Natural resource management in national parks: a management assessment of a Natura 2000 wetlands site in Kotychi-Strofylia,southern Greece

In Europe, the establishment of the Natura 2000 network is one of the main actions that has been undertaken to contribute to the maintenance of biodiversity. However, the management system of sites included in the network is under question. The aim of this study was to assess the natural resource management applied to the National Park of the wetlands Kotychi-Strofylia, southern Greece, an important site belonging to the European ecological network Natura 2000, and the Ramsar convention. The methodological approach applied follows the general framework of International Unit for Nature Conservation/World Committee for Protected Areas (IUCN/WCPA) for the evaluation of protected areas, and it was based on field monitoring data with a view of providing information in achieving the stated management objectives. Two levels of indicators were used: the first concerned the evaluation of the management process and the second the evaluation of the management outputs and outcomes. The assessment of the natural resources management in the National Park showed that the management of the area is oriented towards biodiversity conservation and lies within the scope of the habitat directive and the ecological network Natura 2000. The framework applied and the methodological approach followed in this study appear to provide a useful basis for designing and conducting management evaluation. The indicators used at local scale can be integrated at regional- and national-scale projects of management evaluation, and, at the same time, the evaluation results can help local managers to improve management by taking the appropriate management measures. The analytical hierarchical conceptual flow suggested seems to be considered as an essential tool for evaluating natural resource management.     

Photo-Induced OH reactions of naphthalene and its oxidation products on SiO2

The photo-induced degradation of naphthalene, 1,4-naphthoquinone, 1-naphthol and 1-NO₂ naphthalene, adsorbed on silica gel, and with the addition of nitrogenous air pollutants e.g. NO₂ (as KNO₂) was investigated. Results indicate that compounds adsorbed onto a solid carrier are degraded when irradiated with UV light (λ > 290 nm) in the presence of nitrites. The key species initiating the naphthalene degradation is the OH-radical which is generated through the photolysis of NO₂. Reaction products identified were 2-formyl-cinnamaldehyde, 1,4-naphthoquinone, nitronaphthol, o-phthaldialdehyde, phthalide and nitronaphthalene. A mass balance between 40–50% was achieved. Under the same irradiation conditions, 1-NO₂ naphthalene is mainly degraded by direct photolysis while degradation of 1-naphthol and 1,4-naphthoquinone proceeds via the reaction with OH-radicals. Identified products were hydroxy-nitro-nitroso- and quinones compounds.     

Natural desulfurization in coal-fired units using Greek lignite

This paper analyzes the natural desulfurization process taking place in coal-fired units using Greek lignite. The dry scrubbing capability of Greek lignite appears to be extremely high under special conditions, which can make it possible for the units to operate within the legislative limits of sulfur dioxide (SO2) emissions. According to this study on several lignite-fired power stations in northern Greece, it was found that sulfur oxide emissions depend on coal rank, sulfur content, and calorific value. On the other hand, SO2 emission is inversely proportional to the parameter gammaCO2(max), which is equal to the maximum carbon dioxide (CO2) content by volume of dry flue gas under stoichiometric combustion. The desulfurization efficiency is positively correlated to the molar ratio of decomposed calcium carbonate to sulfur and negatively correlated to the free calcium oxide content of fly ash.     

Transport impacts on atmosphere and climate: Land transport

Emissions from land transport, and from road transport in particular, have significant impacts on the atmosphere and on climate change. This assessment gives an overview of past, present and future emissions from land transport, of their impacts on the atmospheric composition and air quality, on human health and climate change and on options for mitigation.In the past vehicle exhaust emission control has successfully reduced emissions of nitrogen oxides, carbon monoxide, volatile organic compounds and particulate matter. This contributed to improved air quality and reduced health impacts in industrialised countries. In developing countries however, pollutant emissions have been growing strongly, adversely affecting many populations. In addition, ozone and particulate matter change the radiative balance and hence contribute to global warming on shorter time scales. Latest knowledge on the magnitude of land transport's impact on global warming is reviewed here.In the future, road transport's emissions of these pollutants are expected to stagnate and then decrease globally. This will then help to improve the air quality notably in developing countries. On the contrary, emissions of carbon dioxide and of halocarbons from mobile air conditioners have been globally increasing and are further expected to grow. Consequently, road transport's impact on climate is gaining in importance. The expected efficiency improvements of vehicles and the introduction of biofuels will not be sufficient to offset the expected strong growth in both, passenger and freight transportation. Technical measures could offer a significant reduction potential, but strong interventions would be needed as markets do not initiate the necessary changes. Further reductions would need a resolute expansion of low-carbon fuels, a tripling of vehicle fuel efficiency and a stagnation in absolute transport volumes. Land transport will remain a key sector in climate change mitigation during the next decades.     

Quantification of the influence of life cycle parameters on the total environmental impact of steel-framed buildings

Due to the increased urgency with which environmental issues are currently being prioritized, business sectors such as construction, that have been identified as one of the largest consumers of raw materials and energy, are actively involved in research aiming to optimize construction processes and products in terms of environmental impact. Although researchers have pointed out various issues and aspects of a construction project’s delivery process that can significantly affect its environmental impact, the extent to which these issues can influence the total environmental impact of the project is unclear. The current research aims to investigate and eventually quantify the influence of a number of such parameters, utilizing an existing steel-framed building as the basis for the necessary calculations. The conclusions drawn illustrate the actual extent of the influence of the examined life cycle parameters, while also offering specific insight in regard to the determination of criteria that can be used as the basis for recommendations for similar projects.     

Effects of long exposure to low temperatures on nitrifying biofilm and biomass in wastewater treatment

Attached growth biological treatment systems are a promising solution to ammonia removal in cold-temperature climates. Environmental scanning electron microscopy (ESEM) and confocal laser scanning microscopy in combination with fluorescent in situ hybridization (FISH) was used to investigate the effects of 4 months of exposure to 4 degrees C on nitrifying biofilm and biomass. These molecular and microscopic methods were modified to minimize loss of mass and distortion of in situ perspectives. Environmental scanning electron microscopy revealed that nitrifying biofilm did not exhibit significant changes in volume with exposure to 4 degrees C. Confocal laser scanning microscopy in combination with FISH showed that the number of ammonia-oxidizing bacteria (AOB) cells present in the biofilm was statistically consistent during exposure to 4 degrees C. The RNA content of AOB cells remained sufficient for FISH enumeration. The number of nitrite-oxidizing bacteria cells remained steady during exposure to 4 degrees C; however, the RNA content of the cells appeared to decrease with exposure to 4 degrees C, thereby preventing their enumeration using FISH.     

Increasing extremes of heat and drought associated with recent severe wildfires in southern Greece

Mountains of the northern Mediterranean basin face two major threats under global change. Aridity and available fuel are both expected to increase because of climatic and land-use changes, increasing fire danger. There may already be signs of such effects in the case of the Pinus nigra and Abies cephalonica forests on Mt. Taygetos (southern Greece). We reconstructed climate (mid- to late-fire-season drought) using tree-rings for the last 150 years and compared it with the mountain’s fire history reconstructed from P. nigra fire scars. Seven, out of the ten, large fires Mt. Taygetos experienced were associated with below-normal precipitation (P) or above-normal maximum temperature (T _max). The largest fires occurred in late summer of 1879, 1944, 1998, and 2007. However, only the recent fires (1998 and 2007) had both low P and high T _max, also confirmed from long-term meteorological data. The synergy between climate and fuel availability may explain the very high intensity of 1998 and 2007 fires that burned mostly as stand-replacing crown fires. The other two large fire events (1879 and 1944) most likely occurred under reduced availability in burning fuel and were related to above-normal T _max. Our findings are among the first based on long-term and site-specific empirical data to support the prediction that Mediterranean mountainous areas will face a very large threat from wildfires in the twenty-first century, if socioeconomic changes leading to land abandonment and thus burning fuel accumulation are combined with the drought intensification projected for the region under global warming.     

Environmental monitoring of radon in soil during a very seismically active period occurred in South West Greece

This paper focuses on the environmental monitoring of radon in soil as a potential trace gas in the search of earthquake precursors. The paper reports the following: (a) Pre-monitoring experiments. (b) Set-up of methods and devices. (c) Active and passive monitoring results concentrating on two extremely-strong radon anomalies (~ 500 kBq m(-3)). (e) Discussion regarding the employed ± 2σ technique for identifying radon disturbances. (f) Application of wavelet-power-spectrum fractal analysis for detecting power-law behaviour. The strong anomalies exhibited anti-persistent power-law-beta-values (b = (1.8 ± 0.2), b = (1.8 ± 0.3)) significantly higher than those of the baseline. Persistent b-values were also detected. The findings comply with a self-organised-critical pre-earthquake state. (h) Discussion on models that interpret the radon anomalies focusing on the recently-proposed asperity-model. (i) Application of a recent technique which showed that the two strong disturbances were proportional to the strain change. It was concluded that the strong radon disturbances may be linked to the strong earthquake of 8/6/2008, M = 6.5, occurred 29 km away from the installed instrumentation.     

MOSESS: A New Emission Model for the Compilation of Model-Ready Emission Inventories—Application in a Coal Mining Area in Northern Greece

Over the last years, the capabilities of chemical transport models have been greatly improved and the need for more accurate emission data has increased as well. In the past, a number of emission models have been developed and present different functionalities and applications. The majority of these though cover very specific needs. This paper describes the development of a new emission model namely computer model for the construction of model-ready emission inventories (MOSESS) which is used to compile high-resolution emission inventories or improve existing ones, utilizing complex GIS techniques. The model aims in helping chemical modelers to obtain a better overview of their modeling application by having a comprehensive understanding of the emission input. MOSESS incorporates more than 70 different emission calculation methodologies, and it is capable of handling external emission databases (such as EMEP and EPER) from which emissions can be extracted. The temporal variation (annual/daily and diurnal processing), chemical speciation of NMVOCs and particles, vertical distribution and point source treatment, as well as the spatial disaggregation of emissions (utilizing numerous spatial proxies including high-resolution landuses) can help create model-ready emission inventories which can be used for contemporary modeling applications.