Sorption and desorption hysteresis of organic contaminants by kerogen in a sandy aquifer material

Sorption and desorption hysteresis of 1,2-dichlorobenzene, 1,3,5-trichlorobenzene, naphthalene, and phenanthrene were investigated for the Borden aquifer material with total organic carbon of 0.021% and the isolated natural organic matter (NOM). The isolated NOM is a kerogen type of organic matter with relatively low maturation degree and contained many different types of organic matters including vitrinite particles. The modified Freundlich sorption capacities (logK^′_f and logK^′_foc) are very close for the sorption of the four solutes by the isolated NOM and the original sand, respectively. Isotherm non-linearity (n value) and hysteric behaviors are related to solute molecular properties (e.g. K_ow and molecular size). Kerogen encapsulated by inorganic matrices in the original aquifer may not be accessed fully by solutes. The larger the hydrophobic organic chemical (HOC) (hydrophobic organic contaminant) molecule is, the lower accessibility of the HOC to kerogen. This study disputes widely held hypothesis that sorption to mineral surfaces may play a major role in the overall sorption by low TOC (e.g. 0.1% by mass) geomaterials such as Borden sand. It also demonstrates the importance of the condensed NOM domain, even at very low contents, in the sorption and desorption hysteresis of HOCs in groundwater systems.     

隆回县高海拔山区高效生态经济型退耕还林造林模式研究

通过对六种植物配置方式及三种开发模式的对比试验分析，试验出了一种融水土保持效益与经济效益于一体的高效生态经济型造林模式，并探讨了灰毡毛忍冬产量与海拔高度的关系．结果表明：在自然条件恶劣的小沙江高海拔山区，采用金银花(品种为灰毡毛忍冬) 三木药材或其它草本药材，运用景观生态学原理进行设计开发，可获得很好的经济效益与社会效益，并能保持山区的可持续发展．同时还试验出了主栽树种灰毡毛忍冬在海拔1000～1400m之间时经济效益最好．     

芹菜赖氨酸加苏氨酸抗性细胞系的选择

用４ｍｍｏｌ－／Ｌ浓度的赖氨酸加苏氨酸作为选择压，经相同浓度液体和固体选择培养基连续选择，从未经诱变处理的芹菜胚性愈伤组织筛选出一个稳定的赖氨酸加苏氨酸抗性细胞系并得到再生植株。抗性细胞系再生植株整株的氨基酸含量比对照组植株高１０倍左右。但是地上部分氨基酸含量，抗性细胞系再生植株比对照植株有所降低。两种植株叶片的细胞色素氧化酶同工酶谱有明显差异，抗性细胞系再生植株有４条谱带，而对照植株只有两条谱带     

昆明地区酸雨时空分布及其成因初探

对1995－1999年昆明地区降雨监测资料的分析，昆明地区酸雨主要为局 地污染引起的硫酸型酸雨，酸雨污染近五年呈明显上升趋势，在空间分布上，城区酸雨频率和强度均明显强于效县。     

河西走廊水资源供需平衡及其对农业发展的承载潜力

河西走廊是甘肃省主要经济地区之一,河西走廊未来的经济发展规模在很大程度上取决于本地区水资源的承载能力。本文在水量平衡原理的基础上,对河西走廊水资源的供需平衡和水土资源平衡状况以及水资源对农业发展的承载潜力进行了分析计算,并建立了相应的数学模型,指出了河西走廊水资源的潜力巨大,只有在发展节水型农业和水资源合理、高效利用的条件下才能提高农业用水的承载潜力。     

Mechanism studies on nitrogen removal when treating ammonium-rich leachate by sequencing batch biofilm reactor

The nitrogen removal mechanism was studied and analyzed when treating the ammonium-rich landfill leachate by a set of sequencing batch biofilm reactors (SBBRs), which was designed independently. At the liquid temperature of (32 ± 0.4)°C, and after a 58-days domestication period and a 33-days stabilization period, the efficiency of ammonium removal in the SBBR went up to 95%. Highly frequent intermittent aeration suppressed the activity of nitratebacteria, and also eliminated the influence on the activity of anaerobic ammonium oxidation (ANAMMOX) bacteria and nitritebacteria. This influence was caused by the accumulation of nitrous acid and the undulation of pH. During the aeration stage, the concentration of dissolved oxygen was controlled at 1.2–1.4 mg/L. The nitritebacteria became dominant and nitrite accumulated gradually. During the anoxic stage, along with the concentration debasement of the dissolved oxygen, ANAMMOX bacteria became dominant; then, the nitrite that was accumulated in the aeration stage was wiped off with ammonium simultaneously. Translated from Acta Scientiae Circumstantiae, 2006, 26(1): 55–60 [译自: 环境科学学报]     

从“治”到“化”的规模化养殖场废物处理的循环经济模式

首先讨论了“治”字思维模式下,我国禽畜养殖业规模化养殖场存在污染物既不经济又不环保的严峻现实问题。事实上,规模化禽畜养殖场产生的“废物”,既是严重的污染源,又是一种必须利用的资源。因此,针对规模化养殖场的污染物“治”字思维问题,在立足于粪便及污水的综合利用100%“资源化”的“化”字思维指导下,遵循循环经济原则,建立无废无污开放式闭合循环的生态经济新模式。一方面,养殖业所有流程按循环利用原则,实行生态工艺或无废工艺的改造;另一方面,在一个大的区域里把畜禽养殖业与其它产业,特别是大农业中的种植业以生态经济循环链锁关系配置成首尾相接的“废料—原料”的循环经济新模式,在达到边际成本最低的同时取得边际效益的最大化。     

昆明市“十五”期间环境空气质量变化趋势分析与对策

根据昆明市“十五”期间环境空气质量监测结果，分析了主要特征污染物变化趋势。“十五”期间降尘、PM10是市区主要污染物，SO2、NO2亦呈上升趋势，市区空气污染特征属于典型的煤烟型污染。对此。提出了改善空气质量的防治对策与建议。     

污泥分解技术在污泥厌氧消化上的应用

污泥分解技术与厌氧消化相结合，能提高厌氧消化的效率，其中在污泥厌氧消化工艺中适当的结合臭氧氧化技术，可以使挥发性固体平均降解率提高至65％，并减少1／3的厌氧消化池容积。     

石煤渣保温材料的配方研究

以石煤渣为主要原料研制应用于工业窑炉的保温材料，具有较高的耐压强度和使用温度，导热率低。本文通过分析各原料的主要作用，研究了不同原料掺量对材料性能的影响，从而得到了石煤渣保温材料合理的配方范围为：石煤渣４０％～６０％、可燃造孔物３０％～４０％、粘结剂１２％～２０％、外加剂０．１０％～０．２０％。