全文获取类型
收费全文 | 2090篇 |
免费 | 509篇 |
国内免费 | 177篇 |
专业分类
安全科学 | 146篇 |
废物处理 | 103篇 |
环保管理 | 148篇 |
综合类 | 1095篇 |
基础理论 | 364篇 |
污染及防治 | 606篇 |
评价与监测 | 79篇 |
社会与环境 | 108篇 |
灾害及防治 | 127篇 |
出版年
2024年 | 17篇 |
2023年 | 47篇 |
2022年 | 98篇 |
2021年 | 77篇 |
2020年 | 76篇 |
2019年 | 70篇 |
2018年 | 83篇 |
2017年 | 98篇 |
2016年 | 108篇 |
2015年 | 129篇 |
2014年 | 146篇 |
2013年 | 181篇 |
2012年 | 115篇 |
2011年 | 140篇 |
2010年 | 109篇 |
2009年 | 101篇 |
2008年 | 124篇 |
2007年 | 130篇 |
2006年 | 85篇 |
2005年 | 87篇 |
2004年 | 67篇 |
2003年 | 103篇 |
2002年 | 102篇 |
2001年 | 80篇 |
2000年 | 83篇 |
1999年 | 58篇 |
1998年 | 46篇 |
1997年 | 59篇 |
1996年 | 31篇 |
1995年 | 29篇 |
1994年 | 28篇 |
1993年 | 21篇 |
1992年 | 16篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有2776条查询结果,搜索用时 0 毫秒
131.
陶瓷微滤膜过滤黑液的清洗与再生 总被引:4,自引:0,他引:4
对无机陶瓷微滤膜过滤草桨黑液的膜清洗及再生的方法进行了研究。考察了物理和化学方法的再生效果、单种清洗剂的清洗效果、复合方法的清洗效果和效果的可重复性。结果表明物理冲洗、高温灼烧、单一的化学清洗剂清洗均可以提高陶瓷膜的再生通量;但是复合方法对陶瓷微滤膜的再生效果较好,其中按氢氧化钠溶液清洗、硝酸溶液清洗、次氯酸钠溶液清洗的实验步骤,膜的再生渗透通量高.且重复性强,可望在工业生产的在线清洗中应用。 相似文献
132.
Zhanguo Liang Jun Mu Ying Mu Jiaming Shi Wenjing Hao Xuewei Dong Hongquan Yu 《环境科学学报(英文版)》2013,(S1):S106-S109
We have created a new method of ZnS nanospheres synthesis. By interface-mediated precipitation method (IMPM), monodisperse ZnS nanoparticles was synthesized on the particle surface of sulfate-reducing bacterium nutritious agar culture. Sulfate-reducing bacterium (SRB) was used as a sulfide producer because of its dissimilatory sulfate reduction capability, meanwhile produced a variety of amino acids acting as templates for nanomaterials synthesis. Then zinc acetate was dispersed into nutritious agar plate. Subsequently agar plate was broken into particles bearing much external surface, which successfully mediated the synthesis of monodisperse ZnS nanoparticles. The morphology of monodisperse ZnS nanospheres and SRB were examined by scanning electron microscopy (SEM), and the microstructure was investigated by X-ray diffraction (XRD). The thermostability of ZnS nanoparticles was determined by thermo gravimetric-differential thermo gravimetric (TG-DTG). The maximum absorption wavelengh was analysed with an ultravioletvisible spectrophotometer within a range of 199-700 nm. As a result, monodisperse ZnS nanoparticles were successfully synthesized, with an average diameter of 80 nm. Maximum absorption wavelengh was 228 nm, and heat decomposed temperature of monodisperse ZnS nanoparticles was 596℃. 相似文献
133.
Shaobin Lin Shanshan Shi Yi Zhou Yuanjun Ji Peizhi Huang Jianzhu Wu Baojiang Chen Yanmin Luo 《黑龙江环境通报》2018,38(6):381-389
134.
印刷线路板厂含铜污泥固化处理工艺研究 总被引:10,自引:0,他引:10
研究采用水泥作固化基材固化处理某印刷线路板厂酸性废水用石灰混凝所产生的含铜、锡、金的污泥 ,对固化块在不同 pH的水中重金属Cu2 +的浸出实验结果表明 :水泥固化处理该混凝污泥效果良好 ,控制合适的条件 ,可得到混合性能好、初凝时间适当、抗压强度较好的固化块。Cu2 +的浸出率低于允许浸出浓度。混凝过程中加入硫脲硅酸钠等助剂 ,可提高固化效果。研究还对几种不同配比的固化块抗压强度进行了探讨。 相似文献
135.
Weiwei Shi Thomas W. van der Sloot Brandon J. Hart Brook S. Kennedy Jonathan B. Boreyko 《Advanced Sustainable Systems》2020,4(6)
Fog harvesting is useful for passively collecting fresh water in arid regions, but the efficiency of current mesh‐based harvesters is compromised by their poor drainage. Inspired by the linear needles of redwood trees, “fog harps” are developed whose array of vertical wires enables an unobstructed drainage pathway. A full‐scale (1 m2 frame) fog harp is fabricated by winding a stainless steel wire around a spinning aluminum frame featuring threaded rods. The fog harp is field tested for a full year at a local farm (Blacksburg, VA, USA), alongside the control case of a mesh harvester. Under moderate fog conditions, the fog harp collects anywhere from 2 to 78 times more water compared to the mesh harvesters. Under light fog conditions, the fog harp collects up to several hundred milliliters of water per day while the mesh is unable to collect any water at all. The water harvesting performance of fog harps is therefore unprecedented in two ways: they substantively elevate the performance ceiling when exposed to healthy fog while also enabling, for the first time, appreciable water harvesting under light fog. 相似文献
136.
本文目的是研究对羟基苯甲酸丙酯(羟苯丙酯;propylparaben,PP)和对羟基苯甲酸丁酯(羟苯丁酯;butylparaben,BP)对大鼠肝微粒体(rat liver microsomes,RLM)和人肝微粒体(human liver microsomes,HLM)细胞色素P450酶(cytochrome P450 enzyme,CYP)活性的抑制作用,并评价它们的相互作用潜能。在体外将系列浓度的羟苯丙酯和羟苯丁酯与大鼠和人肝微粒体孵育60 min,以非那西丁、安非他酮、甲苯磺丁脲、氯唑沙宗、香豆素、右美沙芬和咪达唑仑为CYP探针底物,应用质谱定量检测各探针底物的代谢产物生成量,计算得到IC50和Ki值,评价2种化学受试物对大鼠和人肝微粒体CYP450酶的抑制活性和抑制类型,并对抑制强度进行分级。大鼠和人肝微粒体中羟苯丙酯是CYP1A2酶的中等强度抑制剂,羟苯丁酯在大鼠肝微粒体中是CYP1A2酶的弱抑制剂,在人肝微粒体中是CYP1A2酶的中等强度抑制剂,观察到对其他CYP450酶无抑制作用,这与用软件预测的羟苯丙酯和羟苯丁酯对CYP450酶的抑制种类结果一致,分子对接的结果也印证了羟苯丙酯和羟苯丁酯对CYP1A2酶活性的抑制作用,按照构效关系和同源CYP的物种敏感度预测模型,本文关于CYP的研究结果可以类推到其他哺乳动物和人类。 相似文献
137.
138.
139.
Diversity of Soil Nematodes in Areas Polluted with Heavy Metals and Polycyclic Aromatic Hydrocarbons (PAHs) in Lanzhou,China 总被引:1,自引:0,他引:1
This study investigated the soil nematode community structure along the Yellow River in the Lanzhou area of China, and analyzed
the impact of heavy metals (Cd, Pb, Cr, Cu, and Zn) and polycyclic aromatic hydrocarbons (PAHs) on the nematode community.
Soil samples from five locations (named A–E), which were chosen for soil analysis, showed significant differences in their
heavy metal content (p < 0.01), as well as in the variety of nematodes (up to 41 genera) and families (up to 20) that were present. The different
samples also differed significantly in the total PAH content (p < 0.05), as well as the six types of PAH present. Sites A–C showed the most severe contamination with heavy metals and PAHs;
these sites had the lowest abundance of fungivores and omnivore/predators, but the proportion of bacteriovores was the highest
(p < 0.05). Site E, in contrast, showed only minor pollution with heavy metals and PAHs, and it contained the highest abundance
of plant parasites (p < 0.05). Several nematode ecological indicators were found to correlate with concentration of soil pollutants at all the
sites tested: the maturity index (MI, in addition to plant parasites), plant parasite index (PPI), ΣMI (including all the
soil nematodes), Shannon-Wiener diversity index (H′′), and Wasilewska index (WI). Disturbance to the soil environment was more severe when MI, ΣMI, and H′ values were lower. The results of the study show that the abundance and structure of the soil nematode communities in the
sampling locations were strongly influenced by levels of heavy metals and PAHs in the soil. They also show that the diversity
index H′ and the maturity index can be valuable tools for assessing the impact of pollutants on nematodes. 相似文献
140.
Fe3O4-CoO/Al2O3 catalyst was prepared by incipient wetness impregnation using Fe(NO3) 3·9H2O and Co(NO3) 2·6H2O as the precursors,and its catalytic performance was investigated in ozonation of 2-(2,4-dichlorophenoxy) propionic acid(2,4-DP) ,nitrobenzene and oxalic acid.The experimental results indicated that Fe3O4-CoO/Al2O3 catalyst enabled an interesting improvement of ozonation eciency during the degradation of each organic pollutant,and the Fe3O4-CoO/Al2O3 catalytic ozonation system followed a radical-type mechanism.The kinetics of ozonation alone and Fe3O4-CoO/Al2O3 catalytic ozonation of three organic pollutants in aqueous solution were discussed under the mere consideration of direct ozone reaction and OH radical reaction to well investigate its performance.In the catalytic ozonation of 2,4-DP,the apparent reaction rate constants(k) were determined to be 1.456×10-2 min-1 for ozonation alone and 4.740×10-2 min-1 for O3/Fe3O4-CoO/Al2O3.And O3/Fe3O4-CoO/Al2O3 had a larger Rct(6.614×10-9) calculated by the relative method than O3 did(1.800×10-9) ,showing O3/Fe3O4-CoO/Al2O3 generated more hydroxyl radical.Similar results were also obtained in the catalytic ozonation of nitrobenzene and oxalic acid.The above results demonstrated that the catalytic performance of Fe3O4-CoO/Al2O3 in ozonation of studied organic substance was universal to a certain degree. 相似文献