Human predisposition to cognitive impairment and its relation with environmental exposure to potentially toxic elements

New lines of evidence suggest that less than 10% of neurodegenerative diseases have a strict genetic aetiology and other factors may be prevalent. Environmental exposures to potentially toxic elements appear to be a risk factor for Parkinson’s, Alzheimer’s and sclerosis diseases. This study proposes a multidisciplinary approach combining neurosciences, psychology and environmental sciences while integrating socio-economic, neuropsychological, environmental and health data. We present the preliminary results of a neuropsychological assessment carried out in elderly residents of the industrial city of Estarreja. A battery of cognitive tests and a personal questionnaire were administered to the participants. Multivariate analysis and multiple linear regression analysis were used to identify potential relationships between the cognitive status of the participants and environmental exposure to potentially toxic elements. The results suggest a relationship between urinary PTEs levels and the incidence of cognitive disorders. They also point towards water consumption habits and profession as relevant factors of exposure. Linear regression models show that aluminium (R ² = 38%), cadmium (R ² = 11%) and zinc (R ² = 6%) are good predictors of the scores of the Mini-Mental State Examination cognitive test. Median contents (µg/l) in groundwater are above admissible levels for drinking water for aluminium (371), iron (860), manganese (250), and zinc (305). While the World Health Organization does not provide health-based reference values for aluminium, results obtained from this study suggest that it may have an important role in the cognitive status of the elderly. Urine proved to be a suitable biomarker of exposure both to elements with low and high excretion rates.     

Hotspots within hotspots? Hammerhead shark movements around Wolf Island, Galapagos Marine Reserve

Are pelagic species such as sharks and tuna distributed homogenously or heterogeneously in the oceans? Large assemblages of these species have been observed at seamounts and offshore islands in the eastern tropical Pacific, which are considered hotspots of pelagic biodiversity. Is the species distribution uniform at these hotspots or do species aggregate at a finer spatial scale at these sites? We employed three techniques to demonstrate that the aggregations of scalloped hammerhead sharks, Sphyrna lewini, and other pelagic species were confined to the southeastern corner of Wolf Island in the Galapagos Marine Reserve. Coded ultrasonic transmitters were placed on individuals at this site and at another aggregation site at Darwin Island, separated from Wolf by 40 km, and they were detected by monitors moored at the southeastern corner of Wolf Island and rarely by monitors deployed at other sites around the island. Hammerhead sharks, carrying depth-sensing continual transmitters, were tracked for two-day periods in a vessel and shown to reside a disproportionately large fraction of their time at the southeastern corner. Visual censuses were carried out seasonally at the eight monitor sites at Wolf Island, recording the abundance of one species of tuna, four species of jacks, and a number of other species. The highest diversity and abundance of these species occurred in the southeastern corner of the island. Our results support the use of hammerhead sharks as indicator and umbrella species for pelagic hotspots on a fine scale.     

Wind energy in the Isthmus of Tehuantepec: conflicts and social implications

Social acceptance is fundamental, and directly affects the installation of wind farms. In this paper, the factors that have had the greatest influence on the development of wind energy in the Itsmo region of Tehuantepec, Mexico are identified. The data were collected face to face through a semi-structured questionnaire of 31 people: owners, municipal authorities, opposition groups, and academic members. The results of the interview highlight the social impact, the lack of application, and concerning ILO Convention 169, the abuse of community rights. As a result, people interviewed perceive that the environmental impact of the installation, and operation of wind farms has been ambivalent: positive due to the intrinsic benefits that wind energy generates compared to other energy sources, and negative in terms of affectation by the noise, and the landscape. However, the income received by the owners of land in which wind facilities are located is lower compared to other parts of the world. In general, the facts show a disintegration between the authorities (federal, state, and municipal), universities are isolated from wind projects, communities are not consulted in projects, and large companies are the main beneficiaries.

     

Global variability of food waste chemical composition and its consequences on the production of biofuels and chemical compounds

Journal of Material Cycles and Waste Management - The use of food waste (FW) for the production of biofuels and value-added compounds is growing worldwide. However, the significant chemical...     

Rapid and Low-Cost Method for Evaluation of Nutrient Release from Controlled-Release Fertilizers Using Electrical Conductivity

Methods to determine nutrient release rates of coated fertilizers usually rely on chemical analyses, which often are time-consuming and/or expensive. Our goal was to develop an innovative and rapid low-cost method to evaluate nutrient release from polymer coated MAP or urea using conductometry. The release in water is determined by measuring the electric conductivity (EC) over time, with intervals dependent on release rates. In the case of soluble salt fertilizers, EC can be immediately determined and converted to a concentration using a calibration curve. In the case of urea, an additional step is needed to convert the neutral urea into ammonium. The release rates in water were assessed for a range of commercial and laboratory-coated fertilizers. A validation test demonstrated strong agreement with the release determined using analytical techniques. The EC method hence offers an easy way to quickly evaluate the time course of release of nutrients from controlled-release fertilizers.     

Determination of pesticides of different chemical classes in drinking water of the state of Santa Catarina (Brazil) using solid-phase microextraction coupled to chromatographic determinations

The evaluation of the concentration of pesticides in drinking water presents a real concern. In this study, a simple and rapid method based on solid-phase microextraction (SPME) followed by gas chromatography–mass spectrometry and electron capture detectors was developed aiming at multiclass determination of 23 pesticides regulated by the Brazilian legislation. The extraction was carried out by direct immersion mode (DI-SPME) using DVB/Car/PDMS fiber coating. In order to improve the extraction efficiency, parameters such as temperature, salting-out effect, and extraction time were optimized. The method was evaluated using drinking water samples spiked with the analytes at different concentrations, and it showed good linearity in the range studied. The values obtained for limits of quantification (LOQ) were below the limits established by Brazilian regulations. Accuracy and precision of the method exhibited satisfactory results, providing relative recoveries from 70 to 123.34% at three spiked levels, and the relative standard deviations ranged from 0.53 to 24.8%. The method was applied in 20 drinking water samples from 13 cities in the State of Santa Catarina, Brazil.

     

Electrochemical conversion of biomass-derived aldehydes into fine chemicals and hydrogen: A review

Environmental Chemistry Letters - The decrease in fossil fuel usage and the projected 28% increase in the global energy demand by 2040 are calling for advanced methods to convert modern biomass...     

A contribution for the evaluation of the territorial impact of transport infrastructures in the early stages of the EIA: application to the Huelva (Spain)–Faro (Portugal) rail link

The Environmental Impact Assessment (EIA) procedure should predict and identify the major impacts of a project development that may cause specific spatial and temporal effects. Early in the EIA, the scoping stage provides all the relevant information on the impacts of the project alternatives. In particular, potential effects on the territorial network such as habitat connectivity loss and accessibility improvements should be taken into account in the various proposed layout alternatives when evaluating transport infrastructure projects. However, several authors have identified deficiencies in practice. The aim of this article is to provide a methodology for the assessment of these territorial impacts using adequate indicators in the early stages of the EIA procedure.

The proposed method is based on a comparison of a range of alternative layouts for a railway line linking two population centres, using indicators calculated with geographic information systems. The methodology was applied to a case study – the rail link between Huelva (Spain) and Faro (Portugal) – and the high speed rail (HSR) and conventional rail were evaluated in different layouts. The method was effective in spatially identifying significant impacts on accessibility improvements, which occurred closer to the cross border area. The conventional railway alternatives have similar accessibility values to the HSR. The results also reveal that connectivity loss is not limited to the area around the infrastructure, but extends throughout the territory. The results are at variance with the initiative proposed by Spanish and Portuguese transport decision-makers, and raise the possibility of selecting a conventional railway option. An adequate territorial evaluation methodology enables the new action to be correctly assessed, and supplies the information required to propose the most suitable alternative from a socio-economic and environmental standpoint, regardless of whether this proposal was initially included in the transport policy.     

BTX in urban areas of eastern Spain: a focus on time variations and sources

Environmental Science and Pollution Research - Seasonal and daily cycles of BTX were studied in a non-industrialized city (Alicante) and an urban area near an oil refinery plant (Castellón) in...