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81.
D'Alessandro W Bellomo S Parello F Brusca L Longo M 《Environmental monitoring and assessment》2008,145(1-3):303-313
Six hundred and sixty-seven water samples were collected from public drinking water supplies in Sicily and analysed for electric conductivity and for their Cl(-), Br(-) and F(-) contents. The samples were, as far as possible, collected evenly over the entire territory with an average sampling density of about one sample for every 7,600 inhabitants. The contents of Cl(-) and Br(-), ranging between 5.53 and 1,302 mg/l and between <0.025 and 4.76 mg/l respectively, correlated well with the electric conductivity, a parameter used as a proxy for water salinity. The highest values were found both along the NW and SE coasts, which we attributed to seawater contamination, and in the central part of Sicily, which we attributed to evaporitic rock dissolution. The fluoride concentrations ranged from 0.023 to 3.28 mg/l, while the highest values (only three exceeding the maximum admissible concentration of 1.5 mg/l) generally correlated either with the presence in the area of crystalline (volcanic or metamorphic) or evaporitic rocks or with contamination from hydrothermal activity. Apart from these limited cases of exceeding F(-) levels, the waters of public drinking water supplies in Sicily can be considered safe for human consumption for the analysed parameters. Some limited concern could arise from the intake of bromide-rich waters (about 3% exceeding 1 mg/l) because of the potential formation of dangerous disinfection by-products. 相似文献
82.
83.
Cristani M Naccari C Nostro A Pizzimenti A Trombetta D Pizzimenti F 《Environmental science and pollution research international》2012,19(1):161-168
Background, aim and scope
Metal pollution is a serious problem for environmental safety and programmes of monitoring and bioremediation are needed. Among the processes of bioremediation, the use of microbes to remove and degrade contaminants is considered a biotechnological approach to clean up polluted environments. 相似文献84.
Rossella Guerrieri Rolf Siegwolf Francesco Ripullone Marco Borghetti 《Environmental pollution (Barking, Essex : 1987)》2010,158(9):2841-2847
We investigated the effect of N deposition (Ndep) on intrinsic water-use efficiency (WUEi), the ratio of photosynthesis (A) to stomatal conductance (gs), for two Quercus cerris stands at different distances to an oil refinery in Southern Italy. We used δ13C in tree rings for assessing changes in WUEi; while the influence of climate and NOx emission was explored through δ18O and δ15N, respectively. Differences in WUEi between the two sites were significant, with trees exposed to different degrees of NOx emissions showing an abrupt increase with the onset of pollution. Assuming similar gs at the two sites, as inferred through δ18O, the higher N availability at the polluted site caused the shift of the A/gs ratio in favour of A. Overall, our result suggests that an increase of Ndep may enhance tree WUE under a scenario of reduction of precipitation predicted for Mediterranean area. 相似文献
85.
Daniele Fattorini Alessandra Notti Marco Nigro Francesco Regoli 《Environmental science and pollution research international》2010,17(1):220-228
Background, aim, and scope
Exceptionally high levels of trace metals have been reported in specific tissues of certain polychaetes. In the present study, the Antarctic fan worm Perkinsiana littoralis was shown to hyperaccumulate vanadium in the branchial tissues, and the hypothesis of an antipredatory strategy has been investigated 相似文献86.
Thermodynamic analysis of the energy recovery from the aerobic bioconversion of solid urban waste organic fraction 总被引:1,自引:0,他引:1
Waste management is of the utmost importance for many countries and especially for highly developed ones due to its implications on society. In particular, proper treatment before disposal of the solid urban waste organic fraction is one of the main issues that is addressed in waste management. In fact, the organic fraction is particularly reactive and if disposed in sanitary landfills without previous adequate treatment, a large amount of dangerous and polluting gaseous, liquid and solid substances can be produced. Some waste treatment processes can also present an opportunity to produce other by-products like energy, recycled materials and other products with both economic and environmental benefits. In this paper, the aerobic treatment of the organic fraction of solid urban waste, performed in a biocell plant with the possibility of recovering heat for civil or industrial needs, was examined from the thermodynamic point of view. A theoretical model was proposed both for the biological process of the organic fraction, as well as for the heat recovery system. The most significant results are represented and discussed. 相似文献
87.
Postconsumer polyethylene terephthalate (PET)/polyolefin blends through reactive processing 总被引:1,自引:0,他引:1
Mauro?AgliettoEmail author Maria-Beatrice?Coltelli Stefania?Savi Francesco?Lochiatto Francesco?Ciardelli Maurizio?Giani 《Journal of Material Cycles and Waste Management》2004,6(1):13-19
Increasing awareness of environmental and energy problems has promoted greater governmental interest in selected waste collection and consequently has attracted the interest of several research groups to the challenge of converting recovered plastics into useful materials. The reactive blending of postconsumer polyethylene terephthalate (PET) with different polyolefins (PO) was studied in attempts to obtain a new material with enhanced properties with respect to the starting materials. The success of the project depends mainly on the possibility of obtaining a compatibilized blend between two starting polymers that, from chemical and thermomechanical viewpoints, are very different. This was approached by employing polyolefins bearing functional groups capable of specific interaction or chemical reaction with PET end groups. Ternary blends of very low density polyethylene (VLDPE)/PET/functionalized polyolefin (FPO) in a weight composition of 70/20/10 and binary blends of FPO/PET in a weight composition of 90/10 were prepared and studied to obtain reinforced polyolefin thermoplastic materials. Reactive blending was achieved in a Brabender Plastograph with a mixing chamber of 30 or 50cm3, at 250°C, and 40rpm for 10min. Differential scanning calorimetry, scanning electron microscopy, and tensile tests were used to investigate the phase behavior, the efficiency of compatibilization, and the mechanical properties of the blends. 相似文献
88.
89.
Francesco Barzagli Fabrizio Mani Maurizio Peruzzini 《International Journal of Greenhouse Gas Control》2011,5(3):448-456
The carbon dioxide capture and release from aqueous 2,2′-iminodiethanol (DEA) and N-methyl-2,2′-iminodiethanol (MDEA) have been investigated by means of 13C NMR spectroscopy. We have designed two experimental procedures using a gas mixture containing 12% (v/v) CO2 in N2 or air and 0.667 M aqueous solutions of DEA and MDEA. To understand the CO2–amine reaction equilibria, separate experiments of CO2 absorption (at 293, 313 and 333 K) and desorption (at boiling temperature, room pressure) were carried out. The 13C NMR analysis has allowed us to establish: (1) the percentage of CO2 stored in solution as HCO3?, CO32? and DEA carbamate; (2) the formation of DEA carbamate as a function of absorption temperature and time; (3) the slower decomposition of DEA carbamate than that of bicarbonate. In the experiments planned to test the reuse of the regenerated amines, the absorbent solution was continuously circulated in a closed cycle while it was absorbing CO2 in the absorber (set at 293 K) and simultaneously regenerating amine in the desorber (set at 388 K). After the equilibrium has been reached (13 h), the CO2 absorption efficiency is comprised between 84.0% (DEA) and 82.6% (MDEA) and the average amine regeneration efficiency ranges between 69.6% (DEA) and 78.2% (MDEA). Additionally, MDEA is more stable towards thermal degradation than DEA. 相似文献
90.
Stefano Cinti Francesco Santella Danila Moscone Fabiana Arduini 《Environmental science and pollution research international》2016,23(9):8192-8199
A miniaturized screen-printed electrode (SPE) modified with a carbon black-gold nanoparticle (CBNP-AuNP) nanocomposite has been developed as an electrochemical sensor for the detection of inorganic mercury ions (Hg2+). The working electrode surface has been modified with nanocomposite constituted of CBNPs and AuNPs by an easy drop casting procedure that makes this approach extendible to an automatable mass production of modified SPEs. Square wave anodic stripping voltammetry (SWASV) was adopted to perform Hg2+ detection, revealing satisfactory sensitivity and detection limit, equal to 14 μA ppb?1 cm?2 and 3 ppb, respectively. The applicability of the CBNP-AuNP-SPE for the determination of inorganic mercury has been assessed in river water by a simple filtration and acidification of the sample as well as in soil by means of a facile acidic extraction procedure assisted by ultrasound. 相似文献