Combining steam injection with hydraulic fracturing for the in situ remediation of the unsaturated zone of a fractured soil polluted by jet fuel

A steam injection pilot-scale experiment was performed on the unsaturated zone of a strongly heterogeneous fractured soil contaminated by jet fuel. Before the treatment, the soil was stimulated by creating sub-horizontal sand-filled hydraulic fractures at three depths. The steam was injected through one hydraulic fracture and gas/water/non-aqueous phase liquid (NAPL) was extracted from the remaining fractures by applying a vacuum to extraction wells. The injection strategy was designed to maximize the heat delivery over the entire cell (10 m × 10 m × 5 m). The soil temperature profile, the recovered NAPL, the extracted water, and the concentrations of volatile organic compounds (VOCs) in the gas phase were monitored during the field test. GC-MS chemical analyses of pre- and post-treatment soil samples allowed for the quantitative assessment of the remediation efficiency. The growth of the heat front followed the configuration of hydraulic fractures. The average concentration of total hydrocarbons (g/kg of soil) was reduced by ～ 43% in the upper target zone (depth = 1.5-3.9 m) and by ～ 72% over the entire zone (depth = 1.5-5.5 m). The total NAPL mass removal based on gas and liquid stream measurements and the free-NAPL product were almost 30% and 2%, respectively, of those estimated from chemical analyses of pre- and post-treatment soil samples. The dominant mechanisms of soil remediation was the vaporization of jet fuel compounds at temperatures lower than their normal boiling points (steam distillation) enhanced by the ventilation of porous matrix due to the forced convective flow of air. In addition, the significant reduction of the NAPL mass in the less-heated deeper zone may be attributed to the counter-current imbibition of condensed water from natural fractures into the porous matrix and the gravity drainage associated with seasonal fluctuations of the water table.     

Case-control and cross-sectional methods for estimating crash modification factors: comparisons from roadway lighting and lane and shoulder width safety effect studies

Problem

While observational before-after studies are considered the industry standard for developing crash modification factors (CMFs), there are practical limitations that may preclude their use in highway safety analysis. There is a need to explore alternative methods for estimating CMFs.

Method

This paper employs case-control and cross-sectional analyses to estimate CMFs for fixed roadway lighting and the allocation of lane and shoulder widths.

Results

Based on the case-control method, the CMF for intersection lighting is 0.886, while the cross-sectional study indicates a CMF of 0.881. The CMFs developed for lane and shoulder widths are also similar when comparing the two methods.

Conclusions

This paper suggests that case-control and cross-sectional studies produce consistent results if care is taken in the study design and model development.

Impact on industry

Case-control and cross-sectional studies may provide a viable alternative to estimate CMFs when a before-after study is impractical due to data restrictions.     

The establishment of a standard operation procedure for psychiatric service after an earthquake

This study presents information on the design and creation of a standard operation procedure (SOP) for psychiatric service after an earthquake. The strategies employed focused on the detection of survivors who developed persistent psychiatric illness, particularly post-traumatic stress and major depressive disorders. In addition, the study attempted to detect the risk factors for psychiatric illness. A Disaster-Related Psychological Screening Test (DRPST) was designed by five psychiatrists and two public health professionals for rapidly and simply interviewing 4,223 respondents within six months of the September 1999 Chi-Chi earthquake. A SOP was established through a systemic literature review, action research, and two years of data collection. Despite the limited time and resources inherent to a disaster situation, it is necessary to develop an SOP for psychiatric service after an earthquake in order to assist the high number of survivors suffering from subsequent psychiatric impairment.     

Deriving a bioavailability-based zinc environmental quality standard for France

Environmental Science and Pollution Research - National Environmental Quality Standards (EQS) for zinc used for the assessment of ecological status in freshwaters have been shown to vary by over...     

Djungarian hamsters (Phodopus sungorus) are not susceptible to stimulating effects of 6-methoxy-2-benzoxazolinone on reproductive organs

The secondary plant metabolite 6-methoxy-2-benzoxazolinone (6-MBOA) is abundant in vegetative parts of monocotyledons emerging in spring. This grazing protective has been shown to promote gonadal growth and, thus enable precise alignment of reproductive activity with favorable environmental conditions in a variety of seasonally breeding rodent species. Feeding and breeding ecology make the Djungarian hamster (Phodopus sungorus) a potential candidate using 6-MBOA as an acute environmental cue to optimize reproductive timing when photorefractoriness induces reproductive recrudescence. Therefore, four different experiments were designed to examine whether the hamsters’ reproductive organs are responsive to oral 6-MBOA administration under different photoperiodic conditions. Only under a long photoperiod, we found a slight increase in uterine weights. In a short photoperiod, 6-MBOA-treated hamsters showed a slight body weight gain without a change in uterine weights. However, these marginal effects are likely not to be of ecophysiological significance for reproductive timing. The results are in agreement with the common view that the annual changes in photoperiod length are not only the predominant environmental cue for Djungarian hamsters, but are also sufficient to synchronize reproductive efforts with favorable breeding conditions in highly predictable climates like the continental Asian steppes.     

Biomechanics of Pediatric Cervical Spine: Compression,Flexion and Extension Responses

The objective of the present study was to develop three separate age-specific one, three, and six year old pediatric human cervical spine (C4-CS-C6) three-dimensional nonlinear finite element models and to quantify the biomechanical responses. The adult model was modified to create one, three, and six year old pediatric spines by incorporating the local geometrical and material characteristics of the developmental anatomy. The adult human cervical spine model was constructed from close-up computed tomography sections and sequential anatomic cryomicrotome sections, and validated with experimental data. The biomechanical responses were compared with the adult human cervical spine behavior under different loading modes using three approaches. Approach 1: using pure overall structural scaling (reduce size) of the adult model. Approach 2: using three separate age-specific pediatric models incorporating local component geometrical and material property changes. Approach 3: applying the overall structural scaling to the above three pediatric models. All pediatric structures were consistently more flexible than the adult spine under all loading modes. However, responses obtained using the pure overall structural scaling (Approach 1) increased the flexibilities slightly. In contrast, the inclusion of local component geometrical and material property changes to create the three individual pediatric cervical spine models (Approach 2) produced significantly higher changes in the flexibilities under all loading modes. When overall structural scaling effects were added to the three pediatric models (Approach 3), the increase was not considerably higher. White the one year old pediatric model was the most flexible followed by the three and six year old models in flexion and extension, the three year old pediatric model was the most flexible under compression followed by the six and one year old models. The differing biomechanical responses among different pediatric groups were ascribed to the individual developmental anatomical features. The present findings of significant increase in biomechanical response due to local geometry and material property changes emphasize the need to consider the developmental anatomical features in the pediatric structures to better predict their biomechanical behavior.     

A conceptual model of the role of complex science in local authority consultations about air quality management

Abstract

There exists a clear imperative across the EU and within the UK towards the enhanced integration of community knowledge in environmental and health decision-making processes. The underlying social force that underpins this dynamic is the drive for a more accountable, transparent and publicly acceptable decision-making arena. However, relatively little research has been undertaken on the evaluation of local air quality management consultation in particular. In this context, the paper presents an evaluation of evidence resulting from questionnaire survey and case study research undertaken in the first round of the statutory process of local air quality management (LAQM), in which local authorities are required to consult on their air quality findings and intentions. We suggest that local authority perceptions of the relative abilities of differing stakeholders' grasp of air quality science, the process that translates that science into policy, and the institutional and organizational status of stakeholders (i.e. whether they are statutory or non-statutory stakeholders) may tend to transitively determine the choice of consultation methods used, the communication strategies chosen and the relative integration of stakeholder feedback into the LAQM decision-making process. In order to interrogate this potentially problematic chain of risk communication events, a preliminary conceptual model has been developed to enable the interrogation of the pathways through, and the obstacles to, the translation of air quality knowledge. The task is to unveil the sequential chains of association that comprise the LAQM risk communication process.     

Waste Management and Climate Change

Waste management has at least five types of impacts on climate change, attributable to: (1) landfill methane emissions; (2) reduction in industrial energy use and emissions due to recycling and waste reduction; (3) energy recovery from waste; (4) carbon sequestration in forests due to decreased demand for virgin paper; and (5) energy used in long-distance transport of waste: A recent USEPA study provides estimates of overall per-tonne greenhouse gas reductions due to recycling. Plausible calculations using these estimates suggest that countries such as the US or Australia could realise substantial greenhouse gas reductions through increased recycling, particularly of paper.     

Synchrotron micro-scale measurement of metal distributions in Phragmites australis and Typha latifolia root tissue from an urban brownfield site

Liberty State Park in New Jersey,USA,is a "brownfield" site containing various levels of contaminants.To investigate metal uptake and distributions in plants on the brownfield site,Phragmites australis and Typha latifolia were collected in Liberty State Park during the growing season(May–September)in 2011 at two sites with the high and low metal loads,respectively.The objective of this study was to understand the metal(Fe,Mn,Cu,Pb and Zn)concentration and spatial distributions in P.australis and T.latifolia root systems with micro-meter scale resolution using synchrotron X-ray microfluorescence(μXRF)and synchrotron X-ray computed microtomography(μCMT)techniques.The root structure measurement by synchrotron μCMT showed that high X-ray attenuation substance appeared in the epidermis.Synchrotron μXRF measurement showed that metal concentrations and distributions in the root cross-section between epidermis and vascular tissue were statistically different.Significant correlations were found between metals(Cu,Mn,Pb and Zn)and Fe in the epidermis,implying that metals were scavenged by Fe oxides.The results from this study suggest that the expression of metal transport and accumulation within the root systems may be element specific.The information derived from this study can improve our current knowledge of the wetland plant ecological function in brownfield remediation.     

One year in the life of <Emphasis Type="Italic">Bufo punctatus</Emphasis>: annual patterns of body temperature in a free-ranging desert anuran

The Mojave Desert is characterized by hot dry summers and cold winters. The red-spotted toad (Bufo (Anaxyrus) punctatus) is the predominant anuran species; yet little is known of their thermal histories and strategies to avoid temperature extremes. We measured body temperature (T(b)) in free-ranging adult toads across all four seasons of a year using implanted data loggers. There is marked individual variation in the temperatures experienced by these toads. As expected, toads generally escape extreme seasonal and diel temperature fluctuations. However, our data demonstrate a much wider estimated T(b) range than was previously assumed. Though often for short periods, red-spotted toads do experience T(b) as low as 3.1 degrees C and as high as 39.1 degrees C. All animals showed periods of prolonged thermal stability in cooler months and wider diel oscillations in warmer months. Red-spotted toad thermal history is likely a function of site choice; the exploitation of different refuges results in diverse thermal experiences. These data represent the most complete record of thermal experiences for a desert anuran and reveal greater extremes in body temperature than previously suggested.