Assessment of Dry Sorbenf Emission Control Technologies Part II. Applications

The injection of dry alkaline compounds into the furnace or post-furnace regions of utility boilers to reduce SO₂ is currently under development as a lower cost option to conventional flue gas desulfurization technology. Part I of this paper focused on the science and process development of the various dry sorbent technologies. Part II will address applications of these technologies, including SO₂ removals in full-scale boilers, methodologies for designing sorbent injection systems, power plant impacts, process integration issues, and cost.

Because the dry technologies use the furnace and/or ducts as the chemical contactor, potential impacts on power plant operation and reliability are as critical in assessing the commercial applicability of each technology as SO₂ removal and sorbent utilization. Consequently, the technical and economic feasibility of the various dry processes is highly site specific.     

Pseudoreplication in Tropical Forests and the Resulting Effects on Biodiversity Conservation

Tropical forest ecosystems are threatened by habitat conversion and other anthropogenic actions. Timber production forests can augment the conservation value of primary forest reserves, but studies of logging effects often yield contradictory findings and thus inhibit efforts to develop clear conservation strategies. We hypothesized that much of this variability reflects a common methodological flaw, simple pseudoreplication, that confounds logging effects with preexisting spatial variation. We reviewed recent studies of the effects of logging on biodiversity in tropical forests (n = 77) and found that 68% were definitively pseudoreplicated while only 7% were definitively free of pseudoreplication. The remaining proportion could not be clearly categorized. In addition, we collected compositional data on 7 taxa in 24 primary forest research plots and systematically analyzed subsets of these plots to calculate the probability that a pseudoreplicated comparison would incorrectly identify a treatment effect. Rates of false inference (i.e., the spurious detection of a treatment effect) were >0.5 for 2 taxa, 0.3–0.5 for 2 taxa, and <0.3 for 3 taxa. Our findings demonstrate that tropical conservation strategies are being informed by a body of literature that is rife with unwarranted inferences. Addressing pseudoreplication is essential for accurately assessing biodiversity in logged forests, identifying the relative merits of specific management practices and landscape configurations, and effectively balancing conservation with timber production in tropical forests. Pseudoreplicación en Bosques Tropicales y Efectos Resultantes Sobre la Conservación de Biodiversidad     

Sorption‐desorption kinetics of some organochlorine insecticides in silt‐water suspensions

Kinetic (batch) sorption and desorption experiments for some organochlorine insecticides in silt‐water suspensions are described. The effect of possible experimental artifacts on the results is examined. The influence of the silt/water ratio on the linear sorption coefficient and on the “nonextractable”; solute fraction is determined. The sorption process is described in terms of some kinetic models.     

Enhanced degradation of carbofuran in pacific northwest soils

Abstract

Persistence of ¹⁴C‐carbonyl carbofuran was measured in Pacific Northwest soils that had received 1–14 applications of the insecticide for root weevil control on perennial crops. Insecticide decay curves were obtained in nonautoclaved soil and several autoclaved soil samples from previously‐treated fields and in nonautoclaved soils from paired control sites not previously treated with carbofuran. The insecticide usually degraded faster in soil from previously‐treated fields than in soil from corresponding control fields. Among 26 previously‐treated fields, the pseudo half‐life (time for 50% loss) of carbofuran was < one wk in 11 soils, 1–3 wks in 8 soils and > 4 wks in the remaining soils. Among the nontreated control fields the pseudo half‐life was > than 2 wks in all cases and > than 15 wks in 5 of the soils. The carbofuran decay curve always possessed an initial lag phase where soil mixing enhanced insecticide decline. Carbofuran degraded very slowly in autoclaved soil samples. The half‐life of carbofuran exceeded 16 wk in all autoclaved soils tested and in most instances 85–90% of the original dosage remained when the tests were terminated 112 days after treatment. These results provided evidence that many of the soils which received applications of carbofuran over the past several years have developed a capacity to degrade carbofuran very rapidly.     

Storage and distribution of trace metals and spheroidal carbonaceous particles (SCPs) from atmospheric deposition in the catchment peats of Lochnagar, Scotland.

Lochnagar is a remote mountain lake to the south-east of the Cairngorm region in Scotland. Its catchment receives anthropogenic trace metals solely from atmospheric deposition. Ten peat cores were taken from the catchment and analysis confirmed that they have been contaminated by trace metals. The peats have an high affinity for trace metals and this results in metal accumulation in the surface peat layers. The formation of trace metal sulphides may also reduce remobilisation. In this way, trace metals derived from atmospheric deposition have been scavenged and accumulated. In contaminated peat layers, 77.4% Hg, 89.6% Pb, 93.4% Cu, 72.4% Zn and 86.5% Cd of the total stored are from anthropogenic sources. The accumulated trace metals in the peats can potentially influence the lake system through erosion. Spheroidal carbonaceous particle (SCP) profiles were used to date the peat cores. By referring to the SCP profiles in the peats and comparing these with the trace metal profiles in the lake sediments, the mobility of trace metals in the catchment peats is confirmed.     

Production of dibenzofuran fumes during splicing of PCB contaminated electrical cable

In the course of evaluating worker exposure during the hot splicing of underground electrical cable, it was discovered that the insulating tape used to make the original joints contained a high percentage (up to 10%) of PCB in the surface varnish. The heating of this PCB by a propane torch flame and molten solder as part of the normal operation of joint breakdown and remake resulted in a composition of airborne fume with a significant fraction (up to 1.3%) of the PCB that was converted to polychlorinated dibenzofurans (PCDF) with the tetra- and penta- chlorinated compounds as the predominant cogeners. No polychlorinated dibenzodioxins were detected.     

Post-Perturbation Genetic Changes in Populations of Endangered Virgin River Chubs

A 34-kilometer reach of the Virgin River, Utah-Arizona-Nevada, was poisoned with rotenone in an attempt to eradicate non-native red shiners ( Cyprinella lutrensis ), a species implicated in the decline of native fish populations in the American West. An error in detoxification resulted in lethal concentrations of piscicide passing through an additional 50 kilometers of stream. We used allozyme electrophoresis to analyze genetic variation among pre- and post-poison samples of endangered Virgin River chubs ( Gila seminuda ). Pre-poison samples indicated a single panmictic population in the river. In contrast, fish subsequently produced through natural recruitment in poisoned reaches exhibited deviations from the original pattern of genetic variation. A genetic bottleneck caused by severe reduction in the number of spawning adults was indicated. The altered pattern persisted 2.5 years post-poisoning, indicating unexpectedly slow recolonization from the unpoisoned reach upstream. Genetic variation among hatchery-produced young was similarly unrepresentative of the original pattern because of the small number of brood fish used in propagation. Because of their small numbers and/or restricted distribution, endangered species are particularly vulnerable to natural or anthropogenic catastrophes. Assessment of the genetic impact of such events is essential but requires that baseline data are available.