全文获取类型
收费全文 | 498篇 |
免费 | 16篇 |
国内免费 | 95篇 |
专业分类
安全科学 | 28篇 |
废物处理 | 33篇 |
环保管理 | 49篇 |
综合类 | 141篇 |
基础理论 | 83篇 |
污染及防治 | 215篇 |
评价与监测 | 29篇 |
社会与环境 | 23篇 |
灾害及防治 | 8篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 21篇 |
2021年 | 17篇 |
2020年 | 17篇 |
2019年 | 7篇 |
2018年 | 10篇 |
2017年 | 9篇 |
2016年 | 13篇 |
2015年 | 12篇 |
2014年 | 27篇 |
2013年 | 59篇 |
2012年 | 38篇 |
2011年 | 42篇 |
2010年 | 17篇 |
2009年 | 25篇 |
2008年 | 25篇 |
2007年 | 51篇 |
2006年 | 22篇 |
2005年 | 20篇 |
2004年 | 16篇 |
2003年 | 34篇 |
2002年 | 14篇 |
2001年 | 19篇 |
2000年 | 12篇 |
1999年 | 5篇 |
1998年 | 5篇 |
1997年 | 6篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 1篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 5篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有609条查询结果,搜索用时 343 毫秒
131.
Wei Zhang Huaqiang Chu Libin Yang Xiaogang You Zhenjiang Yu Yalei Zhang Xuefei Zhou 《Frontiers of Environmental Science & Engineering》2023,17(7):83
132.
Environmental Chemistry Letters - Heavy metals are a common class of toxic contaminants in soil, water and air, yet their occurrence in indoor environments is less known. Heavy metals enter... 相似文献
133.
Changes in biomass activity and characteristics of activated sludge exposed to low ozone dose 总被引:1,自引:0,他引:1
Libing Chu Jianlong Wang Bo Wang Xin-Hui Xing Sangtian Yan Xulin Sun Benjamin Jurcik 《Chemosphere》2009,77(2):269-272
In this paper, the response mechanism of activated sludge exposed to low-dose ozone at less than 20 mg O3 g−1 total suspended solids (TSS) was studied by analyzing the changes in sludge activity and the evolution of C, N, P and metals from sludge following ozonation. The intracellular ATP concentration was not affected at less than 5 mg O3 g−1 TSS and thereafter decreased rapidly to around 60% when the ozone dose increased to 20 mg O3 g−1 TSS. Similarly, the efficiency of sludge solubilization initially changed a little and then increased rapidly to around 30% at an ozone dose of 20 mg O3 g−1 TSS. However, the activities of superoxide dismutase and protease decreased immediately upon exposure to ozone. These findings indicate that ozone firstly destroys the floc, leading to the disruption of the compact aggregates, which does not affect cells viability but induces a decrease in enzyme activities. Ozone then attacks the bacterial cells of the sludge, causing a decrease in cells viability. During ozonation, the content of carbon, nitrogen and phosphorus in the sludge matrix decreased, while the content of these elements in the micro-solids and supernatant gradually increased. Most of the released metals from the sludge matrix were found in the micro-solids. 相似文献
134.
The partitioning and modelling of pesticide parathion in a surfactant-assisted soil-washing system 总被引:1,自引:0,他引:1
Soil sorption of organic pollutants has long been a problematic in the soil washing process because of its durability and low water solubility. This paper discussed the soil washing phenomena over a wide range of parathion concentrations and several soil samples at various fractions of organic content (foc) levels. When parathion dosage is set below the water solubility, washing performance is stable for surfactant concentrations above critical micelle concentration (cmc) and it is observed that more than 90% of parathion can be washed out when dosage is five times lower than the solubility limit. However, such trends change when non-aqueous phase liquids (NAPL) is present in the system. Parathion extraction depends very much on the surfactant dosage but is not affected by the levels of foc in the system. In between the extreme parathion dosage, a two-stage pattern is observed in these boundary regions. Washing performance is first increased with additional surfactant, but the increase slows down gradually since the sorption sites are believed to be saturated by the huge amount of surfactant in the system. A mathematical model has included foc to demonstrate such behavior and this can be used as a prediction for extraction. 相似文献
135.
As marine disposal of sewage sludge and dredged sediments may impose serious adverse effects to marine ecosystems, landfilling seems to be the most feasible method for the final disposal of these wastes. A batch experiment was conducted to study waste degradation and gas production after sewage sludge and marine dredgings were mixed with municipal refuse at 13 different ratios for 36 days. The addition of sludge and dredgings to municipal refuse enhanced gas production, compared with the degradation of refuse or sludge alone. A proper mixing ratio of wastes can also shorten the time to reach the final phase of anaerobiosis. The highest gas production was obtained from the ratio of 75-20-5 (refuse-sludge-dredgings) (wet weight basis). Its average daily gas production rate was 1.42 l kg(-1) waste mixture; methane content was 68.3%. The results indicated that codisposal of the three wastes would be beneficial for energy recovery from landfill gas. 相似文献
136.
J. Ernest Flaek Duane W. Hill 《Journal of the American Water Resources Association》1970,6(4):563-572
Water resources management in the urban areas of the United States to be effective must include dimensions far beyond water supply and sewerage. This paper concerns itself with those problem areas of water resource management outside of potable water supply and sanitary sewers. These areas include flood plain management, greenways and blueways, storm water, vistas of waterways, and other attributes of living in or near a water-related environment. The perceptions and attitudes of the concerned public and community power structure must be known in order to manage the water environment effectively. Methods of measuring these perceptions and attitudes are described and ways in which the resulting citizen-resource can be tapped and used as a management device are explored. 相似文献
137.
ABSTRACT: The Yellowstone River historically has produced an ample supply of high quality water which is widely used for irrigation, municipal and industrial purposes, recreation, and fish and wildlife. Recently, energy companies have attempted to obtain water rights in the Yellowstone basin for energy conversion facilities in coal-rich southeastern Montana. Existing users fear that energy diversions will impair their rights, preclude expansion of present beneficial users, degrade water quality, and adversely effect fish and aquatic life. In response to these concerns, the Montana Legislature enacted several laws to regulate water appropriations in the Yellowstone River basin, including means by which state and federal agencies could apply for reservations of water for future beneficial uses. Thereafter, both the Montana Fish and Game Commission and the State Water Quality Bureau formally requested relatively large instream flows to protect fish and wildlife and to maintain water quality. This paper describes Montana's experience through December of 1977 with the administration of water in the Yellowstone basin under these laws; emphasis is placed on the major requests for instream flows. The final resolution of the reservation applications, and the related ramifications, will be discussed in a future paper. 相似文献
138.
Viruses from contaminant sources can be transported through porous media to drinking water wells. The objective of this study was to investigate inactivation and sorption of viruses during saturated and unsaturated transport in different soils. Bacteriophages phiX174 and MS-2, and Br- tracer in a phosphate-buffered saline solution were introduced into saturated and unsaturated soil columns as a step function under constant flow rate and hydraulic conditions. Results showed that significantly greater virus removal occurred in the unsaturated columns than in the saturated columns in the two soils containing high metal oxides content. However, the increase in virus retention under unsaturated conditions was not significant in two other soils having high phosphorus and calcium contents and high pH, and in another soil with high organic matter content. The results imply that the extent of water content effect on inactivation and sorption of viruses can range from significant to minimal depending on the properties of the transport medium. We found that the presence of in situ metal oxides was a significant factor responsible for virus sorption and inactivation. Therefore, soils with high metal oxides content may have the potential to be used as hydrological barriers in preventing microbial contamination in the subsurface environments. We also found that the water content effect on virus removal and inactivation strongly depended on solid properties of the testing medium. 相似文献
139.
Chlorinated phenols are major industrial and agricultural xenobiotics that pollute soil and ground water. It has been shown that laccases catalyze the oxidative coupling of phenolic compounds. Therefore, the transformation of one or a mixture of several chlorinated phenols by a laccase from the fungus Trametes villosa was studied. Generally, if more than one phenol was added, the transformation of chlorinated phenols decreased, and if the concentration of the laccase was increased, the transformation of the phenols was enhanced. There were exceptions to these observations: for instance, the transformation of 0.1 mM 4-chlorophenol incubated with 1 mM 2,4-dichlorophenol in buffered salt solutions was not enhanced if the concentration of the laccase was increased from 2 to 20 DMP units/mL. The reason for the reduced transformation of chlorinated phenols in the presence of additional phenols is still unknown. However, in spite of some limitations, the application of laccase to decontaminate wastewater polluted with chlorinated phenols appears feasible. 相似文献
140.
Recent studies have shown that dechlorinating bacteria can accelerate the dissolution rate of dense, nonaqueous phase liquids (DNAPLs) containing tetrachloroethene (PCE). We present an advection-dispersion-reaction model for a two-dimensional domain, with groundwater flowing over a pool of free-product PCE. PCE is converted to cis-1,2-dichloroethene (cDCE) and toxicity due to PCE or cDCE is neglected. We adopt previously published correlations relating biomass concentrations and hydraulic conductivity, accounting for biofilm growth and plug-like growth. The system of coupled equations is solved numerically. The high biotransformation rate of PCE increases the concentration gradient of PCE at the water-DNAPL interface, enhancing dissolution. The higher the electron donor (ED) concentration, the larger the dissolution enhancement. Based on the values of maximum specific rate we used, when the electron donor is unlimited, the active biomass accumulates adjacent to the water-NAPL interface and microbial reactions can significantly enhance the pool dissolution. The resulting steady-state dissolution rate can be approximated by a half-order solution when zero-order kinetics are suitable for representing the microbial reaction. However, bioclogging may significantly reduce local hydraulic conductivity; thus, it decreases the flow near the water-DNAPL interface, decreasing dissolution. When the ED is the limiting factor, active biomass accumulates away from the interface. This creates a no-flow zone between the active biomass and the interface. The enlargement of the no-flow zone, due to the donor limitation, diminishes the concentration gradient and the flushing around the water-DNAPL interface. Such adverse impacts may significantly decrease the enhancement predicted by models that do not consider the effects of bioclogging. 相似文献