24 h diffusive sampling of toxic VOCs in air onto Carbopack X solid adsorbent followed by thermal desorption/GC/MS analysis-laboratory studies

Diffusive sampling of a mixture of 42 volatile organic compounds (VOCs) in humidified, purified air onto the solid adsorbent Carbopack X was evaluated under controlled laboratory conditions. The evaluation included variations in sample air temperature, relative humidity and ozone concentration. Linearity of samples with loading was examined both for a constant concentration with time varied up to 24 h and for different concentrations over 24 h. Reverse diffusion and its increase with accumulation of sample were determined for all compounds. Tubes were examined for blank levels, change of blanks with storage time, and variability of blanks. Method detection limits were determined based on seven replicate samples. Based on this evaluation, 27 VOCs were selected for quantitative monitoring in the concentration range from approximately 0.1 to 4 ppbv. Comparison results of active and diffusive samples taken over 24 h and under the same simulated ambient conditions at a constant 2 ppbv were interpreted to estimate the effective diffusive sampling rates (ml min(-1)) and their uncertainties and to calculate the corresponding diffusive uptake rates (ng ppmv(-1) min(-1)).     

A Metamodeling Approach for Integrated Assessment of Air Quality Policies

A method is proposed to build integrated models (also called Metamodels) aimed at quantifying the economic efficiency of air quality policies. This Metamodeling approach is based on the coupling of two complementary models, that operate at different scales in space and time, and which represent the economic and the physical and chemical processes, respectively. The joint consideration of the physico-chemical and techno-economic structure of the pollution control problems permits a comprehensive evaluation of air pollution abatement strategies. The motivating pollution control problems include urban-regional air quality management through efficient energy and traffic control policies. A pilot study, exploiting data collected in the Geneva canton (Switzerland), is used to demonstrate the potential of the approach.     

monitoring bioaccumulation of contaminants in the belted kingfisher (ceryle alcyon)

The belted kingfisher (Ceryle alcyon), acommon piscivore in the eastern United States, hasbecome a common endpoint in ecological riskassessments (ERA) because of their high consumptionof potentially contaminated aquatic prey. Whilebioaccumulation data and biosurveys may be used tosupport conclusions of ERAs for kingfishers, thereare currently no published data on contaminantconcentrations in kingfishers. Additionally,methods available for collecting biological samples(e.g., feathers, eggs, food debris, etc.) fromkingfisher burrows can be detrimental to thereproductive success of the birds. We present amethod for obtaining samples from burrows during orfollowing the nesting season. The method wasapplied to kingfisher burrows on the Oak RidgeReservation (ORR) in eastern Tennessee. Feathers,eggshells, and nestlings were collected from burrows and analyzed. In addition, carcasses ofthree adult kingfishers found dead on the ORR wereanalyzed. Metals and radionuclides were accumulatedby both juvenile and adult birds. Body burdens ofcadmium, lead, and cesium-137 in adult birds were belowlevels associated with toxicity. Concentrations of selenium and mercury were observed at potentiallytoxic levels. Contaminants in eggshells andnestling feathers indicate exposure, however, thereis insufficient information to evaluate thetoxicological significance of this contamination.National Laboratory Oak Ridge National Laboratory is managed for the U.S. Department of Energy by Lockheed Martin Energy Research Corp. under contract DE-AC05-96OR22464     

Fuel characteristics and emissions from biomass burning and land-use change in Nigeria

Nigeria is one of the 13 low-latitude countries that have significant biomass burning activities. Biomass burning occurs in moist savanna, dry forests, and forest plantations. Fires in the forest zone are associated with slash-and-burn agriculture; the areal extent of burning is estimated to be 80% of the natural savanna. In forest plantations, close to 100% of litter is burned. Current estimates of emissions from land-use change are based on a 1976 national study and extrapolations from it. The following non-carbon dioxide (CO₂) trace gas emissions were calculated from savanna burning: methane (CH₄), 145 gigagrams (Gg); carbon monoxide (CO), 3831 Gg; nitrous oxide (N₂O), 2 Gg; and nitrogen oxides (NO_x), 49 Gg. Deforestation rates in forests and woodlands are 300 × 10³ ha (kilohectare, or kha) and 200 × kha per year, respectively. Trace gas emissions from deforestation were estimated to be 300 Gg CH₄, 2.4 Gg N₂O, and 24 Gg NO_x. CO₂ emissions from burning, decay of biomass, and long-term emissions from soil totaled 125 561 Gg. These estimates should be viewed as preliminary, because greenhouse gas emission inventories from burning, deforestation, and land-use change require two components: fuel load and emission factors. Fuel load is dependent on the areal extent of various land uses, and the biomass stocking and some of these data in Nigeria are highly uncertain.     

Fractionation of butyltin species during sample extraction and preparation for analysis

Solvent extraction and evaporative concentration steps are often used in procedures for the measurement of butyltins in environmental samples. As part of a larger study utilizing radiolabeled butyltins, the loss and fractionation of butyltins during sample preparation was investigated. TBT, DBT, and MBT were extracted from acidified seawater by hexane with efficiencies of about 95–99, 50–60 and 11% respectively. In addition, losses of about 70% of DBT were found during evaporative concentration of hexane. A variety of sediment extraction procedures were tested and none were found to be highly efficient for total butyltin extraction.     

Measurement of atmospheric concentrations of common household pesticides: A pilot study

Air concentrations of 28 of the most commonly used household pesticides were measured inside nine homes in Jacksonville, Florida, and compared with corresponding outdoor levels. The households selected were sorted into three categories according to the degree of pesticide indoor usage. Personal air monitoring was also performed on one resident of each household by means of a portable sampler, which was kept with the person at all times. Five of the pesticides were found in the air inside of the majority of the homes at concentrations as high as 15 gm^–3 (average concentrations, 12 ngm^–3 to 2.4 gm^–3). Indoor levels were generally one to two ordrrs of magnitude higher than surrounding outdoor air levels and personal air measurements were within ± 50% of corresponding indoor values. All samples were collected over 24-hr periods on polyurethane foam and analyzed by capillary colum gas chromatography with mass spectrometric and/or electron capture detection.     

Life-history parameters and vertical distribution of Maurolicus muelleri in Masfjorden in summer

Population characteristics, individual life-history variables, feeding and vertical distribution of the mesopelagic fish Müller's pearlside Maurolicus muelleri collected in 1990 in Masfjorden, western Norway, are reported as well as environmental variables from the fjord. Minimum size at maturity was far smaller than reported from previous investigations in the same region. Fecundity was size-dependent and total egg numbers were higher than reported from other investigations of M. muelleri world wide, while the number of maturing eggs was far lower than observed in the same region earlier. Food concentration in the fjord was an order of magnitude lower than previous early summer observations, and several factors indicated that feeding opportunities may have been low for a long period. Daily feeding rate (g prey g^-1 fish) decreased with increasing fish size. These observations fit well with a model of maximizing fitness by means of a flexible size at maturity. Minimum age at maturity seems to be achieved at the expense of fecundity. M. muelleri was concentrated in a 20 to 30 m deep sound scattering layer (SSL). The SSL stayed close to the surface during the night and at 100 to 180 m during the daytime. The vertical position of the SSL varied instantaneously with changes in surface light intensity, remaining at 10^-3 to 10^-4 mol m^-1 s^-1 at the top of the SSL. Stomach fullness was highest during the night; feeding intensity seems to have been peaked at dusk. Cladocerans were the main prey ranked by number, copepods by biomass. Intake of large copepods increased with fish size.     

Immunity in children with exposure to environmental lead: II. Effects on humoral immunity

Lead has been found to depress the immune system in animal studies at levels far below those responsible for overt toxicity. Literature studies in animal systems most clearly showed an effect of lead on response to a specific immunogenic stimulus. Data are sparse concerning the effects of lead on the immune system in the human population at greatest risk for exposure-children up to six years of age. This portion of the Phase I study reports concentrations of IgG, IgM, IgA, and IgE, as well as antibody titers to the specific antigenic stimuli provided by the vaccines against diphtheria, tetanus, and Rubella. The study population consisted of a group of 193 children, ages 9 months to 6 years, who participate in the WIC (Women, Infants and Children) and Lead Poisoning Prevention Programs in the urban area of Springfield-Greene County Missouri. Blood lead levels ranged from 1 to 50 g dL^–1. Total Ig levels were determined and the data were analysed. No consistent significant differences were observed among the risk categories in the five age groups examined. A single Ig class in each of three age groups showed apparent significant differences among the various risk categories, but these differences were not correlated with blood lead. An analysis of specific antibody titers to diphtheria, tetanus, and Rubella was performed. Regression analyses of current data in Phase I of this study suggest a detrimental effect of lead on the antibody titres to diphtheria and Rubella.     

Structural and functional responses of a freshwater plankton community to acute copper stress

An in-situ experiment was performed to quantify the impacts of copper sulfate on plankton structure and carbon dynamics. Plankton were exposed to 140 microg litre(-1) copper in quadruplicate mesocosms. Community structure was monitored for 14 days by microscopical counts and compared with untreated controls. Carbon dynamics were assessed by tracer studies using (14)C bicarbonate and (14)C glucose, to follow the fate of carbon in the algal- and bacterial-based pathways, respectively. Copper reduced the dry-weight biomass of zooplankton, ciliates, flagellates, and autotrophic phytoplankton. Bacterial biomass was increased by an order of magnitude relative to the controls. The bacterial response was most likely due to reduced grazing pressure and/or nutrient release from dying plankton. Copper reduced the effectiveness of the food web in transporting carbon to the surviving zooplankton. Bacterial-based pathways were more greatly affected than algal-based pathways, because zooplankton in the copper treatment were macro-grazers (cyclopoids), which cannot utilize bacteria.     

Comparison of allozyme and mitochondrial DNA spatial differentiation in the limpet Patella vulgata

Allozyme and restriction enzyme analysis of mtDNA was used to study variation in samples from British populations of the marine limpet Patella vulgata in two regions. South Wales and Northeast England. Allozyme analysis revealed significant differences in allele frequencies among samples. However F _ST (population differentiation) values were no higher between than within regions, indicating that genetic heterogeneity was localised and not related to geographic separation. For mtDNA, samples from South Wales exhibited higher haplotype diversity values than samples from Northeast England. In addition there were substantial differences in the haplotype distribution between regions. The value of , the haploid analogoue of F _ST , was low within regions (=0.09) but high between regions (=0.44). The estimated difference in migration rate for allozymes and mtDNA exceed the neutral expectation, unless it is assumed that there are influential differences in the magnitude of female and male gametic dispersal.