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排序方式: 共有190条查询结果,搜索用时 343 毫秒
101.
Annabel Fernandes João Coelho Lurdes Ciríaco Maria José Pacheco Ana Lopes 《Environmental science and pollution research international》2016,23(24):24614-24623
Boron-doped diamond (BDD) and Ti/Pt/PbO2 anodes were utilized to perform the electrodegradation of synthetic samples containing humic acid in the presence of different organic and inorganic carbon-containing and nitrogen-containing compounds. The influence of the chloride ion in the degradation process of the different synthetic samples was also assessed. The results showed that the anodic oxidation process can efficiently degrade recalcitrant compounds such as humic acid. The presence of carbonate in solution enhances the nitrogen removal, whereas it hinders the oxidation of the organic compounds. When organic nitrogen is present, it is converted to NH4 +, which in turn is oxidized to nitrate and to volatile nitrogen compounds. Hydroxyl radicals are more prone to oxidize the organic nitrogen than the ammonium nitrogen. The presence of chloride enhances the organic matter and nitrogen removal rates, BDD being the anode material that yields the highest removals. 相似文献
102.
The current study investigated oxidative stress parameters (enzymes activities, metallothionein content and lipid peroxidation) in freshwater fish, Oreochromis niloticus, tilapia exposure to Monjolinho River (in 4 months of year: January, April, July and November). One critical site in Monjolinho River (site B) was assessed in comparison to a reference site (site A). Water pH and oxygen concentration was lower than that recommended by CONAMA (Brazilian National Environmental Committee), resolution 357/2005 for protection of aquatic communities, and ammonium and the metals Cu, Zn, Mn and Fe (on all months) concentrations were higher than the maximum concentration recommended. Glutathione peroxidase (GPx) and superoxide dismutase (SOD) activities were significantly decreased in liver and muscle in tilapia from Monjolinho River, throughout the year, in relation to reference except in gills that SOD activity increased. Glutathione S-transferase (GST) activity was significantly increased in liver of the tilapia from Monjolinho River in all sites, in relation to reference except in gills that GST activity increased in July and decreased in November, suggesting that GST activity could be induced to neutralize the pollutants toxicity. On the other hand, GST activity was significantly decreased in white muscle indicating a toxic effect of pollutants, resulting in a decreased ability of tilapia to perform defense reactions associated to GSTs. The decrease of catalase (CAT) activity in gills of the O. niloticus together with the increase of SOD activity, could explain the increased lipid peroxidation (LPO) level in this organ. Metallothionein levels in liver and gills were significantly high in all sites. Results indicate that the exposure to metals caused severe damage to tissues; despite the consensually assumed antioxidant induction as a sign of exposure to contaminants the effects seem in part to be mediated by suppression of antioxidant system with SOD, CAT and GPx as potential candidates for tissues toxicity biomarkers of pollutants. 相似文献
103.
Gabriel Hiromite Yoshino Lindemberg Lima Fernandes Júnior Hiroyuki Ishihara Adnilson Igor Martins da Silva 《Environment, Development and Sustainability》2014,16(2):431-442
The Brazilian Amazon has about 69 % of available freshwater in Brazil, an amount that ends up creating the illusion that no lack of water and not lacking in the region, the large supply of this resource becomes a problem when it comes to the Management and Planning Water Resources in the Amazon, according to the wasteful use and lack of maintenance of stocks, compounded by the release of untreated wastewater. Speaking of water conservation programs in the Amazon a few decades ago and still today, with less intensity, is somewhat strange, given the large amount of water available and the culture of abundance. Thus, this research discusses the importance of the use of rainwater for non-potable purposes, since the potential for exploitation, throughout the year, due to this high rainfall in the Amazon region, ranging from, on average, 119.6 mm in months from November to 441.6 mm in March. The methods used for sizing of the reservoir were the Rippl and interactive, and economic viability checking done by the methods of net present value and discounted payback. As a result, there was a volume exceeding 1,000 m³ obtained by the method of Rippl, while the interactive method was a maximum of 75 m³. The economic viability presented fragile as a function of time to return exceeds the useful life of the utilization system for rainwater. 相似文献
104.
Sangram K. Samal E. G. Fernandes Andrea Corti Emo Chiellini 《Journal of Polymers and the Environment》2014,22(1):58-68
Formulations of low cost bio-based oxo-biodegradable polyethylene (PE)/Lignin hybrid polymeric composites were prepared by using ethylene/vinyl acetate (EVA) copolymer as compatibilizer and a transition metal salt as oxo-biodegradation promoter. The hybrid composites and relevant Lignin-free blends were formulated by following a statistical mixture design. The effect of Lignin, pro-degradant additive, EVA copolymer and their compatibility with the PE continuous matrix, was evaluated by means of structural features by attenuated total reflectance, morphological by scanning electron microscopy, thermal by differential scanning calorimetry and thermo-gravimetric analysis and mechanical properties by an Instron Machine. The results attained in this study, regarding especially the thermal and mechanical properties, suggest that bio-based oxo-biodegradable hybrid composites offer an interesting way to produce low cost bio-based materials with fairly enhanced properties. The moderate-low cost hybrid materials appear to be attractive for their potential in the mercantile area of commodities including: packaging, personal care products, agricultural mulch films and disposable items. This will constitute a novel added-value contribution aimed at mitigating the environmental burden caused by plastic waste items improperly abandoned in the environment. 相似文献
105.
106.
Monteiro RC Figueiredo CF Alendouro MS Ferro MC Davim EJ Fernandes MH 《Waste management (New York, N.Y.)》2008,28(7):1119-1125
The characterization of the bottom ashes produced by two Portuguese municipal solid waste incinerators (MSWI) was performed with the aim of assessing the feasibility of using this waste as raw material in the production of glass that can be further processed as glass-ceramics for application in construction. Density and particle size distribution measurements were carried out for physical characterization. Chemical characterization revealed that SiO(2), a network glass former oxide, was present in a relatively high content (52-58wt%), indicating the suitability for this waste to be employed in the development of vitreous materials. CaO, Na(2)O and K(2)O, which act as fluxing agents, were present in various amounts (2-17wt%) together with several other oxides normally present in ceramic and glass raw materials. Mineralogical characterization revealed that the main crystalline phases were quartz (SiO(2)) and calcite (CaCO(3)) and that minor amounts of different alkaline and alkaline-earth aluminosilicate phases were also present. Thermal characterization showed that the decomposition of the different compounds occurred up to 1100 degrees C and that total weight loss was <10wt%. Heating both bottom ashes at 1400 degrees C for 2h resulted in a melt with suitable viscosity to be poured into a mould, and homogeneous black-coloured glasses with a smooth shiny surface were obtained after cooling. The vitrified bottom ashes were totally amorphous as confirmed by X-ray diffraction. The results from the present experimental work indicate that the examined bottom ashes can be a potential material to melt and to obtain a glass that can be further processed as glass-ceramics to be applied in construction. 相似文献
107.
Characterization of Atrazine-Loaded Biodegradable Poly(Hydroxybutyrate-Co-Hydroxyvalerate) Microspheres 总被引:2,自引:0,他引:2
Renato Grillo Nathalie F. S. de Melo Renata de Lima Roberto Wagner Lourenço André Henrique Rosa Leonardo Fernandes Fraceto 《Journal of Polymers and the Environment》2010,18(1):26-32
Polyhydroxybutyrate-co-hydroxyvalerate microspheres (PHBV-MS) were prepared as a delivery system for the herbicide atrazine
(ATZ). Characterization of the system included investigation of in vitro release properties and genotoxicity. ATZ − PHBV-MS
particle diameters showed a size distribution range of 1–13 μm. Differential scanning calorimetry analyses indicated that
ATZ was associated with the PHBV microparticles. The release profiles showed a different release behavior for the pure herbicide
in solution, as compared with that containing ATZ-loaded PHBV-MS. Korsmeyer–Peppas model analyses showed that atrazine release
from the microparticles occurred by a combination of diffusion through the matrix and partial diffusion through water-filled
pores of the PHBV microparticles. A Lactuca sativa test result showed that the genotoxicity of ATZ-loaded PHBV-MP was decreased in relation to ATZ alone. The results demonstrate
a viable biodegradable herbicide release system using atrazine for agrochemical purposes. 相似文献
108.
Rodrigues Ana Sofia Silveira Jefferson E. Carbajo Jaime Zazo Juan A. Casas Jose A. Fernandes Annabel Pacheco Maria José Ciríaco Lurdes Lopes Ana 《Environmental science and pollution research international》2021,28(19):23822-23832
Environmental Science and Pollution Research - Perovskite oxides BaFeyTi1-yO3, with y = 0, 0.6, 0.8 and 1, were prepared by ceramic (CM) and complex polymerization methods (CPM) and utilized in... 相似文献
109.
Sean D. Connell Milena Fernandes Owen W. Burnell Zoë A. Doubleday Kingsley J. Griffin Andrew D. Irving Jonathan Y.S. Leung Samuel Owen Bayden D. Russell Laura J. Falkenberg 《Conservation biology》2017,31(5):1196-1201
Although the public desire for healthy environments is clear‐cut, the science and management of ecosystem health has not been as simple. Ecological systems can be dynamic and can shift abruptly from one ecosystem state to another. Such unpredictable shifts result when ecological thresholds are crossed; that is, small cumulative increases in an environmental stressor drive a much greater change than could be predicted from linear effects, suggesting an unforeseen tipping point is crossed. In coastal waters, broad‐scale seagrass loss often occurs as a sudden event associated with human‐driven nutrient enrichment (eutrophication). We tested whether the response of seagrass ecosystems to coastal nutrient enrichment is subject to a threshold effect. We exposed seagrass plots to different levels of nutrient enrichment (dissolved inorganic nitrogen) for 10 months and measured net production. Seagrass response exhibited a threshold pattern when nutrient enrichment exceeded moderate levels: there was an abrupt and large shift from positive to negative net leaf production (from approximately 0.04 leaf production to 0.02 leaf loss per day). Epiphyte load also increased as nutrient enrichment increased, which may have driven the shift in leaf production. Inadvertently crossing such thresholds, as can occur through ineffective management of land‐derived inputs such as wastewater and stormwater runoff along urbanized coasts, may account for the widely observed sudden loss of seagrass meadows. Identification of tipping points may improve not only adaptive‐management monitoring that seeks to avoid threshold effects, but also restoration approaches in systems that have crossed them. 相似文献
110.
Marcionília Fernandes Pimentel Évila Pinheiro Damasceno Paula Christine Jimenez Pedro Filipe Ribeiro Araújo Marcielly Freitas Bezerra Pollyana Cristina Vasconcelos de Morais Rivelino Martins Cavalcante Susana Loureiro Letícia Veras Costa Lotufo 《Environmental monitoring and assessment》2016,188(5):298