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21.
Baran Agnieszka Tarnawski Marek Koniarz Tomasz 《Environmental science and pollution research international》2016,23(17):17255-17268
Environmental Science and Pollution Research - The aim of study was to integrate chemical analyses and toxicity bioassays in order to assess the environmental risk connected with the presence of... 相似文献
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The separation of catalyst after photocatalytic reactions conducted in the presence of TiO2/FeCl3/UV
One of the problems connected with wastewater treatment by the photocatalytic method in the presence of TiO2 suspension is necessity of the later catalyst separation. The method proposed by us for this purpose, consists in the usage of coagulation of TiO2 suspension with the aid of FeCl3, particularly in the cases when addition of the salt is used in order to intensification of the photocatalytic process. The effects of the TiO2 separation were studied from the mixtures, after photocatalytic Acid Orange 7 degradation, with dosage of FeCl3 at different stages of the process. The coagulation was carried out at different pH values as well as different FeCl3 concentrations. It was stated that nearly 100% of separation and simultaneously, nearly 100% of decolouration of the examined Acid Orange 7 solutions after their illumination in the presence of TiO2/FeCl3 and coagulation which was produced only by increasing of pH of the obtained mixtures, were nearly possible. 相似文献
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Grzegórska Anna Czaplicka Natalia Antonkiewicz Jacek Rybarczyk Piotr Baran Agnieszka Dobrzyński Krzysztof Zabrocki Dawid Rogala Andrzej 《Environmental science and pollution research international》2023,30(9):22305-22318
Environmental Science and Pollution Research - Phytoremediation, as a cost-effective, highly efficient, environmentally friendly, and green approach, gained attention to the removal of metals,... 相似文献
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Céline Gaullier Sylvie Dousset David Billet Nicole Baran 《Environmental science and pollution research international》2018,25(15):14324-14335
Constructed wetlands (CWs) are used to reduce the pesticide inputs from tile drainage or run-off to surface water. Their effectiveness appears variable and remains to be better characterized and understood. The aim of this study was to assess the influences of two hydraulic parameters (i.e., dynamics and water level) on the sorption process occurring in CWs. Then, two solid/liquid ratios were studied (1/1 and 1/5) to mimic the water level variation in the field, and two agitation speeds were used (none and gentle agitation) to simulate different water dynamics (stagnation and flow pass, respectively). Sorption kinetics and isotherms were obtained for four pesticides with contrasting properties. The pesticide adsorption coefficients were classified as follows: boscalid (BSC) > cyproconazole (CYP) > isoproturon (IPU) ~ dimethachlor (DMT) at any ratio or agitation, in agreement with their water solubilities and K ow values. The effect of the solid/liquid ratio was evidenced for all conditions. Indeed, the adsorption equilibrium time was reached more quickly for the 1/1 ratio (24–72 h) than for the 1/5 ratio (96–120 h). In addition, the adsorption coefficients (K f ads) were larger for the 1/1 ratio (1.8–11.2 L kg?1) than for the 1/5 ratio (1.0–5.9 L kg?1). The agitation effect was ?more evidenced for the 1/5 ratio and for the more hydrophobic molecules, such as BSC and CYP, for which adsorption equilibrium time was never reached with agitation (>120 h), while it was reached at 96 h without agitation. Moreover, the K f ads values were larger with agitation than without agitation for BSC and CYP, whereas they were similar for the two agitations for IPU and DMT. Our results demonstrated that the hydrodynamic function of CWs could influence pesticide sorption with variable effects according to the molecular properties and consequently influence the mitigation effect of CWs throughout the year. 相似文献
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To obtain data concerning the risk of leaching of acetochlor (2-chloro-2'-methyl-6'-ethyl-N-ethoxymethyl-acetanilide) and its major metabolites, ethanesulfonic acid (ESA) and oxanilic acid (OA), to ground water, we studied the fate of these products in two different soil types (luvisol and calcisol) under the same weather conditions. The metabolites were detected in the soils as early as 7 d after application, indicating a rapid onset of acetochlor degradation. Ethanesulfonic acid was predominant over OA in the calcisol, regardless of time or depth, whereas the ESA to OA ratio varied with both time and depth in the luvisol. The maximum depths at which they were detected were 60 to 70 and 10 to 20 cm for ESA and OA, respectively, in the luvisol, and 60 to 70 cm (maximum depth sampled) and 30 to 40 cm for ESA and OA, respectively, in the calcisol. Acetochlor was still detected in the surface layer of the two soils 344 d after its application, although the molecule was partially leached. The maximum depths at which acetochlor was detected (60-70 cm in the luvisol and 50-60 cm [maximum depth sampled] in the calcisol) were recorded during the first sampling 7 d after application. Acetochlor was not detected on later dates below the 30- to 40-cm layer in the calcisol or the 5- to 10-cm layer in the luvisol. The greater preferential flow in the luvisol, which would have favored leaching, might partially explain why the mass balances done 7 d after application were lower in the luvisol (approximately 26%) than in the calcisol (approximately 45%). 相似文献
27.
Toxicity and biodegradability of sulfonamides and products of their photocatalytic degradation in aqueous solutions 总被引:7,自引:0,他引:7
The photocatalytic degradation of sulfacetamide, sulfathiazole, sulfamethoxazole and sulfadiazine in water solutions during their illumination of UV radiation (lambda(max) 366 nm) with TiO2 catalyst was examined. The growth-inhibition effect of sulfonamides and intermediate products theirs photodegradation was investigated in aqueous solution with the green alga Chlorella vulgaris. The biodegradability of the investigated compounds was determined in the illuminated solutions and is expressed as Biochemical Oxygen Demand. It was found that all of the investigated sulfonamides in the initial solutions were resistant to biodegradation and were toxic relative to C. vulgaris. The toxicity (EC50 values) relative to C. vulgaris increased in the following order sulfacetamide, sulfathiazole, sulfamethoxazole, sulfadiazine. All of the investigated sulfonamides undergo photocatalytic degradation. The toxicity of intermediate products of the sulfonamides degradation was significantly lower than the toxicity of sulfonamides in the initial solutions and was dependent on illumination time and degradation rate. The intermediate products of photocatalysis in contrast to the initial sulfonamides, might be mineralized using biological methods. 相似文献
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Urbaniak Magdalena Lee Sunmi Takazawa Mari Mierzejewska Elżbieta Baran Agnieszka Kannan Kurunthachalam 《Environmental science and pollution research international》2020,27(9):8872-8884
Environmental Science and Pollution Research - The aim of the study was to evaluate the influence of the application of increasing proportions (0%, 10%, 25%, 50%, 75%, and 100%) of an admixture of... 相似文献
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Agarwalla Hridesh Das Tarit Baran Senapati Rabinarayan Gangopadhyay Monalisa Masto Reginald E. Kumar Manish Singh Vikram 《Journal of Material Cycles and Waste Management》2023,25(5):2632-2641
Journal of Material Cycles and Waste Management - India is considered as one of the major mercury emitters of the world. Coal combustion in power plants is the foremost source of mercury emissions.... 相似文献
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Agarwalla Hridesh Senapati Rabi Narayan Das Tarit Baran 《Journal of Material Cycles and Waste Management》2022,24(6):2636-2643
Journal of Material Cycles and Waste Management - The Minamata convention addresses the issue related to mercury poisoning and aim to reduce mercury pollution, as mercury is one of the major... 相似文献