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131.
Environmental Geochemistry and Health - Accumulation of heavy metals (HMs) in fish tissues is an important factor in monitoring the health and safety of aquatic ecosystems. Furthermore, fish are...  相似文献   
132.
Environmental Geochemistry and Health - Polycyclic aromatic hydrocarbons (PAHs) are an important group of compounds of major environmental concern, which are in the class of persistent organic...  相似文献   
133.
Heterogeneous catalysts are used for control of environmental pollution. Heterogeneous catalysts are easily separated from the reaction mixture, thus allowing their recovery and re-use. There is a need for catalysts that are efficient under mild conditions. Here, we show that silica-supported antimony(III) chloride (SbCl3/SiO2) acts as a highly efficient heterogeneous Lewis acid catalyst for the Paal–Knorr pyrrole synthesis at room temperature. We found that condensation of hexane-2,5-dione with aromatic and aliphatic primary amines in hexane using SbCl3/SiO2 with 7.6 wt% SbCl3 was the best reaction condition. The silica support facilitated the workup of the reaction mixture and provided a reusable catalyst at least for 7 runs without significant loss in activity. Indeed, the yield was 98% for the first run and 84% for the 7th run. We conclude that low catalyst loading, operational simplicity, practicability and applicability to various substrates make this reaction an interesting alternative to previously applied procedures. From the environmental standpoint, this eco-friendly catalyst is stable, highly active, easy to prepare and handle.  相似文献   
134.
This investigation discloses a greener reaction to prepare pyrrole derivatives. Metal-free catalysts are greener alternatives to existing metal catalysts in synthetic organic chemistry. Indeed, transition metals are often costly and toxic. They may be found as traces in health reaction products such as pharmaceuticals. Alternatively small organic molecules termed “organocatalysts” allow the synthesis of valuable products without traces of toxic metals. Here, we show for the first time the use of vitamin B1 as new organocatalyst for the Paal–Knorr pyrrole synthesis under ambient conditions. Reaction conditions were optimized for the reaction of hexane-2,5-dione with 4-methoxyaniline. Ethanol was the most effective solvent. The conversion was quantitative using vitamin B1, by comparison with a low yield of 30?% without catalysis. The best conditions were performed in ethanol with 5?mol % of vitamin B1 during 1?h. This reaction was tested using various aromatic amines. To conclude the use of vitamin B1 for the Paal–Knorr pyrrole, cyclocondensation has mild reaction conditions, is simple to perform, and gives moderate to excellent yields. It is therefore a promising reaction for the preparation of various pyrrole derivatives.  相似文献   
135.
Turbulent velocity profile in fully-developed open channel flows   总被引:2,自引:0,他引:2  
The determination of velocity profile in turbulent narrow open channels is a difficult task due to the significant effects of the anisotropic turbulence that involve the Prandtl’s second type of secondary flow occurring in the cross section. With these currents the maximum velocity appears below the free surface that is called dip phenomenon. The well-known logarithmic law describes the velocity distribution in the inner region of the turbulent boundary layer but it is not adapted to define the velocity profile in the outer region of narrow channels. This paper relies on an analysis of the Navier–Stokes equations and yields a new formulation of the vertical velocity profile in the center region of steady, fully developed turbulent flows in open channels. This formulation is able to predict time averaged primary velocity in the outer region of the turbulent boundary layer for both narrow and wide open channels. The proposed law is based on the knowledge of the aspect ratio and involves a parameter CAr depending on the position of the maximum velocity (ξdip). ξdip may be derived, either from measurements or from an empirical equation given in this paper. A wide range of longitudinal velocity profile data for narrow open channels has been used for validating the model. The agreement between the measured and the computed velocities is rather good, despite the simplification used.  相似文献   
136.
Cesium and mercury are two mono-valent elements which can be found in toxic industrial, medical, and nuclear wastes. Their presence in the environment has deleterious effects on the ecosystem, living organisms including humans. Due to the chemical nature of these metals, bioremediation by conventional methods is more difficult to achieve compared to other metals. In this study, we used three biosorbents (oak powder, gall nut, and bacterial exopolymer) for the bioremediation of Hg and Cs. Bio-polymer was produced in the GMS mineral broth. Synthetic wastes of Hg(NO3)2 and isotope Cs-133 as the single-metal solutions were used. The biorefining process was carried out in glass columns, made of Pyrex, with dimensions 20?×?7/2?cm2 with a V-shaped bottom. The samples were analyzed using atomic absorption. The experimental results showed that eliminated metal percent by oak powder, gall nut, and bacterial exopolymer were, respectively, of 94.8%, 96%, and 13.8% for Hg and 7.8%, 4.4%, and 69.4% for Cs. The tests revealed that Ca++, when used as flocculant, played a key role in both biosorption and bio-precipitation rates. Consequently, it was concluded that the investigated biosorbents could be use as an integrated biosorption system for the refinement of mixed wastes.  相似文献   
137.
In this investigation, Fe3O4 magnetic nanoparticles (MNPs) were prepared by the alkalinization of an aqueous medium containing ferrous sulfate and ferric chloride. In the next step, a Fe3O4–AgCl magnetic nanocomposite was fabricated by the drop-by-drop addition of silver nitrate solution into a NaCl solution containing Fe3O4 MNPs. All prepared nanoparticles were characterized by transition electron microscopy (TEM), X-ray diffraction (XRD), and energy-dispersive X-ray spectroscopy (EDS). Both particle types varied in size from 2.5 to 20?nm, with an average size of 7.5?nm for Fe3O4 MNPs and 12.5?nm for Fe3O4–AgCl nanocomposites. The antibacterial effect of the Fe3O4 MNPs and fabricated Fe3O4–AgCl nanocomposites against Escherichia coli (ATCC 35218) were investigated by conventional serial agar dilution method using the Müller–Hinton Agar medium. The minimum inhibitory concentration was 4?mg?mL?1 for Fe3O4 MNPs and 2?mg?mL?1 for the Fe3O4–AgCl magnetic nanocomposites. Time-kill course assays showed that the Fe3O4–AgCl magnetic nanocomposites successfully killed all inoculated bacterial cells during an exposure time of 60?min. The antibacterial activity of recycled Fe3O4–AgCl magnetic nanocomposites over four 60?min cycles of antibacterial treatment was further tested against E. coli by the colony-forming unit (CFU) method. The antibacterial efficiency of the nanocomposites was constant over two cycles of antibacterial testing.  相似文献   
138.
Environment, Development and Sustainability - Spatial simulation of land-use change scenarios in metropolitan areas is essential for analyzing both the causes and consequences of various future...  相似文献   
139.
140.
Because of the recent frequent observations of major dust storms in southwestern cities in Iran such as Ahvaz, and the importance of the ionic composition of particulate matters regarding their health effects, source apportionment, etc., the present work was conducted aiming at characterizing the ionic composition of total suspended particles (TSP) and particles on the order of ~10?μm or less (PM(10)) during dust storms in Ahvaz in April-September 2010. TSP and PM(10) samples were collected and their ionic compositions were determined using an ion chromatography. Mean concentrations of TSP and PM(10) were 1,481.5 and 1,072.9?μg/m(3), respectively. Particle concentrations during the Middle Eastern Dust (MED) days were up to four times higher than those in normal days. Ionic components contributed to only 9.5% and 11.3% of the total mass of TSP and PM(10), respectively. Crustal ions were most abundant during dust days, while secondary ions were dominant during non-dust days. Ca(2+)/Na(+) and Cl(-)/Na(+) ratios can be considered as the indicators for identification of the MED occurrence. It was found that possible chemical forms of NaCl, (NH(4))(2)SO(4), KCl, K(2)SO(4), CaCl(2), Ca(NO(3))(2), and CaSO(4) may exist in TSP. Correlation between the anionic and cationic components suggests slight anion and cation deficiencies in TSP and PM(10) samples, though the deficiencies were negligible.  相似文献   
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