from parks. A higher proportion of the soil metal content was found in bioaccessible forms at roadsides than in parks.
Comparison of the current findings with results of earlier work involving sequential extraction of the same soils indicated
that the sequential procedure gave a relative, but not an absolute, indication of bioaccessibility. Calculations based on
the bioaccessible analyte concentrations suggest that ingestion of only 2–3 g of some of the roadside soil samples from Torino
could deliver the tolerable daily oral intake of chromium, nickel and lead to a 20-kg child. The developed procedure is useful
for preliminary screening of soils and prediction of whether their bioaccessible metal contents are likely to pose a risk
to human health. 相似文献
48.
49.
Meharg AA Deacon C Edwards KJ Donaldson M Davidson DA Spring C Scrimgeour CM Feldmann J Rabb A 《Chemosphere》2006,64(11):1818-1828
The impact of ancient fertilization practices on the biogeochemistry of arable soils on the remote Scottish island of Hirta, St Kilda was investigated. The island was relatively unusual in that the inhabitants exploited seabird colonies for food, enabling high population densities to be sustained on a limited, and naturally poor, soil resource. A few other Scottish islands, the Faeroes and some Icelandic Islands, had similar cultural dependence on seabirds. Fertilization with human and animal waste streams (mainly peat ash and bird carcases) on Hirta over millennia has led to over-deepened, nutrient-rich soils (plaggen). This project set out to examine if this high rate of fertilization had adversely impacted the soil, and if so, to determine which waste streams were responsible. Arable soils were considerably elevated in Pb and Zn compared to non-arable soils. Using Pb isotope signatures and analysis of the waste streams, it was determined that this pollution came from peat and turf ash (Pb and Zn) and from bird carcases (Zn). This was also confirmed by 13C and 15N analysis of the profiles which showed that soil organic matter was highly enriched in marine-derived C and N compared to non-arable soils. The pollution of such a remote island may be typical of other ‘bird culture’ islands, and peat ash contamination of marginal arable soils at high latitudes may be widespread in terms of geographical area, but less intense at specific locations due to lower population densities than on Hirta. 相似文献
50.
Thomas A. Davidson Sebastian Wetterich Kasper L. Johansen Bjarne Grønnow Torben Windirsch Erik Jeppesen Jari Syväranta Jesper Olsen Ivan González-Bergonzoni Astrid Strunk Nicolaj K. Larsen Hanno Meyer Jens Søndergaard Rune Dietz Igor Eulears Anders Mosbech 《Ambio》2018,47(2):175-192
The North Water (NOW) polynya is one of the most productive marine areas of the Arctic and an important breeding area for millions of seabirds. There is, however, little information on the dynamics of the polynya or the bird populations over the long term. Here, we used sediment archives from a lake and peat deposits along the Greenland coast of the NOW polynya to track long-term patterns in the dynamics of the seabird populations. Radiocarbon dates show that the thick-billed murre (Uria lomvia) and the common eider (Somateria mollissima) have been present for at least 5500 cal. years. The first recorded arrival of the little auk (Alle alle) was around 4400 cal. years bp at Annikitsoq, with arrival at Qeqertaq (Salve Ø) colony dated to 3600 cal. years bp. Concentrations of cadmium and phosphorus (both abundant in little auk guano) in the lake and peat cores suggest that there was a period of large variation in bird numbers between 2500 and 1500 cal. years bp. The little auk arrival times show a strong accord with past periods of colder climate and with some aspects of human settlement in the area. 相似文献