全文获取类型
收费全文 | 16323篇 |
免费 | 109篇 |
国内免费 | 93篇 |
专业分类
安全科学 | 357篇 |
废物处理 | 697篇 |
环保管理 | 1671篇 |
综合类 | 4160篇 |
基础理论 | 3656篇 |
环境理论 | 13篇 |
污染及防治 | 4179篇 |
评价与监测 | 947篇 |
社会与环境 | 775篇 |
灾害及防治 | 70篇 |
出版年
2022年 | 122篇 |
2021年 | 122篇 |
2019年 | 112篇 |
2018年 | 229篇 |
2017年 | 221篇 |
2016年 | 329篇 |
2015年 | 264篇 |
2014年 | 360篇 |
2013年 | 1058篇 |
2012年 | 417篇 |
2011年 | 635篇 |
2010年 | 481篇 |
2009年 | 540篇 |
2008年 | 663篇 |
2007年 | 687篇 |
2006年 | 607篇 |
2005年 | 497篇 |
2004年 | 498篇 |
2003年 | 488篇 |
2002年 | 487篇 |
2001年 | 552篇 |
2000年 | 422篇 |
1999年 | 282篇 |
1998年 | 172篇 |
1997年 | 185篇 |
1996年 | 169篇 |
1995年 | 221篇 |
1994年 | 219篇 |
1993年 | 170篇 |
1992年 | 188篇 |
1991年 | 217篇 |
1990年 | 195篇 |
1989年 | 175篇 |
1988年 | 175篇 |
1987年 | 152篇 |
1986年 | 118篇 |
1985年 | 135篇 |
1984年 | 161篇 |
1983年 | 156篇 |
1982年 | 171篇 |
1981年 | 134篇 |
1980年 | 117篇 |
1979年 | 134篇 |
1978年 | 123篇 |
1977年 | 118篇 |
1976年 | 116篇 |
1975年 | 112篇 |
1974年 | 130篇 |
1967年 | 119篇 |
1965年 | 125篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
Christian Reichel Urte Undine Frömming Marion Glaser 《Regional Environmental Change》2009,9(4):335-343
This study analyses how the conflict potential between different stakeholder groups is affecting the ecology and economy of
the Segara Anakan region, a mangrove-fringed lagoon in central Java, Indonesia. The lagoon’s increasing sedimentation/silting
up and the area’s expanding population has led to various interest groups conflicting with one another over how the resources
of the lagoon and its surrounding area are to be utilized. Conflicts arise between occupational and ethnic groups in the lagoon’s
bordering villages in the context of a transformation from fisheries to wetland agriculture. Land and mangrove use is therefore
a cause for conflict between multiple groups, including Javanese fishermen, Sundanese farmers from Central and West Java and
external shrimp farm owners. A result of the “Segara Anakan Development Project”—an 8-year undertaking that began in 1996—is
that the lagoon was frequently dredged. Due to the dredging and resulting contamination of the land, a regional clash was
triggered between Sundanese farmers and Javanese fishers. Our study reveals that the conflict potential between the various
interest groups in the Segara Anakan Lagoon area could be reduced if the scarcity of natural resources were alleviated. Religious
aspects also play a large role in marine resource utilization. Recognizing that the human utilization of natural resources
is strongly symbolic and thereby culturally defined, we unravel the resource conflicts in our study area and offer some strategic
approaches towards more sustainable outcomes. 相似文献
992.
Use and knowledge of fuelwood in three rural caatinga (dryland) communities in NE Brazil 总被引:1,自引:0,他引:1
I. M. M. Sá e Silva L. C. Marangon N. Hanazaki U. P. Albuquerque 《Environment, Development and Sustainability》2009,11(4):833-851
The woody species known, used, and preferred as fuelwood were examined in three rural communities within the county of Soledade,
Paraíba State, NE Brazil. Ethnobotanical information was collected using semi-structured interviews with more than 90% of
the local households (55 adult residents; 31 women, and 24 males). The interviewees cited 36 plant species as fuelwoods, distributed
among 30 genera and 15 families, in addition to two unidentified plants. The plant families represented by the largest numbers
of species were Euphorbiaceae, Anacardiaceae, Mimosaceae, Caesalpiniaceae, Sapotaceae, and Fabaceae. The species Caesalpinia pyramidalis Tul. (“catingueira”) was cited with the greatest frequency in all three communities. Within the communities we found significant
differences on the number of plants cited and actually used (p < 0.05), indicating that the residents knew more fuelwood species than they effectively harvest. The different distances
from the communities to the urban centers were not related to differences on the use or the size of the stocks of fuelwood.
Additionally, the study revealed that the communities examined still maintain a significant knowledge of the use of energy-providing
plants in spite of the widespread use of liquefied petroleum gas (LPG).
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. 相似文献
993.
The degradation of linuron, one of phenylurea herbicides, was investigated for its reaction kinetics by different treatment processes including ultraviolet irradiation (UV), ozonation (O3), and UV/O3. The decay rate of linuron by UV/O3 process was found to be around 3.5 times and 2.5 times faster than sole-UV and ozone-alone, respectively. Experimental results also indicate overall rate constants increased exponentially with pH above 9.0 while the increase of rate constants with pH below 9 is insignificant in O3 system. All dominant parameters involved in the three processes were determined in the assistant of proposed linear models in this study. The approach was found useful in predicting the process performances through the quantification of quantum yield (rate constant for the formation of free radical HOO− from ozone decomposition at high pH), rate constant of linuron with ozone (kO3,LNR), rate constant of linuron with hydroxyl radical (kOH,LNR), and α (the ratio of the production rate of OH and the decay rate of ozone in UV/O3 system). 相似文献
994.
The boundary between preferential flow and Richards-type flow is a priori set at a volumetric soil water content θ at which soil water diffusivity D (θ) = η (= 10− 6 m2 s− 1), where η is the kinematic viscosity. First we estimated with a hydrostatic approach from soil water retention curves the boundary, θK, between the structural pore domain, in which preferential flow occurs, and the matrix pore domain, in which Richards-type flow occurs. We then compared θK with θ that was derived from the respective soil hydrological property functions of same soil sample. Second, from in situ investigations we determined 96 values of θG as the terminal soil water contents that established themselves when the corresponding water-content waves of preferential flow have practically ceased. We compared the frequency distribution of θG with the one of θ that was calculated from the respective soil hydrological property functions of 32 soil samples that were determined with pressure plate apparatuses in the laboratory. There is support of the notion that θK ≈ θG ≈ θ, thus indicating the potential of θ to explain more generally what constitutes preferential flow. However, the support is assessed as working hypothesis on which to base further research rather than a procedure to a clear-cut identification of preferential flow and associated flow paths. 相似文献
995.
Nadeem W. Shah Steven F. Thornton Simon H. Bottrell Michael J. Spence 《Journal of contaminant hydrology》2009,103(3-4):119-133
The potential for aerobic biodegradation of MTBE in a fractured chalk aquifer is assessed in microcosm experiments over 450 days, under in situ conditions for a groundwater temperature of 10 °C, MTBE concentration between 0.1 and 1.0 mg/L and dissolved O2 concentration between 2 and 10 mg/L. Following a lag period of up to 120 days, MTBE was biodegraded in uncontaminated aquifer microcosms at concentrations up to 1.2 mg/L, demonstrating that the aquifer has an intrinsic potential to biodegrade MTBE aerobically. The MTBE biodegradation rate increased three-fold from a mean of 6.6 ± 1.6 μg/L/day in uncontaminated aquifer microcosms for subsequent additions of MTBE, suggesting an increasing biodegradation capability, due to microbial cell growth and increased biomass after repeated exposure to MTBE. In contaminated aquifer microcosms which also contained TAME, MTBE biodegradation occurred after a shorter lag of 15 or 33 days and MTBE biodegradation rates were higher (max. 27.5 μg/L/day), probably resulting from an acclimated microbial population due to previous exposure to MTBE in situ. The initial MTBE concentration did not affect the lag period but the biodegradation rate increased with the initial MTBE concentration, indicating that there was no inhibition of MTBE biodegradation related to MTBE concentration up to 1.2 mg/L. No minimum substrate concentration for MTBE biodegradation was observed, indicating that in the presence of dissolved O2 (and absence of inhibitory factors) MTBE biodegradation would occur in the aquifer at MTBE concentrations (ca. 0.1 mg/L) found at the front of the ether oxygenate plume. MTBE biodegradation occurred with concomitant O2 consumption but no other electron acceptor utilisation, indicating biodegradation by aerobic processes only. However, O2 consumption was less than the stoichiometric requirement for complete MTBE mineralization, suggesting that only partial biodegradation of MTBE to intermediate organic metabolites occurred. The availability of dissolved O2 did not affect MTBE biodegradation significantly, with similar MTBE biodegradation behaviour and rates down to ca. 0.7 mg/L dissolved O2 concentration. The results indicate that aerobic MTBE biodegradation could be significant in the plume fringe, during mixing of the contaminant plume and uncontaminated groundwater and that, relative to the plume migration, aerobic biodegradation is important for MTBE attenuation. Moreover, should the groundwater dissolved O2 concentration fall to zero such that MTBE biodegradation was inhibited, an engineered approach to enhance in situ bioremediation could supply O2 at relatively low levels (e.g. 2–3 mg/L) to effectively stimulate MTBE biodegradation, which has significant practical advantages. The study shows that aerobic MTBE biodegradation can occur at environmentally significant rates in this aquifer, and that long-term microcosm experiments (100s days) may be necessary to correctly interpret contaminant biodegradation potential in aquifers to support site management decisions. 相似文献
996.
Impact of initial and boundary conditions on preferential flow 总被引:4,自引:1,他引:3
Preferential flow in soil is approached by a water-content wave, WCW, that proceeds downward from the ground surface. WCWs were obtained from sprinkler experiments with infiltration rates varying from 5 to 40 mm h− 1. TDR-probes and tensiometers measured volumetric water contents θ(z,t) at seven depths, and capillary heads, h(z,t) at six depths in a column of an undisturbed soil. The wave is characterized by the velocity of the wetting front, cW, the amplitude, wS, and the final water content, θ. We tested with uni-variate and bi-variate linear regressions the impacts of initial volumetric water contents, θini, and input rates, qS, on cW, wS and θ.The test showed that θini influenced θ and wS and qS effected cW. The expected proportionality of wS ≈ qs1/3 was weak and cW ≈ qs2/3 was strong. 相似文献
997.
Kumpiene J Ragnvaldsson D Lövgren L Tesfalidet S Gustavsson B Lättström A Leffler P Maurice C 《Chemosphere》2009,74(2):206-215
The impact of water saturation level (oxidizing-reducing environment) on As and metal solubility in chromium, copper, arsenic (CCA)-contaminated soil amended with Fe-containing materials was studied. The soil was mixed with 0.1 and 1 wt% of iron grit (Fe(0)) and 1, 7 and 15 wt% of oxygen scarfing granulate (OSG, a by-product of steel processing). Solubility of As and metals was evaluated by a batch leaching test and analysis of soil pore water. Soil saturation with water greatly increased As solubility in the untreated as well as in the Fe-amended soil. This was related to the reductive dissolution of Fe oxides and increased concentration of As(III) species. Fe amendments showed As reducing capacity under both oxic and anoxic conditions. The cytotoxicity of the soil pore water correlated with the concentration of As(III). The Fe-treatments as well as water saturation of soil were less significant for the solubility of Cu, Cr and Zn than for As. The batch leaching test used for waste characterization substantially underestimated As solubility that could occur under water-saturated (anaerobic) conditions. In the case of soil landfilling, other techniques than Fe-stabilization of As containing soil should be considered. 相似文献
998.
Degassing of H/He, CFCs and SF6 by denitrification: Measurements and two-phase transport simulations
Ate Visser Joris D. Schaap Hans Peter Broers Marc F.P. Bierkens 《Journal of contaminant hydrology》2009,103(3-4):206-218
The production of N2 gas by denitrification may lead to the appearance of a gas phase below the water table prohibiting the conservative transport of tracer gases required for groundwater dating. We used a two-phase flow and transport model (STOMP) to study the reliability of 3H/3He, CFCs and SF6 as groundwater age tracers under agricultural land where denitrification causes degassing. We were able to reproduce the amount of degassing (R2 = 69%), as well as the 3H (R2 = 79%) and 3He (R2 = 76%) concentrations observed in a 3H/3He data set using simple 2D models. We found that the TDG correction of the 3H/3He age overestimated the control 3He/3He age by 2.1 years, due to the accumulation of 3He in the gas phase. The total uncertainty of degassed 3H/3He ages of 6 years (± 2 σ) is due to the correction of degassed 3He using the TDG method, but also due to the travel time in the unsaturated zone and the diffusion of bomb peak 3He. CFCs appear to be subject to significant degradation in anoxic groundwater and SF6 is highly susceptible to degassing. We conclude that 3H/3He is the most reliable method to date degassed groundwater and that two-phase flow models such as STOMP are useful tools to assist in the interpretation of degassed groundwater age tracer data. 相似文献
999.
A.A.L. Oiffer J.F. Barker F.M. Gervais K.U. Mayer C.J. Ptacek D.L. Rudolph 《Journal of contaminant hydrology》2009,108(3-4):89-106
An anaerobic plume of process-affected groundwater was characterized in a shallow sand aquifer adjacent to an oil sands tailings impoundment. Based on biological oxygen demand measurements, the reductive capacity of the plume is considered minimal. Major dissolved components associated with the plume include HCO3, Na, Cl, SO4, and naphthenic acids (NAs). Quantitative and qualitative NA analyses were performed on groundwater samples to investigate NA fate and transport in the subsurface. Despite subsurface residence times exceeding 20 years, significant attenuation of NAs by biodegradation was not observed based on screening techniques developed at the time of the investigation. Relative to conservative tracers (i.e., Cl), overall NA attenuation in the subsurface is limited, which is consistent with batch sorption and microcosm studies performed by other authors. Insignificant biological oxygen demand and low concentrations of dissolved As (< 10 µg L− 1) in the plume suggest that the potential for secondary trace metal release, specifically As, via reductive dissolution reactions driven by ingress of process-affected water is minimal. It is also possible that readily leachable As is not present in significant quantities within the sediments of the study area. Thus, for similar plumes of process-affected groundwater in shallow sand aquifers which may occur as oil sands mining expands, a reasonable expectation is for NA persistence, but minimal trace metal mobilization. 相似文献
1000.
Spohn P Hirsch C Hasler F Bruinink A Krug HF Wick P 《Environmental pollution (Barking, Essex : 1987)》2009,157(4):1134-1139
Since the discovery of fullerenes in 1985, these carbon nanospheres have attracted attention regarding their physico/chemical properties. Despite little knowledge about their impact on the environment and human health, the production of fullerenes has already reached an industrial scale. However, the toxicity of C60 is still controversially discussed.The aim of this study was to clarify the biological effects of tetrahydrofuran (THF) suspended C60 fullerene in comparison to water stirred C60 fullerene suspensions. Beyond that, we analyzed the effects on the Crustacea Daphnia magna an indicator for ecotoxicological effects and the human lung epithelial cell line A549 as a simplified model for the respiratory tract.We could demonstrate that water-soluble side products which were formed in THF nC60 suspension were responsible for the observed acute toxic effects, whereas fullerenes themselves had no negative effect regardless of the preparative route on either A549 cell in vitro or D. magna in vivo. 相似文献