Boundary impulse response functions in a century-long eddying global ocean simulation

Results are presented from a century-long 1/10° global ocean simulation that included a suite of age-related passive tracers. In particular, an ensemble of five global Boundary Impulse Response functions (BIRs, which are statistically related to the more fundamental Transit Time Distributions, TTDs) was included to quantify the character of the TTD when mesoscale eddies are explicitly simulated rather than parameterized. We also seek to characterize the level of variability in water mass ventilation timescales arising from eddy motions. The statistics of the BIR timeseries are described, and it is shown that the greatest variability occurs at early times, followed by a remarkable conformity between ensemble members at longer timescales. The statistics of the first moment of the BIRs are presented, and the upper-ocean spatial distribution of the standard deviation of the first moment of the BIRs discussed. It is shown that variations in the BIR first moment with respect to the ensemble average are typically only a few percent, and that the variability slightly decreases with increasing ensemble size, implying that only a few ensemble members may be necessary for a reasonable estimate of the TTD. The completeness of the estimated TTD, i.e., the degree to which the century long BIRs capture the range of global ocean ventilation timescales is discussed, and the potential for extrapolation of the BIR to longer times is briefly explored. Several regional BIRs were also simulated in order to quantify the relative abundance of fluid parcels that originate in specific geographical locations.     

Cuttlebone calcification increases during exposure to elevated seawater pCO2 in the cephalopod Sepia officinalis

Changes in seawater carbonate chemistry that accompany ongoing ocean acidification have been found to affect calcification processes in many marine invertebrates. In contrast to the response of most invertebrates, calcification rates increase in the cephalopod Sepia officinalis during long-term exposure to elevated seawater pCO₂. The present trial investigated structural changes in the cuttlebones of S. officinalis calcified during 6 weeks of exposure to 615 Pa CO₂. Cuttlebone mass increased sevenfold over the course of the growth trail, reaching a mean value of 0.71 ± 0.15 g. Depending on cuttlefish size (mantle lengths 44–56 mm), cuttlebones of CO₂-incubated individuals accreted 22–55% more CaCO₃ compared to controls at 64 Pa CO₂. However, the height of the CO₂-exposed cuttlebones was reduced. A decrease in spacing of the cuttlebone lamellae, from 384 ± 26 to 195 ± 38 μm, accounted for the height reduction The greater CaCO₃ content of the CO₂-incubated cuttlebones can be attributed to an increase in thickness of the lamellar and pillar walls. Particularly, pillar thickness increased from 2.6 ± 0.6 to 4.9 ± 2.2 μm. Interestingly, the incorporation of non-acid-soluble organic matrix (chitin) in the cuttlebones of CO₂-exposed individuals was reduced by 30% on average. The apparent robustness of calcification processes in S. officinalis, and other powerful ion regulators such as decapod cructaceans, during exposure to elevated pCO₂ is predicated to be closely connected to the increased extracellular [HCO₃ ⁻] maintained by these organisms to compensate extracellular pH. The potential negative impact of increased calcification in the cuttlebone of S. officinalis is discussed with regard to its function as a lightweight and highly porous buoyancy regulation device. Further studies working with lower seawater pCO₂ values are necessary to evaluate if the observed phenomenon is of ecological relevance.     

Long-term reactions of plants and macroinvertebrates to extreme floods in floodplain grasslands

Extreme summertime flood events are expected to become more frequent in European rivers due to climate change. In temperate areas, where winter floods are common, extreme floods occurring in summer, a period of high physiological activity, may seriously impact floodplain ecosystems. Here we report on the effects of the 2002 extreme summer flood on flora and fauna of the riverine grasslands of the Middle Elbe (Germany), comparing pre- and post-flooding data collected by identical methods. Plants, mollusks, and carabid beetles differed considerably in their response in terms of abundance and diversity. Plants and mollusks, displaying morphological and behavioral adaptations to flooding, showed higher survival rates than the carabid beetles, the adaptation strategies of which were mainly linked to life history. Our results illustrate the complexity of responses of floodplain organisms to extreme flood events. They demonstrate that the efficiency of resistance and resilience strategies is widely dependent on the mode of adaptation.     

A multi-scale examination of stopover habitat use by birds

Most of our understanding of habitat use by migrating land birds comes from studies conducted at single, small spatial scales, which may overemphasize the importance of intrinsic habitat factors, such as food availability, in shaping migrant distributions. We believe that a multi-scale approach is essential to assess the influence of factors that control en route habitat use. We determined the relative importance of eight variables, each operating at a habitat-patch, landscape, or regional spatial scale, in explaining the differential use of hardwood forests by Nearctic-Neotropical land birds during migration. We estimated bird densities through transect surveys at sites near the Mississippi coast during spring and autumn migration within landscapes with variable amounts of hardwood forest cover. At a regional scale, migrant density increased with proximity to the coast, which was of moderate importance in explaining bird densities, probably due to constraints imposed on migrants when negotiating the Gulf of Mexico. The amount of hardwood forest cover at a landscape scale was positively correlated with arthropod abundance and had the greatest importance in explaining densities of all migrants, as a group, during spring, and of insectivorous migrants during autumn. Among landscape scales ranging from 500 m to 10 km radius, the densities of migrants were, on average, most strongly and positively related to the amount of hardwood forest cover within a 5 km radius. We suggest that hardwood forest cover at this scale may be an indicator of habitat quality that migrants use as a cue when landing at the end of a migratory flight. At the patch scale, direct measures of arthropod abundance and plant community composition were also important in explaining migrant densities, whereas habitat structure was of little importance. The relative amount of fleshy-fruited trees was positively related and was the most important variable explaining frugivorous migrant density during autumn. Although constraints extrinsic to habitat had a moderate role in explaining migrant distributions, our results are consistent with the view that food availability is the ultimate factor shaping the distributions of birds during stopover.     

Synthesis of chromium-containing pigments from chromium recovered from leather waste

Cobalt-chromite green and chrome-tin pink pigments have been prepared from chromium extracted from leather shavings produced as a waste product of the leather-tanning industry. The alkaline agent (NaOH, CaO, MgO, NH4OH) used in the extraction process influences the nature of the final product. The effect of the NH4OH:CaO ratio on the final product in the case of cobalt-chromite green was examined. The pigments obtained were characterized by FT-IR and X-ray diffraction (XRD). Colour measurements were compared with those recorded from materials prepared from pure Cr2O3. The leaching of Cr(VI) from the materials was examined by UV spectroscopy.     

Assessing potential risks to wildlife and sportsmen from exposure to dioxin in pulp and paper mill sludge spread on managed woodlands

Potential human and wildlife exposures to TCDD in landspread pulp and paper mill sludge in the State of Maine were evaluated by means of a human health and an ecological risk assessment methodology. The highest historical concentrations of TCDD reported for these sludges do not present a risk to American woodcock, selected as an indicator species for this analysis. Concentrations of TCDD as high as 50 ppt in soil are not likely to produce adverse effects in the embryonic/hatchling stage of the woodcock. This soil concentration of TCDD does not present a significant risk to sportsmen and their families that may consume birds which inhabit these sites.     

Risk assessment of pesticide runoff from turf

The TurfPQ model was used to simulate the runoff of 15 pesticides commonly applied to creeping bentgrass (Agrostis stolonifera L.) fairways and greens on golf courses in the northeastern USA. Simulations produced 100-yr daily records of water runoff, pesticide runoff, and pesticide concentration in runoff for three locations: Boston, MA, Philadelphia, PA, and Rochester, NY. Results were summarized as annual and monthly means and annual maximum daily loads (AMDLs) corresponding to 10- and 20-yr return periods. Mean annual pesticide runoff loads did not exceed 3% of annual applications for any pesticide or site, and most losses were substantially less than 1% of application. However, annual or monthly mean concentrations of chlorothalonil, iprodione, and PCNB in fairway runoff often exceeded concentrations that result in 50% mortality of the affected species (LC50) for aquatic organisms. Concentrations of azoxystrobin, bensulide, cyfluthrin, and trichlorfon in extreme (1 in 10 yr or 1 in 20 yr) events often approached or exceeded LC50 levels. Concentrations of halofenozide, mancozeb, MCPP, oxadiazon, propiconazole, thiophanate-methyl, triadimefon, and trinexapac-ethyl were well below LC50 levels, and turf runoff of these chemicals does not appear to be hazardous to aquatic life in surface waters.     

Protected forests in Europe approaches-harmonising the definitions for international comparison and forest policy making

Comparison of forest protection between regions in Europe is extremely difficult, because there is such wide variation of strategies, procedures and constraints; the way forests have been used historically and their present closeness to nature also varies, and furthermore so does the definition of what constitutes a forest. For the European Ministerial Conference on the Protection of Forests in Europe (MCPFE) in 2003, forest protection has been harmonised into three categories for the sake of comparison: protection to safeguard biodiversity, protection of landscape and specific natural features, and protective forest functions.There is no single, uniform and universal model and no internationally agreed target with respect to the percentage of forests which should be protected. What is more important than a fixed percentage level of forested area (e.g. 5 or 10%) is that the protection network should be biogeographically and ecologically representative and accordingly distributed on a regional basis. Long-term practical experience and research have proved that conservation of different species of organisms can be assured by appropriate silvicultural management of multifunctional production forests. Consequently, the focus of debate in Europe appears to shift more and more from total protection in segregated areas to 'precision protection' and to combining protection and timber production in the holistic, integrated concept of modern management of forest areas.Advances in regional ecological planning and the growing adoption of naturalistic forest management practices have slowed the decline of the biological diversity in the multifunctional production forests. However, this fact is not yet widely and sufficiently acknowledged and appreciated. There is consequently a political and scientific need for continued study of the effects of naturalistic silvicultural management on the biodiversity of forests. Information from such research is crucially needed before new and additional protection networks and schemes are set up on a large-scale. Protection by voluntary contracts between parties is a workable model concept for European forestry based on private forest ownership. In small private forests, patches of forest worth protecting are often small and located within production forests.Forest certification can contribute to the efforts of maintaining biodiversity in multifunctional production forests and offers an instrument of independently monitoring and verifying that forests are managed according to the agreed criteria. Forest certification is not an alternative or a means of increasing forest protection, because as a voluntary process it cannot guarantee the permanence of protected areas or deal with issues of finance and compensation.     

Untersuchungen zur Aufnahme von HCB und Pyren durch den KompostwurmEisenia fetida und ausgew?hlte Regenwurmwildarten

Zusammenfassung  Ziel der beschriebenen Untersuchungen war die praktische überprüfung eines Methodenentwurfs zur Erfassung der Bioakkumulation von Umweltchemikalien mitEisenia fetida, der Eignung vonE. fetida als Modellorganismus und des OECD-Kunstbodens als Standardsubstrat. Als Testorganismen wurden aus eigener Zucht der KompostwurmEisenia fetida und nach FeldentnahmeAllolobophora caliginosa, Allolobophora chlorotica, Allolobophora longa undLumbricus rubellus eingesetzt. Testb?den waren der OECD-Kunstboden und ein Boden vom Versuchsfeld der BBA in Berlin-Dahlem. Beiden B?den wurden die Testsubstanzen Hexachlorbenzol und Pyren in einer Konzentration von 10 mg/kg Bodentrockengewicht zugemischt. Die Expositionszeit der Regenwürmer betrug 4 Wochen bei w?chentlicher Bestimmung der Konzentrationen der Testsubstanzen in den Würmern und B?den. Die fürE. fetida sowie die Wildarten errechneten Anreicherungsfaktoren (AF) beliefen sich bei HCB in Abh?ngigkeit des verwendeten Bodens auf Werte zwischen 10 und 17 und bei Pyren auf Werte zwischen 0,9 und 1,7. Durch Umrechnung der Bodenkonzentrationen auf Gehalte in der Wasserphase und Ableitung der entsprechenden Anreicherungsfaktoren kann ein Vergleich mit BCF-Werten, die aus QSAR’S anderer Regenwurmarten und Fischen berechnet wurden, hergestellt werden. Die Ergebnisse lassen den Schluss zu, dass der Regenwurmtest mitE. fetida (OECD 1984, ISO 1998) für die Untersuchung der Bioakkumulation geeignet ist. OnlineFirst: 31. 05. 2002